Visible Light‐Induced [3+2] Annulation Reaction of Alkenes with Vinyl Azides: Direct Synthesis of Functionalized Pyrroles
Comprehensive Summary A photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic dye photocatalysts. Broad substrate scope and high functional group tolerance were demonstrated by more than 50 examples. The reaction prov...
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Published in | Chinese journal of chemistry Vol. 42; no. 2; pp. 151 - 156 |
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Format | Journal Article |
Language | English |
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Weinheim
WILEY‐VCH Verlag GmbH & Co. KGaA
15.01.2024
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Abstract | Comprehensive Summary
A photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic dye photocatalysts. Broad substrate scope and high functional group tolerance were demonstrated by more than 50 examples. The reaction provides a novel and efficient method for the synthesis of polyfunctionalized pyrroles under very mild metal‐free conditions without other additives.
A visible‐light‐induced catalytic [3+2] annulation of alkenes with vinyl azides was developed in the presence of organic dye photocatalysts. The reaction provides a novel and efficient strategy for the construction of polyfunctionalized pyrroles under very mild metal‐free conditions without other additives. |
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AbstractList | Comprehensive SummaryA photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic dye photocatalysts. Broad substrate scope and high functional group tolerance were demonstrated by more than 50 examples. The reaction provides a novel and efficient method for the synthesis of polyfunctionalized pyrroles under very mild metal‐free conditions without other additives. A photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic dye photocatalysts. Broad substrate scope and high functional group tolerance were demonstrated by more than 50 examples. The reaction provides a novel and efficient method for the synthesis of polyfunctionalized pyrroles under very mild metal‐free conditions without other additives. Comprehensive Summary A photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic dye photocatalysts. Broad substrate scope and high functional group tolerance were demonstrated by more than 50 examples. The reaction provides a novel and efficient method for the synthesis of polyfunctionalized pyrroles under very mild metal‐free conditions without other additives. A visible‐light‐induced catalytic [3+2] annulation of alkenes with vinyl azides was developed in the presence of organic dye photocatalysts. The reaction provides a novel and efficient strategy for the construction of polyfunctionalized pyrroles under very mild metal‐free conditions without other additives. |
Author | Wang, Xin‐Yu Zhao, Yu‐Long Yang, Ming Wang, Jie |
Author_xml | – sequence: 1 givenname: Ming surname: Yang fullname: Yang, Ming organization: Northeast Normal University – sequence: 2 givenname: Xin‐Yu surname: Wang fullname: Wang, Xin‐Yu organization: Northeast Normal University – sequence: 3 givenname: Jie surname: Wang fullname: Wang, Jie organization: Northeast Normal University – sequence: 4 givenname: Yu‐Long surname: Zhao fullname: Zhao, Yu‐Long email: zhaoyl351@nenu.edu.cn organization: Northeast Normal University |
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Keywords | CATALYSIS Vinyl azides Alkenes Radical reactions Photocatalysis Pyrroles Annulation |
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A photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of... A photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic dye photocatalysts.... Comprehensive SummaryA photocatalytic [3+2] annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic... |
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SubjectTerms | Additives Alkenes Annulation Chemical reactions Chemical synthesis Chemistry Chemistry, Multidisciplinary Functional groups Irradiation Organic chemistry Photocatalysis Physical Sciences Pyrroles Radical reactions Science & Technology Substrates Vinyl azides |
Title | Visible Light‐Induced [3+2] Annulation Reaction of Alkenes with Vinyl Azides: Direct Synthesis of Functionalized Pyrroles |
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