High Air Stability and Excellent Li Metal Compatibility of Argyrodite‐Based Electrolyte Enabling Superior All‐Solid‐State Li Metal Batteries

• Published in: Advanced functional materials Vol. 32; no. 32
• Main Authors: Liu, Hong, Zhu, Qisi, Wang, Chao, Wang, Guoxu, Liang, Yuhao, Li, Dabing, Gao, Lei, Fan, Li‐Zhen
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc 01.08.2022
• Subjects: air stability; all‐solid‐state Li metal batteries; Bismuth base alloys; Chlorobenzene; Compatibility; Critical current density; Density functional theory; Diffusion barriers; Electrolytes; Ion currents; Li metal compatibility; Lithium batteries; Machinability; Materials science; Molten salt electrolytes; Room temperature; Solid electrolytes; Structural stability; sulfide electrolytes

Sulfide solid electrolytes (SSEs) for all‐solid‐state Li metal batteries (ASSLMBs) are attracting increasing attention due to their ultrahigh ionic conductivity and good machinability. However, current SSEs generally suffer from inferior Li metal compatibility and poor air‐stability, which severely...