Light‐Induced Electron Transfer Toward On/Off Room Temperature Phosphorescence in Two Photochromic Coordination Polymers

• Published in: Advanced functional materials Vol. 33; no. 47
• Main Authors: Feng, Dong‐Xue, Mu, Ying, Li, Jie, De Han, Song‐, Li, Jin‐Hua, Sun, Hui‐Li, Pan, Mei, Hu, Ji‐Xiang, Wang, Guo‐Ming
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc 01.11.2023
• Subjects: Benzene; bidirectional regulation; charge separation; Chemical synthesis; Coordination polymers; Electron transfer; Energy transfer; Materials science; Phosphorescence; Photochromism; Room temperature; room temperature phosphorescence

Photoswitchable room temperature phosphorescence (RTP) materials are of great interest due to their potential applications in optical devices and switches. Herein, two Zn‐based coordination polymers (CPs) (H3‐TPB)·[Zn6(H‐HEDP)(HEDP)3(H2O)2]·5H2O (complex 1; HEDP = hydroxyethylidene diphosphonate; TP...