Cobalt Nanoparticles Embedded in N‐Doped Porous Carbon Derived from Bimetallic Zeolitic Imidazolate Frameworks for One‐Pot Selective Oxidative Depolymerization of Lignin

• Published in: ChemCatChem Vol. 11; no. 4; pp. 1264 - 1271
• Main Authors: Sun, Kangkang, Chen, Shujie, Zhang, Jiawei, Lu, Guo‐Ping, Cai, Chun
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 20.02.2019
• Subjects: Bimetallic zeolitic imidazolate frameworks; Bimetals; Carbon; Catalysis; Catalysts; Cobalt; Cobalt nanoparticles; Depolymerization; Electron transfer; Heterogeneous catalysis; Lignin; Magnetic fields; Metal-organic frameworks; Nanoparticles; Nitrogen; Oxidation depolymerization; Pressure; Pyrolysis; Substrates

Cobalt nanoparticles embedded in N‐doped porous carbon (Co@CN) were prepared by the pyrolysis of bimetallic zeolitic imidazolate frameworks (BMZIFs) based on ZIF‐8 and ZIF‐67. The catalyst shows excellent catalytic efficiency in one‐pot selective oxidative cleavage of different linkages like β‐O‐4,...