Diffusion model of sulfate ions in concrete based on pore change of cement mortar and its application in mesoscopic numerical simulation
Sulfate attack is a major cause of the deterioration of concrete structures. Accurately predicting the temporal and spatial distribution of sulfate ions in concrete is the basis for revealing the mechanism of concrete performance deterioration caused by sulfate attack. In this article, based on the...
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Published in | Structural concrete : journal of the FIB Vol. 23; no. 6; pp. 3786 - 3803 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY‐VCH Verlag GmbH & Co. KGaA
01.12.2022
Wiley Subscription Services, Inc |
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Abstract | Sulfate attack is a major cause of the deterioration of concrete structures. Accurately predicting the temporal and spatial distribution of sulfate ions in concrete is the basis for revealing the mechanism of concrete performance deterioration caused by sulfate attack. In this article, based on the pore change caused by sulfate damage to cement mortar, a diffusion model of sulfate ions in cement mortar considering changes in surface concentration was established. Furthermore, a two‐dimensional mesoscopic concrete model composed of cement mortar, coarse aggregate, the intrafacial transition zone (ITZ) and macroscopic defects, which can reflect the real aggregate shape, was constructed to study the diffusion of sulfate ions in concrete. The correctness of the model is verified with existing experimental data, and the model is further studied. The results show the following. (1) The average value of the calculation results of multiple sets of models can be used to eliminate the influence of the randomness of the construction of the two‐dimensional mesoscopic concrete model. (2) With increasing stone content, the corrosion depth increases, but the average concentration at a given location decreases. (3) With increasing sulfate solution concentration and water‐cement ratio, the sulfate ion concentration and the corrosion depth in concrete increase. |
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AbstractList | Abstract
Sulfate attack is a major cause of the deterioration of concrete structures. Accurately predicting the temporal and spatial distribution of sulfate ions in concrete is the basis for revealing the mechanism of concrete performance deterioration caused by sulfate attack. In this article, based on the pore change caused by sulfate damage to cement mortar, a diffusion model of sulfate ions in cement mortar considering changes in surface concentration was established. Furthermore, a two‐dimensional mesoscopic concrete model composed of cement mortar, coarse aggregate, the intrafacial transition zone (ITZ) and macroscopic defects, which can reflect the real aggregate shape, was constructed to study the diffusion of sulfate ions in concrete. The correctness of the model is verified with existing experimental data, and the model is further studied. The results show the following. (1) The average value of the calculation results of multiple sets of models can be used to eliminate the influence of the randomness of the construction of the two‐dimensional mesoscopic concrete model. (2) With increasing stone content, the corrosion depth increases, but the average concentration at a given location decreases. (3) With increasing sulfate solution concentration and water‐cement ratio, the sulfate ion concentration and the corrosion depth in concrete increase. Sulfate attack is a major cause of the deterioration of concrete structures. Accurately predicting the temporal and spatial distribution of sulfate ions in concrete is the basis for revealing the mechanism of concrete performance deterioration caused by sulfate attack. In this article, based on the pore change caused by sulfate damage to cement mortar, a diffusion model of sulfate ions in cement mortar considering changes in surface concentration was established. Furthermore, a two‐dimensional mesoscopic concrete model composed of cement mortar, coarse aggregate, the intrafacial transition zone (ITZ) and macroscopic defects, which can reflect the real aggregate shape, was constructed to study the diffusion of sulfate ions in concrete. The correctness of the model is verified with existing experimental data, and the model is further studied. The results show the following. (1) The average value of the calculation results of multiple sets of models can be used to eliminate the influence of the randomness of the construction of the two‐dimensional mesoscopic concrete model. (2) With increasing stone content, the corrosion depth increases, but the average concentration at a given location decreases. (3) With increasing sulfate solution concentration and water‐cement ratio, the sulfate ion concentration and the corrosion depth in concrete increase. |
Author | Zhuang, Yang Du, Libing Zhou, Xiaohan Liu, Xinrong |
Author_xml | – sequence: 1 givenname: Yang surname: Zhuang fullname: Zhuang, Yang email: zhuangyangchn@outlook.com organization: National Joint Engineering Research Center of Geohazards Prevention in The Reservoir Areas (Chongqing) – sequence: 2 givenname: Xinrong surname: Liu fullname: Liu, Xinrong email: liuxrong@126.com organization: National Joint Engineering Research Center of Geohazards Prevention in The Reservoir Areas (Chongqing) – sequence: 3 givenname: Xiaohan orcidid: 0000-0003-2228-4924 surname: Zhou fullname: Zhou, Xiaohan email: zhouxh2008@126.com organization: National Joint Engineering Research Center of Geohazards Prevention in The Reservoir Areas (Chongqing) – sequence: 4 givenname: Libing surname: Du fullname: Du, Libing email: dulibing0622@126.com organization: National Joint Engineering Research Center of Geohazards Prevention in The Reservoir Areas (Chongqing) |
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Copyright | 2022 . International Federation for Structural Concrete 2022 fib. International Federation for Structural Concrete |
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Notes | Funding information National Natural Science Foundation for Young Scientists of China, Grant/Award Number: 52104076; Science and Technology Foundation of the Department of Transportation of Zhejiang Province, China, Grant/Award Number: 2020028 Discussion on this paper must be submitted within two months of the print publication. The discussion will then be published in print, along with the authors’ closure, if any, approximately nine months after the print publication. |
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Snippet | Sulfate attack is a major cause of the deterioration of concrete structures. Accurately predicting the temporal and spatial distribution of sulfate ions in... Abstract Sulfate attack is a major cause of the deterioration of concrete structures. Accurately predicting the temporal and spatial distribution of sulfate... |
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SubjectTerms | Cement cement mortar Concrete deterioration Concrete structures Corrosion Diffusion diffusion model Ion concentration Mathematical models mesoscopic model Mortars (material) Performance degradation Spatial distribution sulfate attack volume fraction of damage |
Title | Diffusion model of sulfate ions in concrete based on pore change of cement mortar and its application in mesoscopic numerical simulation |
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