Synthesis of Fused B‐Containing Heterocyclic Compounds and Their Relevant Optical Properties
A series of fused 4,5‐borazaropyrrolo[1,2‐a]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via direct formation of C–B and N–B bonds. The target products were obtained in moderate to high yields under mild conditions. The optical propert...
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| Published in | European journal of organic chemistry Vol. 2018; no. 34; pp. 4812 - 4817 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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16.09.2018
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| Abstract | A series of fused 4,5‐borazaropyrrolo[1,2‐a]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via direct formation of C–B and N–B bonds. The target products were obtained in moderate to high yields under mild conditions. The optical properties of some products were investigated by UV/Vis spectroscopy and spectrofluorometry. Moreover, the influence of structural modification on the spectroscopic and electronic properties was studied by DFT calculations.
A new B‐containing heterocyclic compound! A series of azaborines were prepared through 1‐(2‐aminophenyl)pyrroles and organotrifluoroborates in a one‐pot reaction. The optical properties of these azaborines were investigated and the attractive photometrics could be applied in many scientific fields. |
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| AbstractList | A series of fused 4,5‐borazaropyrrolo[1,2‐a]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via direct formation of C–B and N–B bonds. The target products were obtained in moderate to high yields under mild conditions. The optical properties of some products were investigated by UV/Vis spectroscopy and spectrofluorometry. Moreover, the influence of structural modification on the spectroscopic and electronic properties was studied by DFT calculations. A series of fused 4,5‐borazaropyrrolo[1,2‐ a ]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via direct formation of C–B and N–B bonds. The target products were obtained in moderate to high yields under mild conditions. The optical properties of some products were investigated by UV/Vis spectroscopy and spectrofluorometry. Moreover, the influence of structural modification on the spectroscopic and electronic properties was studied by DFT calculations. A series of fused 4,5‐borazaropyrrolo[1,2‐a]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via direct formation of C–B and N–B bonds. The target products were obtained in moderate to high yields under mild conditions. The optical properties of some products were investigated by UV/Vis spectroscopy and spectrofluorometry. Moreover, the influence of structural modification on the spectroscopic and electronic properties was studied by DFT calculations. A new B‐containing heterocyclic compound! A series of azaborines were prepared through 1‐(2‐aminophenyl)pyrroles and organotrifluoroborates in a one‐pot reaction. The optical properties of these azaborines were investigated and the attractive photometrics could be applied in many scientific fields. |
| Author | Yan, Rulong An, Zhenyu Qi, Zhenjie Yuan, Bingxiang Ni, Jixiang Kang, Jie Wu, Mingzhong |
| Author_xml | – sequence: 1 givenname: Zhenyu surname: An fullname: An, Zhenyu organization: Lanzhou University – sequence: 2 givenname: Mingzhong surname: Wu fullname: Wu, Mingzhong organization: Lanzhou University – sequence: 3 givenname: Jie surname: Kang fullname: Kang, Jie organization: Lanzhou University – sequence: 4 givenname: Jixiang surname: Ni fullname: Ni, Jixiang organization: Lanzhou University – sequence: 5 givenname: Zhenjie surname: Qi fullname: Qi, Zhenjie organization: Lanzhou University – sequence: 6 givenname: Bingxiang surname: Yuan fullname: Yuan, Bingxiang organization: Lanzhou University – sequence: 7 givenname: Rulong orcidid: 0000-0002-0450-3065 surname: Yan fullname: Yan, Rulong email: yanrl@lzu.edu.cn organization: Lanzhou University |
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| Keywords | CORES Boron Synthesis design CROSS-COUPLINGS ACID 2,1-BORAZARONAPHTHALENES Optical properties HETEROAROMATIC-COMPOUNDS Fused-ring systems Functional organic materials |
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| Snippet | A series of fused 4,5‐borazaropyrrolo[1,2‐a]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via... A series of fused 4,5-borazaropyrrolo[1,2-a]quinolines have been prepared from potassium organotrifluoroborates and substituted 1-(2-aminophenyl)pyrroles via... A series of fused 4,5‐borazaropyrrolo[1,2‐ a ]quinolines have been prepared from potassium organotrifluoroborates and substituted 1‐(2‐aminophenyl)pyrroles via... |
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| SubjectTerms | Boron Chemistry Chemistry, Organic Functional organic materials Fused‐ring systems Heterocyclic compounds Optical properties Organic compounds Physical Sciences Pyrroles Science & Technology Synthesis design |
| Title | Synthesis of Fused B‐Containing Heterocyclic Compounds and Their Relevant Optical Properties |
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