Iron and copper recovery from copper slags through smelting with waste cathode carbon from aluminium electrolysis
To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent b...
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Published in | Journal of Central South University Vol. 28; no. 7; pp. 2010 - 2021 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Changsha
Central South University
01.07.2021
Springer Nature B.V |
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Abstract | To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent but also as a fluxing agent to decrease slag melting point. Upon holding for 60 min in air atmosphere first and then smelting with 14.4 wt% waste cathode carbon and 25 wt% CaO for 180 min in high purity Ar atmosphere at 1450 °C, the recovery rates of Cu and Fe reach 95.89% and 94.64%, respectively, and meanwhile greater than 90% of the fluoride from waste cathode carbon is transferred into the final slag as CaF
2
and Ca
2
Si
2
F
2
O
7
, which makes the content of soluble F in the slag meet the national emission standard. Besides, the sulphur content in the obtained Fe-Cu alloy is low to 0.03 wt%. |
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AbstractList | To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent but also as a fluxing agent to decrease slag melting point. Upon holding for 60 min in air atmosphere first and then smelting with 14.4 wt% waste cathode carbon and 25 wt% CaO for 180 min in high purity Ar atmosphere at 1450 °C, the recovery rates of Cu and Fe reach 95.89% and 94.64%, respectively, and meanwhile greater than 90% of the fluoride from waste cathode carbon is transferred into the final slag as CaF
2
and Ca
2
Si
2
F
2
O
7
, which makes the content of soluble F in the slag meet the national emission standard. Besides, the sulphur content in the obtained Fe-Cu alloy is low to 0.03 wt%. To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent but also as a fluxing agent to decrease slag melting point. Upon holding for 60 min in air atmosphere first and then smelting with 14.4 wt% waste cathode carbon and 25 wt% CaO for 180 min in high purity Ar atmosphere at 1450 °C, the recovery rates of Cu and Fe reach 95.89% and 94.64%, respectively, and meanwhile greater than 90% of the fluoride from waste cathode carbon is transferred into the final slag as CaF2 and Ca2Si2F2O7, which makes the content of soluble F in the slag meet the national emission standard. Besides, the sulphur content in the obtained Fe-Cu alloy is low to 0.03 wt%. |
Author | Mao, Kai-xuan Li, Lei Xu, Miao |
Author_xml | – sequence: 1 givenname: Kai-xuan surname: Mao fullname: Mao, Kai-xuan organization: State Key Laboratory of Complex Non-ferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction of Ministry of Education, Kunming University of Science and Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology – sequence: 2 givenname: Lei orcidid: 0000-0003-1205-3989 surname: Li fullname: Li, Lei email: tianxiametal1008@163.com organization: State Key Laboratory of Complex Non-ferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction of Ministry of Education, Kunming University of Science and Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology – sequence: 3 givenname: Miao surname: Xu fullname: Xu, Miao organization: State Key Laboratory of Complex Non-ferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction of Ministry of Education, Kunming University of Science and Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology |
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Keywords | copper slags waste cathode carbon iron and copper recovery 氟化物 废阴极碳 铜渣 氧化脱硫 fluoride 铁和铜的回收 oxidative desulfurization smelting reduction 熔融还原 |
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Snippet | To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one... |
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SubjectTerms | Aluminum Carbon Cathodes Copper Electrolysis Emission standards Engineering Ferrous alloys Fluxing Hazardous wastes Iron Melting points Metallic Materials Metallurgy Recovery Reducing agents Slag Smelting reduction |
Title | Iron and copper recovery from copper slags through smelting with waste cathode carbon from aluminium electrolysis |
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