Iron and copper recovery from copper slags through smelting with waste cathode carbon from aluminium electrolysis

To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent b...

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Published inJournal of Central South University Vol. 28; no. 7; pp. 2010 - 2021
Main Authors Mao, Kai-xuan, Li, Lei, Xu, Miao
Format Journal Article
LanguageEnglish
Published Changsha Central South University 01.07.2021
Springer Nature B.V
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Abstract To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent but also as a fluxing agent to decrease slag melting point. Upon holding for 60 min in air atmosphere first and then smelting with 14.4 wt% waste cathode carbon and 25 wt% CaO for 180 min in high purity Ar atmosphere at 1450 °C, the recovery rates of Cu and Fe reach 95.89% and 94.64%, respectively, and meanwhile greater than 90% of the fluoride from waste cathode carbon is transferred into the final slag as CaF 2 and Ca 2 Si 2 F 2 O 7 , which makes the content of soluble F in the slag meet the national emission standard. Besides, the sulphur content in the obtained Fe-Cu alloy is low to 0.03 wt%.
AbstractList To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent but also as a fluxing agent to decrease slag melting point. Upon holding for 60 min in air atmosphere first and then smelting with 14.4 wt% waste cathode carbon and 25 wt% CaO for 180 min in high purity Ar atmosphere at 1450 °C, the recovery rates of Cu and Fe reach 95.89% and 94.64%, respectively, and meanwhile greater than 90% of the fluoride from waste cathode carbon is transferred into the final slag as CaF 2 and Ca 2 Si 2 F 2 O 7 , which makes the content of soluble F in the slag meet the national emission standard. Besides, the sulphur content in the obtained Fe-Cu alloy is low to 0.03 wt%.
To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one hazardous waste (waste cathode carbon) was used to treat another (copper slags). The waste cathode carbon is used not only as a reducing agent but also as a fluxing agent to decrease slag melting point. Upon holding for 60 min in air atmosphere first and then smelting with 14.4 wt% waste cathode carbon and 25 wt% CaO for 180 min in high purity Ar atmosphere at 1450 °C, the recovery rates of Cu and Fe reach 95.89% and 94.64%, respectively, and meanwhile greater than 90% of the fluoride from waste cathode carbon is transferred into the final slag as CaF2 and Ca2Si2F2O7, which makes the content of soluble F in the slag meet the national emission standard. Besides, the sulphur content in the obtained Fe-Cu alloy is low to 0.03 wt%.
Author Mao, Kai-xuan
Li, Lei
Xu, Miao
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  organization: State Key Laboratory of Complex Non-ferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction of Ministry of Education, Kunming University of Science and Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology
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  fullname: Xu, Miao
  organization: State Key Laboratory of Complex Non-ferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Engineering Research Center of Metallurgical Energy Conservation and Emission Reduction of Ministry of Education, Kunming University of Science and Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology
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Issue 7
Keywords copper slags
waste cathode carbon
iron and copper recovery
氟化物
废阴极碳
铜渣
氧化脱硫
fluoride
铁和铜的回收
oxidative desulfurization
smelting reduction
熔融还原
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Snippet To recover metal from copper slags, a new process involving two steps of oxidative desulfurization followed by smelting reduction was proposed in which one...
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SubjectTerms Aluminum
Carbon
Cathodes
Copper
Electrolysis
Emission standards
Engineering
Ferrous alloys
Fluxing
Hazardous wastes
Iron
Melting points
Metallic Materials
Metallurgy
Recovery
Reducing agents
Slag
Smelting reduction
Title Iron and copper recovery from copper slags through smelting with waste cathode carbon from aluminium electrolysis
URI https://link.springer.com/article/10.1007/s11771-021-4749-z
https://www.proquest.com/docview/2573868334
Volume 28
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