New Catalytic Systems Based on Pd(0) Complexes for Addition Polymerization of Norbornene

Addition polynorbornenes are the promising class of polymers for macromolecular design of various engineering polymers. This work has shown for the first time the fundamental possibility to obtain addition polynorbornenes in the presence of catalytic systems based on Pd(0) complexes activated by org...

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Bibliographic Details
Published inDoklady. Chemistry Vol. 495; no. 2; pp. 195 - 198
Main Authors Karpov, G. O., Bermeshev, M. V.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.12.2020
Springer Nature B.V
Subjects
Addition polymerization
Aromatic compounds
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Halides
Industrial Chemistry/Chemical Engineering
Polymerization
Polymers
Polynorbornene
norbornene
addition polymerization
Pd complexes
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Summary:Addition polynorbornenes are the promising class of polymers for macromolecular design of various engineering polymers. This work has shown for the first time the fundamental possibility to obtain addition polynorbornenes in the presence of catalytic systems based on Pd(0) complexes activated by organic cocatalysts (aryl halides). Addition polymerization of norbornene has been studied in the presence of different cocatalysts, which allowed one to assess the effect of cocatalyst nature on the activity of the catalytic system.
ISSN:0012-5008
1608-3113
DOI:10.1134/S0012500820120046