Synthesis and Comparative Study of the Microstructure and Properties of LiNbO3 and LiNbO3:Zn Ceramics Manufactured by Sol–Gel Processes
The manufacture of LiNbO 3 and LiNbO 3 :Zn fine-grained powders by two variants of the sol–gel process was studied. The microstructure, mechanical and electric properties of LiNbO 3 and LiNbO 3 :Zn ceramics prepared from powders of various origins were studied. The ceramics prepared from powders tha...
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| Published in | Russian journal of inorganic chemistry Vol. 64; no. 5; pp. 673 - 679 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Moscow
Pleiades Publishing
01.05.2019
Springer Nature B.V |
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| Abstract | The manufacture of LiNbO
3
and LiNbO
3
:Zn fine-grained powders by two variants of the sol–gel process was studied. The microstructure, mechanical and electric properties of LiNbO
3
and LiNbO
3
:Zn ceramics prepared from powders of various origins were studied. The ceramics prepared from powders that had been fractionated by elutriation had uniform micro- and submicrostructure, improved strength characteristics, and ionic grain-boundary conductivity. Doping LiNbO
3
with Zn
2+
reduced the electronic conductivity of LiNbO
3
:Zn ceramics, and this allowed the ceramics to be efficiently polarized and their piezoelectric properties to be improved. |
|---|---|
| AbstractList | The manufacture of LiNbO3 and LiNbO3:Zn fine-grained powders by two variants of the sol–gel process was studied. The microstructure, mechanical and electric properties of LiNbO3 and LiNbO3:Zn ceramics prepared from powders of various origins were studied. The ceramics prepared from powders that had been fractionated by elutriation had uniform micro- and submicrostructure, improved strength characteristics, and ionic grain-boundary conductivity. Doping LiNbO3 with Zn2+ reduced the electronic conductivity of LiNbO3:Zn ceramics, and this allowed the ceramics to be efficiently polarized and their piezoelectric properties to be improved. The manufacture of LiNbO 3 and LiNbO 3 :Zn fine-grained powders by two variants of the sol–gel process was studied. The microstructure, mechanical and electric properties of LiNbO 3 and LiNbO 3 :Zn ceramics prepared from powders of various origins were studied. The ceramics prepared from powders that had been fractionated by elutriation had uniform micro- and submicrostructure, improved strength characteristics, and ionic grain-boundary conductivity. Doping LiNbO 3 with Zn 2+ reduced the electronic conductivity of LiNbO 3 :Zn ceramics, and this allowed the ceramics to be efficiently polarized and their piezoelectric properties to be improved. |
| Author | Efremov, V. V. Vladimirova, S. V. Palatnikov, M. N. Masloboeva, S. M. Ivanenko, D. V. Shcherbina, O. B. |
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| References_xml | – volume-title: Syntheses of Ferroelectric and Luminescent Complex Oxides of Rare Earths year: 2009 ident: 1799_CR5 contributor: fullname: V I Ivanenko – volume-title: Handbook of Analytical Chemistry year: 1979 ident: 1799_CR11 contributor: fullname: Yu Yu Lur’e – volume: 77 start-page: 565 year: 2010 ident: 1799_CR10 publication-title: J. Opt. Technol. doi: 10.1364/JOT.77.000565 contributor: fullname: S G Garanin – volume-title: Principles and Application of Ferroelectrics and Related Materials year: 1977 ident: 1799_CR1 contributor: fullname: M E Lines – volume: 7 start-page: 129 year: 1982 ident: 1799_CR16 publication-title: Solid State Ionics doi: 10.1016/0167-2738(82)90006-6 contributor: fullname: Y-T Tsai – volume: 14 start-page: 2427 year: 2012 ident: 1799_CR20 publication-title: J. Phys. Chem. doi: 10.1039/C2CP23548J contributor: fullname: J Rahn – volume-title: Dielectric Relaxation in Solids year: 1983 ident: 1799_CR17 contributor: fullname: A K Jonscher – volume: 311 start-page: 1553 year: 2009 ident: 1799_CR21 publication-title: J. Cryst. Growth doi: 10.1016/j.jcrysgro.2008.09.178 contributor: fullname: H Kimura – volume: 53 start-page: 573 year: 2008 ident: 1799_CR7 publication-title: Crystallog. Repts. doi: 10.1134/S106377450804007X contributor: fullname: T S Chernaya – volume-title: Lithium Niobate and Lithium Tantalates—Nonlinear Optical Materials year: 1975 ident: 1799_CR2 contributor: fullname: Yu S Kuz’minov – volume-title: Lithium Niobate: Defects, Photorefraction, Vibrational Spectrum, Polaritons year: 2003 ident: 1799_CR3 contributor: fullname: N V Sidorov – start-page: 239 volume-title: Physicochemical Aspects of Studies into Clusters, Nanostructures, and Nanomaterials. Collected Works year: 2016 ident: 1799_CR12 contributor: fullname: S M Masloboeva – volume-title: Diagnostics of Metal Powders year: 1983 ident: 1799_CR13 doi: 10.1557/JMR.1992.1564 contributor: fullname: V Ya Bulanov – start-page: 1978 volume-title: Physics of Electrolytes: Transport Processes in Solid Electrolytes and in Electrodes year: 1972 ident: 1799_CR18 contributor: fullname: J Hladik – volume: 6 start-page: 1564 year: 1992 ident: 1799_CR14 publication-title: J. Mater. Res. doi: 10.1557/JMR.1992.1564 contributor: fullname: WC Oliver – volume: 52 start-page: 147 year: 2016 ident: 1799_CR22 publication-title: Inorg. Mater. doi: 10.1134/S0020168516020114 contributor: fullname: M N Palatnikov – volume: 11 start-page: 4 year: 2003 ident: 1799_CR9 publication-title: Priroda contributor: fullname: V I Simonov – volume: 104 start-page: 15290 year: 2014 ident: 1799_CR4 publication-title: Appl. Phys. Lett. doi: 10.1063/1.4871707 contributor: fullname: F Wang – volume: 1 start-page: 134 year: 2004 ident: 1799_CR15 publication-title: Prib. Tekh. Eksp. contributor: fullname: A S Useinov – volume: 100 start-page: 3703 year: 2017 ident: 1799_CR6 publication-title: J. Am. Ceram. Soc. doi: 10.1111/jace.14851 contributor: fullname: M N Palatnikov – volume: 95 start-page: 3116 year: 2004 ident: 1799_CR19 publication-title: J. Appl. Phys. doi: 10.1063/1.1647263 contributor: fullname: G T Niitsu – volume: 51 start-page: 397 year: 1990 ident: 1799_CR8 publication-title: J. Phys. Chem. Solids doi: 10.1016/0022-3697(90)90173-D contributor: fullname: H Feng |
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| Snippet | The manufacture of LiNbO
3
and LiNbO
3
:Zn fine-grained powders by two variants of the sol–gel process was studied. The microstructure, mechanical and electric... The manufacture of LiNbO3 and LiNbO3:Zn fine-grained powders by two variants of the sol–gel process was studied. The microstructure, mechanical and electric... |
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| SubjectTerms | Ceramic powders Ceramics Chemistry Chemistry and Materials Science Comparative studies Electric properties Elutriation Inorganic Chemistry Inorganic Materials and Nanomaterials Lithium niobates Microstructure Piezoelectricity Properties (attributes) Sol-gel processes |
| Title | Synthesis and Comparative Study of the Microstructure and Properties of LiNbO3 and LiNbO3:Zn Ceramics Manufactured by Sol–Gel Processes |
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