Sorption of Metal Ions from Aqueous Solutions by Humic Substances
Humic substances (HSs) extracted from brown coal, peat, and other sources are considered as an efficient and affordable sorbent used to trap and bind heavy metal ions, which are hazardous to the environment. This paper provides an overview of modern works on this subject matter. Typical structural c...
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| Published in | Solid fuel chemistry Vol. 57; no. 5; pp. 297 - 306 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Moscow
Pleiades Publishing
01.10.2023
Springer Nature B.V |
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| Abstract | Humic substances (HSs) extracted from brown coal, peat, and other sources are considered as an efficient and affordable sorbent used to trap and bind heavy metal ions, which are hazardous to the environment. This paper provides an overview of modern works on this subject matter. Typical structural characteristics and properties of HSs and methods for their extraction from brown coal, peat, swamp waters, and other media are described, and quantitative results of a wide range of experiments on the sorption of metal ions by HSs are presented. Significant fluctuations in the measured sorption capacity of HSs in different experiments probably arise not so much due to variations in the elemental composition and structure of HSs extracted from different sources, but they are associated with experimental conditions, such as the acidity (pH) of solution, ionic strength, concentration of metal ions, and concentration of HSs in the solution. In terms of the order of magnitude, the maximum sorption capacity of HSs is comparable to the total concentration of surface carboxyl and hydroxyl groups, and it amounts to several millimoles of metal ions per gram of HSs. |
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| AbstractList | Humic substances (HSs) extracted from brown coal, peat, and other sources are considered as an efficient and affordable sorbent used to trap and bind heavy metal ions, which are hazardous to the environment. This paper provides an overview of modern works on this subject matter. Typical structural characteristics and properties of HSs and methods for their extraction from brown coal, peat, swamp waters, and other media are described, and quantitative results of a wide range of experiments on the sorption of metal ions by HSs are presented. Significant fluctuations in the measured sorption capacity of HSs in different experiments probably arise not so much due to variations in the elemental composition and structure of HSs extracted from different sources, but they are associated with experimental conditions, such as the acidity (pH) of solution, ionic strength, concentration of metal ions, and concentration of HSs in the solution. In terms of the order of magnitude, the maximum sorption capacity of HSs is comparable to the total concentration of surface carboxyl and hydroxyl groups, and it amounts to several millimoles of metal ions per gram of HSs. |
| Author | Smirnov, V. G. Zherebtsov, S. I. Ismagilov, Z. R. Malyshenko, N. V. |
| Author_xml | – sequence: 1 givenname: Z. R. surname: Ismagilov fullname: Ismagilov, Z. R. organization: Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences – sequence: 2 givenname: V. G. surname: Smirnov fullname: Smirnov, V. G. email: smirnovvg@mail.ru organization: Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences – sequence: 3 givenname: N. V. surname: Malyshenko fullname: Malyshenko, N. V. email: profkemsc@yandex.ru organization: Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences – sequence: 4 givenname: S. I. surname: Zherebtsov fullname: Zherebtsov, S. I. email: sizh@yandex.ru organization: Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences |
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| Cites_doi | 10.15372/KhUR2022410 10.1016/j.msec.2015.12.001 10.1016/s0039-9140(00)00606-8 10.1021/la0363231 10.1016/j.desal.2010.01.006 10.1016/j.orggeochem.2008.05.007 10.1007/s11356-018-1836-2 10.1016/j.marenvres.2007.06.001 10.1590/S0103-50532010001200018 10.1016/j.molstruc.2022.132766 10.1039/b206352b 10.1016/S0043-1354(98)00263-2 10.1007/s11356-010-0322-2 10.3103/S0361521910020023 10.1016/j.jhazmat.2008.03.136 10.1021/es00086a012 10.1021/es060742d 10.1016/S0378-3820(02)00246-1 10.1021/es0010251 10.1016/j.jhazmat.2014.07.039 10.15372/KhUR20150415 10.1016/j.geoderma.2004.10.006 10.1016/j.scitotenv.2018.04.176 10.1016/S0048-9697(97)00141-1 10.1016/j.molliq.2022.120875 10.15372/KhUR20160316 10.1016/j.geoderma.2005.12.003 10.1289/ehp.8983191 10.3103/S0361521915050110 10.2136/sssaj1977.03615995004100020037x |
| ContentType | Journal Article |
| Copyright | Allerton Press, Inc. 2023. ISSN 0361-5219, Solid Fuel Chemistry, 2023, Vol. 57, No. 5, pp. 297–306. © Allerton Press, Inc., 2023. Russian Text © The Author(s), 2023, published in Khimiya Tverdogo Topliva, 2023, No. 5, pp. 5–14. |
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| Keywords | fulvic acids humic acids humic substances heavy metal ions sorption |
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| Title | Sorption of Metal Ions from Aqueous Solutions by Humic Substances |
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