Polarographic redox potentials of diazotized polycyclic aromatic amines and the absolute electrode potentials
The half-wave potentials (E 1/2 ) of polycyclic diazonium salts as well as those of the parent hydrocarbons, the corresponding aldehydes, and the nitro compounds, when plotted against the coefficient of the energy of either the lowest vacant orbital − m m −1 or the coefficient of the highest occupie...
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| Published in | Canadian journal of chemistry Vol. 62; no. 9; pp. 1772 - 1775 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English French |
| Published |
Ottawa, Canada
NRC Research Press
01.09.1984
National Research Council of Canada |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The half-wave potentials (E
1/2
) of polycyclic diazonium salts as well as those of the parent hydrocarbons, the corresponding aldehydes, and the nitro compounds, when plotted against the coefficient of the energy of either the lowest vacant orbital
−
m
m
−1
or the coefficient of the highest occupied orbital +m
m
of the parent hydrocarbon tend toward the midpoint potential, E
m
, equal to −0.31 V vs. sce as established by Parker. The polarographic results are correlated with
13
C nmr results with comments on solvation energies. |
|---|---|
| AbstractList | The half-wave potentials (E
1/2
) of polycyclic diazonium salts as well as those of the parent hydrocarbons, the corresponding aldehydes, and the nitro compounds, when plotted against the coefficient of the energy of either the lowest vacant orbital
−
m
m
−1
or the coefficient of the highest occupied orbital +m
m
of the parent hydrocarbon tend toward the midpoint potential, E
m
, equal to −0.31 V vs. sce as established by Parker. The polarographic results are correlated with
13
C nmr results with comments on solvation energies. |
| Abstract_FL | On a dressé un graphique mettant en opposition d'une part les potentiels à demi-vague (E
1/2
) de sels de diazonium de dérivés polycycliques, de leurs hydrocarbures, des aldéhydes et des dérivés nitro correspondants et d'autre part le coefficient de l'énergie soit de l'orbitale basse vacante (
−
m
m
−1
) ou le coefficient de l'orbitale haute occupée (+m
m
) de l'hydrocarbure de base. Ces courbes tendent vers un potentiel à mi-point, E
m
, qui est égal à −0,31 V vs. sce tel qu'établi par Parker. On peut établir une corrélation entre les résultats polarographiques et les résultats de rmn du
13
C qui reflète sur les énergies de solvatation. [Traduit par le journal] |
| Author | Laidler, James K Elofson, Richard M Gadallah, Fahmi F Schulz, Karlo F |
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| Issue | 9 |
| Keywords | MO method Half wave potential Chemical shift Electrochemical properties Polarography Bicyclic compound Diazonium compounds Redox potential Tricyclic compound NMR spectrum Condensed benzenic compound Electrode potential |
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| Snippet | The half-wave potentials (E
1/2
) of polycyclic diazonium salts as well as those of the parent hydrocarbons, the corresponding aldehydes, and the nitro... |
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| StartPage | 1772 |
| SubjectTerms | Chemistry Condensed benzenic and aromatic compounds Exact sciences and technology Organic chemistry Preparations and properties |
| Title | Polarographic redox potentials of diazotized polycyclic aromatic amines and the absolute electrode potentials |
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