Synthesis of Dimethyl Phenylphosphonates Catalyzed by Group VI Metal(0) Hexacarbonyls

The coupling of dimethyl phosphite and iodobenzene occurs in the presence of catalytic amounts of homoligand carbonyl complexes of chromium subgroup metals to form dimethyl phenylphosphonate in yields of 50–73% depending on the metal.

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Bibliographic Details
Published inRussian journal of organic chemistry Vol. 54; no. 11; pp. 1746 - 1748
Main Authors Kuramshin, A. I., Plotnikova, A. V., Adel’shina, M. V., Galkin, V. I.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.11.2018
Springer Nature B.V
Subjects
Carbonyls
Catalysis
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chromium
Coordination compounds
Organic Chemistry
Short Communications
Subgroups
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Summary:The coupling of dimethyl phosphite and iodobenzene occurs in the presence of catalytic amounts of homoligand carbonyl complexes of chromium subgroup metals to form dimethyl phenylphosphonate in yields of 50–73% depending on the metal.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428018110234