Electrochemical Properties of Tungsten in Molten Alkali Metal Chlorides
The anodic dissolution of metallic tungsten in the eutectic 3LiCl–2KCl (723–1023 K) and NaCl–2CsCl (823–1023 K) melts was studied by high-temperature electrochemistry and spectroscopy. W(IV) ions are formed in the melt. The conventional electrode potentials of tungsten were determined.
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| Published in | Russian metallurgy Metally Vol. 2019; no. 2; pp. 149 - 151 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Moscow
Pleiades Publishing
01.02.2019
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The anodic dissolution of metallic tungsten in the eutectic 3LiCl–2KCl (723–1023 K) and NaCl–2CsCl (823–1023 K) melts was studied by high-temperature electrochemistry and spectroscopy. W(IV) ions are formed in the melt. The conventional electrode potentials of tungsten were determined. |
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| AbstractList | The anodic dissolution of metallic tungsten in the eutectic 3LiCl–2KCl (723–1023 K) and NaCl–2CsCl (823–1023 K) melts was studied by high-temperature electrochemistry and spectroscopy. W(IV) ions are formed in the melt. The conventional electrode potentials of tungsten were determined. |
| Author | Ivanov, A. B. Volkovich, V. A. Ryzhov, A. A. |
| Author_xml | – sequence: 1 givenname: A. A. surname: Ryzhov fullname: Ryzhov, A. A. organization: Ural Federal University – sequence: 2 givenname: A. B. surname: Ivanov fullname: Ivanov, A. B. organization: Ural Federal University – sequence: 3 givenname: V. A. surname: Volkovich fullname: Volkovich, V. A. email: v.a.volkovich@urfu.ru organization: Ural Federal University |
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| Copyright | Pleiades Publishing, Ltd. 2019 Copyright Springer Nature B.V. 2019 |
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| Keywords | electrode potential chloride melt tungsten |
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| References | Shkol’nikov, Mannenkov, Yarmo-lovich (CR3) 1973; 46 CR2 CR4 Danilov, Volkovich, Vasin, Polovov, Griffiths (CR1) 2007; 62 Ivanov, Volkovich, Poskryakov, Vasin, Griffiths (CR5) 2016; 1767 D. A. Danilov (10143_CR1) 2007; 62 10143_CR2 S. N. Shkol’nikov (10143_CR3) 1973; 46 A. B. Ivanov (10143_CR5) 2016; 1767 10143_CR4 |
| References_xml | – volume: 62 start-page: 739 year: 2007 end-page: 744 ident: CR1 article-title: Tungsten chemistry in alkali chloride melts publication-title: Z. Naturforsch. A doi: 10.1515/zna-2007-1211 contributor: fullname: Griffiths – volume: 1767 start-page: 020010 year: 2016 ident: CR5 article-title: Electrode potentials of tungsten in fused alkali chlorides publication-title: AIP Conf. Proceed. doi: 10.1063/1.4962594 contributor: fullname: Griffiths – ident: CR4 – ident: CR2 – volume: 46 start-page: 1918 year: 1973 end-page: 1921 ident: CR3 article-title: Equilibrium potentials of tungsten in the melt of sodium and potassium chlorides publication-title: ZhPKh contributor: fullname: Yarmo-lovich – volume: 1767 start-page: 020010 year: 2016 ident: 10143_CR5 publication-title: AIP Conf. Proceed. doi: 10.1063/1.4962594 contributor: fullname: A. B. Ivanov – volume: 62 start-page: 739 year: 2007 ident: 10143_CR1 publication-title: Z. Naturforsch. A doi: 10.1515/zna-2007-1211 contributor: fullname: D. A. Danilov – ident: 10143_CR4 – volume: 46 start-page: 1918 year: 1973 ident: 10143_CR3 publication-title: ZhPKh contributor: fullname: S. N. Shkol’nikov – ident: 10143_CR2 |
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| Snippet | The anodic dissolution of metallic tungsten in the eutectic 3LiCl–2KCl (723–1023 K) and NaCl–2CsCl (823–1023 K) melts was studied by high-temperature... |
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| SubjectTerms | Alkali metals Anodic dissolution Chemistry and Materials Science Dissolution Electrochemical analysis Electrochemistry High temperature Materials Science Melts Metal chlorides Metallic Materials Tungsten |
| Title | Electrochemical Properties of Tungsten in Molten Alkali Metal Chlorides |
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