Homeotropic Alignment and Selective Adsorption of Nanoporous Polymer Film Polymerized from Hydrogen-bonded Liquid Crystal

Nanoporous polymer film with a hexagonal columnar (Col h ) structure was fabricated by templated hydrogen-bonding discotic liquid crystals containing methacrylate functional group. The supramolecular hydrogen-bonded complex T3Ph-L is composed of a 1,3,5-tris(1 H -benzo[ d ]imidazol-2-yl)benzene (T3P...

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Published inChinese journal of polymer science Vol. 38; no. 11; pp. 1185 - 1191
Main Authors Xiao, An-Qi, Lyu, Xiao-Lin, Pan, Hong-Bing, Tang, Zhe-Hao, Zhang, Wei, Shen, Zhi-Hao, Fan, Xing-He
Format Journal Article
LanguageEnglish
Published Beijing Chinese Chemical Society and Institute of Chemistry, CAS 01.11.2020
Springer Nature B.V
Subjects
Alignment
Benzene
Benzoic acid
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Columnar structure
Condensed Matter Physics
Crosslinking
Crystal structure
Functional groups
Hydrogen
Hydrogen bonding
Industrial Chemistry/Chemical Engineering
Liquid crystals
Molecular structure
Nanofiltration
Polymer films
Polymer Sciences
Polymers
Porosity
Selective adsorption
Self-assembly
Liquid crystal
Homeotropic alignment
Hydrogen bonding
Nanoporous polymer film
Selective adsorption
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Abstract Nanoporous polymer film with a hexagonal columnar (Col h ) structure was fabricated by templated hydrogen-bonding discotic liquid crystals containing methacrylate functional group. The supramolecular hydrogen-bonded complex T3Ph-L is composed of a 1,3,5-tris(1 H -benzo[ d ]imidazol-2-yl)benzene (T3Ph) core molecule as the hydrogen-bonding acceptor and 3,4,5-tris((11-(methacryloyloxy)undecyl)oxy)benzoic acid (L) peripheral molecules as donors. And the Col h structure is always retained after self-assembly, photo-crosslinking, and removal of the template T3Ph. The nanoporous polymer film can retain the Col h phase even under the dry condition, which indicates more possibilities for practical applications. After chemical modification of the inner wall of the nanopores, the nanoporous polymer film with pores of about 1 nm selectively adsorbs ionic dyes, and the adsorption process is spontaneous and exothermic in nature. Homeotropic alignment can be obtained when the blend complex was sandwiched between two modified glasses after annealing by slow cooling, which shows that the nanoporous polymer film has potential in applications such as nanofiltration.
AbstractList Nanoporous polymer film with a hexagonal columnar (Colh) structure was fabricated by templated hydrogen-bonding discotic liquid crystals containing methacrylate functional group. The supramolecular hydrogen-bonded complex T3Ph-L is composed of a 1,3,5-tris(1H-benzo[d]imidazol-2-yl)benzene (T3Ph) core molecule as the hydrogen-bonding acceptor and 3,4,5-tris((11-(methacryloyloxy)undecyl)oxy)benzoic acid (L) peripheral molecules as donors. And the Colh structure is always retained after self-assembly, photo-crosslinking, and removal of the template T3Ph. The nanoporous polymer film can retain the Colh phase even under the dry condition, which indicates more possibilities for practical applications. After chemical modification of the inner wall of the nanopores, the nanoporous polymer film with pores of about 1 nm selectively adsorbs ionic dyes, and the adsorption process is spontaneous and exothermic in nature. Homeotropic alignment can be obtained when the blend complex was sandwiched between two modified glasses after annealing by slow cooling, which shows that the nanoporous polymer film has potential in applications such as nanofiltration.
Nanoporous polymer film with a hexagonal columnar (Col h ) structure was fabricated by templated hydrogen-bonding discotic liquid crystals containing methacrylate functional group. The supramolecular hydrogen-bonded complex T3Ph-L is composed of a 1,3,5-tris(1 H -benzo[ d ]imidazol-2-yl)benzene (T3Ph) core molecule as the hydrogen-bonding acceptor and 3,4,5-tris((11-(methacryloyloxy)undecyl)oxy)benzoic acid (L) peripheral molecules as donors. And the Col h structure is always retained after self-assembly, photo-crosslinking, and removal of the template T3Ph. The nanoporous polymer film can retain the Col h phase even under the dry condition, which indicates more possibilities for practical applications. After chemical modification of the inner wall of the nanopores, the nanoporous polymer film with pores of about 1 nm selectively adsorbs ionic dyes, and the adsorption process is spontaneous and exothermic in nature. Homeotropic alignment can be obtained when the blend complex was sandwiched between two modified glasses after annealing by slow cooling, which shows that the nanoporous polymer film has potential in applications such as nanofiltration.
Author Lyu, Xiao-Lin
Tang, Zhe-Hao
Xiao, An-Qi
Zhang, Wei
Fan, Xing-He
Shen, Zhi-Hao
Pan, Hong-Bing
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Issue 11
Keywords Liquid crystal
Homeotropic alignment
Hydrogen bonding
Nanoporous polymer film
Selective adsorption
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Snippet Nanoporous polymer film with a hexagonal columnar (Col h ) structure was fabricated by templated hydrogen-bonding discotic liquid crystals containing...
Nanoporous polymer film with a hexagonal columnar (Colh) structure was fabricated by templated hydrogen-bonding discotic liquid crystals containing...
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SubjectTerms Alignment
Benzene
Benzoic acid
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Columnar structure
Condensed Matter Physics
Crosslinking
Crystal structure
Functional groups
Hydrogen
Hydrogen bonding
Industrial Chemistry/Chemical Engineering
Liquid crystals
Molecular structure
Nanofiltration
Polymer films
Polymer Sciences
Polymers
Porosity
Selective adsorption
Self-assembly
Title Homeotropic Alignment and Selective Adsorption of Nanoporous Polymer Film Polymerized from Hydrogen-bonded Liquid Crystal
URI https://link.springer.com/article/10.1007/s10118-020-2431-9
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