Tribological Behavior of Film Forming Organosilane/-Siloxane Oil Additives: Film Characterization and Influences on Lubrication
Vinyltrimethoxysilane monomer and oligomer film former were investigated as oil additives in terms of their tribological as well as their tribochemical behavior. The additives were dissolved in mineral oil and tested in different tribometers to evaluate the influences on friction, wear, lubricating...
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Published in | Tribology letters Vol. 68; no. 1; pp. 1 - 11 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
New York
Springer US
01.03.2020
Springer Nature B.V |
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Abstract | Vinyltrimethoxysilane monomer and oligomer film former were investigated as oil additives in terms of their tribological as well as their tribochemical behavior. The additives were dissolved in mineral oil and tested in different tribometers to evaluate the influences on friction, wear, lubricating film thickness and to track the film formation. The obtained reaction films from the friction tests were analyzed upon their morphology and chemical structure. It was found that organosilane/-siloxane molecules can deposit in a multi-layered film architecture, consisting of a polymeric layer on top of a glass-like coating. The glass-like tribofilm is adhesive, while the polymeric layer is weakly cross-linked and viscous. Depending on film structure, friction and wear can be reduced by more than 40%. |
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AbstractList | Vinyltrimethoxysilane monomer and oligomer film former were investigated as oil additives in terms of their tribological as well as their tribochemical behavior. The additives were dissolved in mineral oil and tested in different tribometers to evaluate the influences on friction, wear, lubricating film thickness and to track the film formation. The obtained reaction films from the friction tests were analyzed upon their morphology and chemical structure. It was found that organosilane/-siloxane molecules can deposit in a multi-layered film architecture, consisting of a polymeric layer on top of a glass-like coating. The glass-like tribofilm is adhesive, while the polymeric layer is weakly cross-linked and viscous. Depending on film structure, friction and wear can be reduced by more than 40%. |
ArticleNumber | 5 |
Author | Wilkens, Roland Hagemann, Michael Juretzka, Benjamin Kolb, Robert Riedel, Ralf Wieber, Stephan |
Author_xml | – sequence: 1 givenname: Benjamin orcidid: 0000-0003-1065-9864 surname: Juretzka fullname: Juretzka, Benjamin email: Juretzka@materials.tu-darmstadt.de organization: Fachgebiet Disperse Feststoffe, Fachbereich Material und Geowissenschaften, Technische Universität Darmstadt, Evonik Resource Efficiency GmbH, Oil Additives – sequence: 2 givenname: Stephan surname: Wieber fullname: Wieber, Stephan organization: Evonik Resource Efficiency GmbH, Oil Additives – sequence: 3 givenname: Roland surname: Wilkens fullname: Wilkens, Roland organization: Evonik Resource Efficiency GmbH, Oil Additives – sequence: 4 givenname: Michael surname: Hagemann fullname: Hagemann, Michael organization: Evonik Resource Efficiency GmbH, Oil Additives – sequence: 5 givenname: Robert surname: Kolb fullname: Kolb, Robert organization: Evonik Resource Efficiency GmbH, Oil Additives – sequence: 6 givenname: Ralf surname: Riedel fullname: Riedel, Ralf organization: Fachgebiet Disperse Feststoffe, Fachbereich Material und Geowissenschaften, Technische Universität Darmstadt |
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CitedBy_id | crossref_primary_10_1007_s11249_020_01342_5 crossref_primary_10_1016_j_fuel_2021_121555 crossref_primary_10_1016_j_matchemphys_2021_124973 crossref_primary_10_1016_j_surfcoat_2022_128092 crossref_primary_10_1007_s11249_023_01728_1 |
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Snippet | Vinyltrimethoxysilane monomer and oligomer film former were investigated as oil additives in terms of their tribological as well as their tribochemical... |
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SubjectTerms | Adhesive strength Chemistry and Materials Science Corrosion and Coatings Crosslinking Film thickness Friction Glass Lubrication Materials Science Mineral oils Morphology Multilayers Nanotechnology Oil additives Organic chemistry Original Paper Physical Chemistry Siloxanes Surfaces and Interfaces Theoretical and Applied Mechanics Thin Films Tribology Tribometers Wear |
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Title | Tribological Behavior of Film Forming Organosilane/-Siloxane Oil Additives: Film Characterization and Influences on Lubrication |
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