Ultrasensitive methyl salicylate gas sensing determined by Pd-doped SnO2

• Published in: Frontiers of materials science Vol. 16; no. 4
• Main Authors: Zhu, Chaoqi, Li, Xiang, Wang, Xiaoxia, Su, Huiyu, Ma, Chaofan, Guo, Xiang, Xie, Changsheng, Zeng, Dawen
• Format: Journal Article
• Language: English
• Published: Beijing Higher Education Press 01.12.2022; Springer Nature B.V
• Subjects: Chemical warfare; Gas sensors; Materials Science; Nanoparticles; Noble metals; Palladium; Research Article; Sensors; Terrorism; Tin dioxide; methyl salicylate; gas sensor; SnO; Pd doping; noble metal
• ISSN: 2095-025X; 2095-0268
• DOI: 10.1007/s11706-022-0625-5

Efficient chemical warfare agents (CWAs) detection is required to protect people from the CWAs in war and terrorism. In this work, a Pd-doped SnO 2 nanoparticles-based gas sensor was developed to detect a nerve agent simulant named methyl salicylate. The sensing measurements of methyl salicylate under different Pd doping amounts found that the 0.5 at.% Pd-doped SnO 2 exhibited a significant improvement in the detection of methyl salicylate at the ppb (1 ppb = 10 −9 ) level, and the response value to 160 ppb methyl salicylate is 0.72 at 250 °C. Compared with the pure SnO 2 , the response value is increased by 4.5 times, which could be attributed to the influence of the noble metal Pd on the oxygen state and its catalytic effect. In addition, the 0.5 at.% Pd-doped SnO 2 sensor still has an obvious response to 16 ppb methyl salicylate with a response value of 0.13, indicating the lower detection limit of the sensor.