Crystal growth and phase interaction studies in the Cu7GeS5I-Cu7SiS5I superionic system
Solid solutions of Cu7SiS5I-Cu7GeS5I system were synthesized using solid-phase reactions involving a technique specifically developed for the synthesis of ternary compounds that exhibit incongruent melting behaviour. Chemical interaction in the Cu7GeS5I-Cu7SiS5I system was studied by X-ray phase ana...
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| Published in | Journal of crystal growth Vol. 306; no. 2; pp. 326 - 329 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier
15.08.2007
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Solid solutions of Cu7SiS5I-Cu7GeS5I system were synthesized using solid-phase reactions involving a technique specifically developed for the synthesis of ternary compounds that exhibit incongruent melting behaviour. Chemical interaction in the Cu7GeS5I-Cu7SiS5I system was studied by X-ray phase analysis, microstructural analysis and density determination. Specific features of the energy gap and its compositional behaviour with Si- > Ge cation substitution in Cu7SiS5I-Cu7GeS5I solid solution system are reported. |
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| AbstractList | Solid solutions of Cu7SiS5I-Cu7GeS5I system were synthesized using solid-phase reactions involving a technique specifically developed for the synthesis of ternary compounds that exhibit incongruent melting behaviour. Chemical interaction in the Cu7GeS5I-Cu7SiS5I system was studied by X-ray phase analysis, microstructural analysis and density determination. Specific features of the energy gap and its compositional behaviour with Si- > Ge cation substitution in Cu7SiS5I-Cu7GeS5I solid solution system are reported. |
| Author | STUDENYAK, I. P KOKHAN, O. P PANKO, V. V KRANJCEC, M HRECHYN, M. I |
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| Cites_doi | 10.1016/0167-2738(87)90077-4 10.1103/PhysRevB.44.1613 10.1016/0025-5408(79)90125-9 10.1016/S0022-3697(99)00220-6 10.1103/PhysRevLett.51.662 10.1016/S0022-3697(01)00139-1 10.1103/PhysRevB.29.1882 10.1016/S0167-2738(96)00477-8 |
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| Keywords | Crystal growth Inorganic compounds Ternary compounds 81.10.Bk; 81.05.Hd Phase analysis Al. Solid solutions; A2. Growth from vapour; B1. Inorganic compounds Energy gap Solid solutions Growth mechanism Germanium Silicon Solid state crystal growth Microstructure Ionic crystals |
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| References | Kuhs (10.1016/j.jcrysgro.2007.05.029_bib1) 1979; 14 Jaffe (10.1016/j.jcrysgro.2007.05.029_bib10) 1984; 29 Stasyuk (10.1016/j.jcrysgro.2007.05.029_bib5) 1999; 4 Zunger (10.1016/j.jcrysgro.2007.05.029_bib9) 1983; 51 Studenyak (10.1016/j.jcrysgro.2007.05.029_bib2) 1997; 95 Studenyak (10.1016/j.jcrysgro.2007.05.029_bib3) 1999; 60 Studenyak (10.1016/j.jcrysgro.2007.05.029_bib7) 2001; 3 Tinoco (10.1016/j.jcrysgro.2007.05.029_bib8) 1991; 44 Studenyak (10.1016/j.jcrysgro.2007.05.029_bib6) 2002; 63 Laqibi (10.1016/j.jcrysgro.2007.05.029_bib4) 1987; 23 |
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| SubjectTerms | Cross-disciplinary physics: materials science; rheology Exact sciences and technology Growth from solid phases (including multiphase diffusion and recrystallization) Materials science Methods of crystal growth; physics of crystal growth Physics Theory and models of crystal growth; physics of crystal growth, crystal morphology and orientation |
| Title | Crystal growth and phase interaction studies in the Cu7GeS5I-Cu7SiS5I superionic system |
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