Room-Temperature Synthesis of Sn2P2S6
Twenty-nanometer particles of Sn2P2S6are prepared at room temperature (RT) via a metathesis reaction in aqueous media. Mössbauer and Raman spectroscopy and X-ray diffraction characterization of these powders accord with data on Sn2P2S6synthesized at high temperature (HT). The phase transition and se...
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| Published in | Journal of solid state chemistry Vol. 129; no. 1; pp. 157 - 159 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
San Diego, CA
Elsevier Inc
15.02.1997
Elsevier |
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| Abstract | Twenty-nanometer particles of Sn2P2S6are prepared at room temperature (RT) via a metathesis reaction in aqueous media. Mössbauer and Raman spectroscopy and X-ray diffraction characterization of these powders accord with data on Sn2P2S6synthesized at high temperature (HT). The phase transition and second harmonic generation known to exist in the HT form were not detected in the RT variant, suggesting a critical particle size >20 nm for the occurrence of polar order in Sn2P2S6. It is argued that thermal enhancement of the metathesis reaction and growth kinetics should lead to larger, ferroelectric Sn2P2S6crystallites. |
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| AbstractList | Twenty-nanometer particles of Sn2P2S6are prepared at room temperature (RT) via a metathesis reaction in aqueous media. Mössbauer and Raman spectroscopy and X-ray diffraction characterization of these powders accord with data on Sn2P2S6synthesized at high temperature (HT). The phase transition and second harmonic generation known to exist in the HT form were not detected in the RT variant, suggesting a critical particle size >20 nm for the occurrence of polar order in Sn2P2S6. It is argued that thermal enhancement of the metathesis reaction and growth kinetics should lead to larger, ferroelectric Sn2P2S6crystallites. |
| Author | Prouzet, E. Bourdon, X. Cajipe, V.B. |
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| Cites_doi | 10.4028/www.scientific.net/KEM.92-93.217 10.1016/S0022-4596(05)80262-2 10.1107/S0021889893001670 10.1016/0167-2738(88)90290-1 10.1016/0038-1098(94)90162-7 10.1021/cm00053a007 10.1016/0038-1098(93)90765-F 10.1021/cm950327c 10.1080/00150199408017608 10.1016/0022-3093(93)90278-6 10.1557/JMR.1992.1839 |
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| Keywords | Tin Thiophosphates Chemical preparation Room temperature |
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| References_xml | – volume: 19 start-page: 1165 year: 1977 ident: SC967244RF4 publication-title: Sov. Phys. Solid State contributor: fullname: Slivka – volume: 8 start-page: 226 year: 1996 ident: SC967244RF1 publication-title: Chem. Mater. contributor: fullname: Dutta – volume: 27 start-page: 525 year: 1985 ident: SC967244RF7A publication-title: Sov. Phys. Solid State contributor: fullname: Voroshilov – volume: 93 start-page: 217 year: 1994 ident: SC967244RF3A publication-title: Key Eng. Mater. contributor: fullname: Das-Gupta – volume: 96 start-page: 294 year: 1992 ident: SC967244RF5 publication-title: J. 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| Snippet | Twenty-nanometer particles of Sn2P2S6are prepared at room temperature (RT) via a metathesis reaction in aqueous media. Mössbauer and Raman spectroscopy and... |
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| SubjectTerms | Chemistry Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties Salts |
| Title | Room-Temperature Synthesis of Sn2P2S6 |
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