Stepwise dissolution of chalcopyrite bioleaching by thermophile A.manzaensis and mesophile L. ferriphilum
Chalcopyrite dissolution was evaluated by bioleaching and electrochemical experiments with thermophile A. manzaensis ( Acidianus manzaensis ) and mesophile L. ferriphilum ( Leptospirillum ferriphium ) cultures at 65 °C and 40 °C, respectively. It was investigated that the bioleaching of chalcopyrite...
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| Published in | Journal of Central South University Vol. 22; no. 10; pp. 3751 - 3759 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Changsha
Central South University
01.10.2015
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 2095-2899 2227-5223 |
| DOI | 10.1007/s11771-015-2919-6 |
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| Abstract | Chalcopyrite dissolution was evaluated by bioleaching and electrochemical experiments with thermophile
A. manzaensis
(
Acidianus manzaensis
) and mesophile
L. ferriphilum
(
Leptospirillum ferriphium
) cultures at 65 °C and 40 °C, respectively. It was investigated that the bioleaching of chalcopyrite was stepwise. It was reduced to Cu
2
S at a lower redox potential locating in the whole bioleaching process by
A. manzaensis
at high temperature while only at initial days of bioleaching by
L. ferriphilum
at a relative low temperature. No reduced product was detected when the redox potential was beyond a high level (e.g., 550 mV (vs SCE)) bioleached by
L. ferriphilum
. Chalcopyrite bioleaching efficiency was substantially improved bioleached by
A. manaensis
compared to that by
L. ferriphilum
, which was mainly attributed to the reduction reaction occurring during bioleaching. The reductive intermediate Cu
2
S was more amenable to oxidation than chalcopyrite, causing enhanced copper extraction. |
|---|---|
| AbstractList | Chalcopyrite dissolution was evaluated by bioleaching and electrochemical experiments with thermophile
A. manzaensis
(
Acidianus manzaensis
) and mesophile
L. ferriphilum
(
Leptospirillum ferriphium
) cultures at 65 °C and 40 °C, respectively. It was investigated that the bioleaching of chalcopyrite was stepwise. It was reduced to Cu
2
S at a lower redox potential locating in the whole bioleaching process by
A. manzaensis
at high temperature while only at initial days of bioleaching by
L. ferriphilum
at a relative low temperature. No reduced product was detected when the redox potential was beyond a high level (e.g., 550 mV (vs SCE)) bioleached by
L. ferriphilum
. Chalcopyrite bioleaching efficiency was substantially improved bioleached by
A. manaensis
compared to that by
L. ferriphilum
, which was mainly attributed to the reduction reaction occurring during bioleaching. The reductive intermediate Cu
2
S was more amenable to oxidation than chalcopyrite, causing enhanced copper extraction. |
| Author | Hu, Ke-ting Wang, Chong-qing Li, Shuang-ke Gu, Guo-hua Xiong, Xian-xue |
| Author_xml | – sequence: 1 givenname: Guo-hua surname: Gu fullname: Gu, Guo-hua organization: School of Mineral Processing and Bioengineering, Central South University – sequence: 2 givenname: Xian-xue surname: Xiong fullname: Xiong, Xian-xue email: xiongxianxue00@163.com organization: School of Mineral Processing and Bioengineering, Central South University – sequence: 3 givenname: Ke-ting surname: Hu fullname: Hu, Ke-ting organization: School of Mineral Processing and Bioengineering, Central South University – sequence: 4 givenname: Shuang-ke surname: Li fullname: Li, Shuang-ke organization: School of Mineral Processing and Bioengineering, Central South University – sequence: 5 givenname: Chong-qing surname: Wang fullname: Wang, Chong-qing organization: School of Chemistry and Chemical Engineering, Central South University |
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| Cites_doi | 10.1007/s12598-013-0114-1 10.1016/j.hydromet.2011.01.011 10.1016/j.hydromet.2011.03.008 10.1016/S0304-386X(03)00143-9 10.1016/j.hydromet.2008.04.016 10.1016/j.mineng.2007.10.018 10.1016/S0304-386X(00)00089-X 10.1016/j.hydromet.2010.10.001 10.1016/j.biortech.2008.03.003 10.1016/j.hydromet.2007.12.005 10.1016/j.electacta.2008.01.088 10.1007/s11837-005-0252-5 10.1007/s11771-012-1198-8 10.1016/j.hydromet.2010.10.012 10.1016/j.hydromet.2010.02.002 10.1016/S0301-7516(00)00056-9 10.1016/S0304-386X(97)00032-7 10.1016/0304-386X(96)00010-2 10.1016/0304-386X(85)90030-1 10.1016/S0892-6875(01)00208-4 10.1016/j.hydromet.2011.07.009 10.1007/s11771-013-1474-2 10.1016/j.mineng.2004.08.004 10.1016/S0304-386X(00)00155-9 10.1016/j.mineng.2010.11.008 10.1016/j.hydromet.2004.01.003 10.1016/j.apsusc.2003.10.030 10.1016/j.hydromet.2006.07.006 10.1016/S0301-7516(02)00004-2 |
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| Snippet | Chalcopyrite dissolution was evaluated by bioleaching and electrochemical experiments with thermophile
A. manzaensis
(
Acidianus manzaensis
) and mesophile
L.... |
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| SubjectTerms | Engineering Metallic Materials |
| Title | Stepwise dissolution of chalcopyrite bioleaching by thermophile A.manzaensis and mesophile L. ferriphilum |
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