ε-Caprolactone as a medium for improving dispersability of graphene oxide in polyamide based composites
[Display omitted] •ε-Caprolactone enhances dispersability of graphene oxide in ε-caprolactam melt.•Polyesteramide composites were prepared by in situ polymerization casting method.•Physical character of polymer-filler interactions was proved.•Presence of graphene oxide leads to an increase in tensil...
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| Published in | European polymer journal Vol. 91; pp. 212 - 220 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
01.06.2017
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| Abstract | [Display omitted]
•ε-Caprolactone enhances dispersability of graphene oxide in ε-caprolactam melt.•Polyesteramide composites were prepared by in situ polymerization casting method.•Physical character of polymer-filler interactions was proved.•Presence of graphene oxide leads to an increase in tensile modulus.
We described preparation of composites of graphene oxide with copolymers containing ε-caprolactam and ε-caprolactone structural units. Graphene oxide was prepared using modified Hummers method and characterized by elemental analysis and X-ray photoelectron spectroscopy measurements, interlayer distance was evaluated from X-ray diffraction. Two types of copolymers - polyesteramides - with molar ratio of ε-caprolactam to ε-caprolactone units in polymerization feed 80/20 and 90/10 were prepared by polymerization casting method. Graphene oxide content in both types of polyesteramides was in range from 0.1 to 1wt.%. Thermogravimetric analysis and differential scanning calorimetry were utilized to study thermal stability and crystallization behaviour of materials. Prepared composites were characterized by tensile modulus and impact strength. Rheological properties of polymer melts and viscometry of diluted polymer solutions revealed the physical character of polymer-filler interactions. |
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| AbstractList | [Display omitted]
•ε-Caprolactone enhances dispersability of graphene oxide in ε-caprolactam melt.•Polyesteramide composites were prepared by in situ polymerization casting method.•Physical character of polymer-filler interactions was proved.•Presence of graphene oxide leads to an increase in tensile modulus.
We described preparation of composites of graphene oxide with copolymers containing ε-caprolactam and ε-caprolactone structural units. Graphene oxide was prepared using modified Hummers method and characterized by elemental analysis and X-ray photoelectron spectroscopy measurements, interlayer distance was evaluated from X-ray diffraction. Two types of copolymers - polyesteramides - with molar ratio of ε-caprolactam to ε-caprolactone units in polymerization feed 80/20 and 90/10 were prepared by polymerization casting method. Graphene oxide content in both types of polyesteramides was in range from 0.1 to 1wt.%. Thermogravimetric analysis and differential scanning calorimetry were utilized to study thermal stability and crystallization behaviour of materials. Prepared composites were characterized by tensile modulus and impact strength. Rheological properties of polymer melts and viscometry of diluted polymer solutions revealed the physical character of polymer-filler interactions. |
| Author | Minář, Jaroslav Brožek, Jiří |
| Author_xml | – sequence: 1 givenname: Jaroslav surname: Minář fullname: Minář, Jaroslav email: minarj@vscht.cz – sequence: 2 givenname: Jiří surname: Brožek fullname: Brožek, Jiří email: Jiri.Brozek@vscht.cz |
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| CitedBy_id | crossref_primary_10_3390_polym10040357 crossref_primary_10_1016_j_colsurfa_2020_125668 crossref_primary_10_1021_acs_biomac_2c00150 crossref_primary_10_1088_1742_6596_2131_4_042020 crossref_primary_10_1016_j_matpr_2019_10_077 crossref_primary_10_1177_0892705719880942 crossref_primary_10_1016_j_aiepr_2018_06_003 crossref_primary_10_1016_j_matchemphys_2020_122807 crossref_primary_10_1016_j_compositesb_2019_107019 crossref_primary_10_1002_masy_201800009 crossref_primary_10_1016_j_surfin_2023_102747 |
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J. doi: 10.1016/j.eurpolymj.2007.10.026 contributor: fullname: Bernat – volume: 53 start-page: 38 year: 2013 ident: 10.1016/j.eurpolymj.2017.03.058_b0110 article-title: The chemical and structural analysis of graphene oxide with different degrees of oxidation publication-title: Carbon doi: 10.1016/j.carbon.2012.10.013 contributor: fullname: Krishnamoorthy – year: 2003 ident: 10.1016/j.eurpolymj.2017.03.058_b0060 article-title: Intercalation polymerization contributor: fullname: Duguet |
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•ε-Caprolactone enhances dispersability of graphene oxide in ε-caprolactam melt.•Polyesteramide composites were prepared by in situ... |
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| SubjectTerms | Composite Graphene oxide In situ intercalation polymerization Polyesteramide |
| Title | ε-Caprolactone as a medium for improving dispersability of graphene oxide in polyamide based composites |
| URI | https://dx.doi.org/10.1016/j.eurpolymj.2017.03.058 |
| Volume | 91 |
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