Preparation and transport properties of AgSbTe2 by high-pressure and high-temperature

In the paper, ternary thermoelectric material AgSbTe2 was prepared by high-pressure and high-temperature (HPHT) technique. Near single phase AgSbTe2 was obtained using normal stoichiometric powder mixtures which were indexed by powder X-ray diffraction. The dependence of transport properties for AgS...

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Published inJournal of alloys and compounds Vol. 454; no. 1-2; pp. 415 - 418
Main Authors Ma, Hongan, Su, Taichao, Zhu, Pinwen, Guo, Jiangang, Jia, Xiaopeng
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier 24.04.2008
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Abstract In the paper, ternary thermoelectric material AgSbTe2 was prepared by high-pressure and high-temperature (HPHT) technique. Near single phase AgSbTe2 was obtained using normal stoichiometric powder mixtures which were indexed by powder X-ray diffraction. The dependence of transport properties for AgSbTe2 on synthetic pressure was studied at room temperature. With the increase of synthetic pressure, the electrical resistivity and Seebeck coefficient of AgSbTe2 decrease while the power factor increases, and the maximum value reaches 10.3muWcm-1K-2 at the synthetic pressure of 5.2GPa. The results show that the HPHT offers to a potential processing route to produce single phase ternary thermoelectric material AgSbTe2, which is helpful to improve its thermoelectric properties.
AbstractList In the paper, ternary thermoelectric material AgSbTe2 was prepared by high-pressure and high-temperature (HPHT) technique. Near single phase AgSbTe2 was obtained using normal stoichiometric powder mixtures which were indexed by powder X-ray diffraction. The dependence of transport properties for AgSbTe2 on synthetic pressure was studied at room temperature. With the increase of synthetic pressure, the electrical resistivity and Seebeck coefficient of AgSbTe2 decrease while the power factor increases, and the maximum value reaches 10.3muWcm-1K-2 at the synthetic pressure of 5.2GPa. The results show that the HPHT offers to a potential processing route to produce single phase ternary thermoelectric material AgSbTe2, which is helpful to improve its thermoelectric properties.
Author PINWEN ZHU
JIANGANG GUO
HONGAN MA
TAICHAO SU
XIAOPENG JIA
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Issue 1-2
Keywords Electrical conductivity
Material processing
Seebeck effect
XRD
High temperature
High pressure
Thermoelectric materials
Antimony Silver Tellurides Mixed
High-temperature high-pressure
Thermoelectric power
Transport processes
Thermoelectric
AgSbTe2
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Snippet In the paper, ternary thermoelectric material AgSbTe2 was prepared by high-pressure and high-temperature (HPHT) technique. Near single phase AgSbTe2 was...
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SubjectTerms Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity phenomena in semiconductors and insulators
Electronic transport in condensed matter
Exact sciences and technology
Physics
Thermoelectric and thermomagnetic effects
Title Preparation and transport properties of AgSbTe2 by high-pressure and high-temperature
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