Design strategies of phosphorus-containing catalysts for photocatalytic, photoelectrochemical and electrocatalytic water splitting

Photocatalytic, photoelectrochemical and electrocatalytic water splitting provide advanced approaches to produce green hydrogen as a sustainable and renewable energy carrier. The development of highly efficient catalysts is the key to achieving cost-effective and large-scale production of hydrogen....

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Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 24; no. 2; pp. 713 - 747
Main Authors Chen, Lei, Ren, Jin-Tao, Yuan, Zhong-Yong
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 24.01.2022
Subjects
Catalysts
Catalytic activity
cost effectiveness
Design
Green chemistry
Green hydrogen
hydrogen
Hydrogen production
Interfaces
Phosphates
Phosphides
Phosphonates
Phosphorus
Photocatalysis
Physicochemical properties
Renewable energy
renewable energy sources
Splitting
Sustainable energy
Transition metals
Valence
Water splitting
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Abstract Photocatalytic, photoelectrochemical and electrocatalytic water splitting provide advanced approaches to produce green hydrogen as a sustainable and renewable energy carrier. The development of highly efficient catalysts is the key to achieving cost-effective and large-scale production of hydrogen. Recently, P-containing catalysts have gained a great deal of attention owing to their diverse chemical valence states, tunable structure and unique physicochemical properties. In this review, an overview of up-to-date progress in water splitting of P-containing photo- and electro-catalysts including elemental P, transition metal phosphides, metal phosphates/phosphonates and metal phosphorus trichalcogenides is provided. A general introduction to the water splitting mechanism and the activity origin of P-containing catalysts is briefly presented to provide rational guidance for the design of highly efficient catalysts. Notably, innovational strategies to design P-containing catalysts with enhanced catalytic activity are summarized with respect to modifying the phase, introducing foreign elements, tailoring morphology and engineering interfaces. In each section, we aim to deeply clarify the theory-structure-property relationship and provide underlying reasons behind enhanced catalytic performance. Finally, some challenges and research orientations of P-containing catalysts toward water splitting are briefly proposed from the perspectives of practical application and mechanism investigation. The innovational strategies to design P-containing catalysts with enhanced photo-/electro-catalytic water splitting activity are reviewed with respect to phase modifying, foreign elements introducing, morphology tailoring and interface engineering.
AbstractList Photocatalytic, photoelectrochemical and electrocatalytic water splitting provide advanced approaches to produce green hydrogen as a sustainable and renewable energy carrier. The development of highly efficient catalysts is the key to achieving cost-effective and large-scale production of hydrogen. Recently, P-containing catalysts have gained a great deal of attention owing to their diverse chemical valence states, tunable structure and unique physicochemical properties. In this review, an overview of up-to-date progress in water splitting of P-containing photo- and electro-catalysts including elemental P, transition metal phosphides, metal phosphates/phosphonates and metal phosphorus trichalcogenides is provided. A general introduction to the water splitting mechanism and the activity origin of P-containing catalysts is briefly presented to provide rational guidance for the design of highly efficient catalysts. Notably, innovational strategies to design P-containing catalysts with enhanced catalytic activity are summarized with respect to modifying the phase, introducing foreign elements, tailoring morphology and engineering interfaces. In each section, we aim to deeply clarify the theory–structure–property relationship and provide underlying reasons behind enhanced catalytic performance. Finally, some challenges and research orientations of P-containing catalysts toward water splitting are briefly proposed from the perspectives of practical application and mechanism investigation.
Photocatalytic, photoelectrochemical and electrocatalytic water splitting provide advanced approaches to produce green hydrogen as a sustainable and renewable energy carrier. The development of highly efficient catalysts is the key to achieving cost-effective and large-scale production of hydrogen. Recently, P-containing catalysts have gained a great deal of attention owing to their diverse chemical valence states, tunable structure and unique physicochemical properties. In this review, an overview of up-to-date progress in water splitting of P-containing photo- and electro-catalysts including elemental P, transition metal phosphides, metal phosphates/phosphonates and metal phosphorus trichalcogenides is provided. A general introduction to the water splitting mechanism and the activity origin of P-containing catalysts is briefly presented to provide rational guidance for the design of highly efficient catalysts. Notably, innovational strategies to design P-containing catalysts with enhanced catalytic activity are summarized with respect to modifying the phase, introducing foreign elements, tailoring morphology and engineering interfaces. In each section, we aim to deeply clarify the theory-structure-property relationship and provide underlying reasons behind enhanced catalytic performance. Finally, some challenges and research orientations of P-containing catalysts toward water splitting are briefly proposed from the perspectives of practical application and mechanism investigation. The innovational strategies to design P-containing catalysts with enhanced photo-/electro-catalytic water splitting activity are reviewed with respect to phase modifying, foreign elements introducing, morphology tailoring and interface engineering.
Author Ren, Jin-Tao
Chen, Lei
Yuan, Zhong-Yong
AuthorAffiliation School of Materials Science and Engineering
Nankai University
National Institute for Advanced Materials
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
AuthorAffiliation_xml – name: Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)
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  surname: Yuan
  fullname: Yuan, Zhong-Yong
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Notes Jin-Tao Ren received his Ph.D. degree from Nankai University in 2020 under the supervision of Prof. Zhong-Yong Yuan. He is currently a postdoctoral fellow at Nankai University. His research interests focus on advanced nanomaterials for applications in electrocatalysis, metal-air batteries, fuel cells
and as editorial board member of several journals. His research interests are mainly focused on the self-assembly of hierarchically nanoporous and nanostructured materials for energy and environmental applications.
etc
Lei Chen received her BEng degree from Northeast Forestry University in 2017 and obtained her MEng degree from Nankai University in 2020. She is currently a PhD candidate under the supervision of Prof. Zhong-Yong Yuan at Nankai University. Her current research focuses on the fabrication of nanostructured materials for energy-related applications.
RSC Advances
.
Zhong-Yong Yuan received his PhD degree from Nankai University in 1999. After his postdoctoral research at the Institute of Physics, Chinese Academy of Sciences, he joined the Laboratory of Inorganic Materials Chemistry at the University of Namur, Belgium in 2001. In 2005, he was appointed Professor in Nankai University. In 2006, he was awarded the "Program for New Century Excellent Talents in University" by the Ministry of Education. In 2016, he was elected as a fellow of the Royal Society of Chemistry. He is currently serving as an Associate Editor of
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  year: 2022
  text: 2022-01-24
  day: 24
PublicationDecade 2020
PublicationPlace Cambridge
PublicationPlace_xml – name: Cambridge
PublicationTitle Green chemistry : an international journal and green chemistry resource : GC
PublicationYear 2022
Publisher Royal Society of Chemistry
Publisher_xml – name: Royal Society of Chemistry
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Snippet Photocatalytic, photoelectrochemical and electrocatalytic water splitting provide advanced approaches to produce green hydrogen as a sustainable and renewable...
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SubjectTerms Catalysts
Catalytic activity
cost effectiveness
Design
Green chemistry
Green hydrogen
hydrogen
Hydrogen production
Interfaces
Phosphates
Phosphides
Phosphonates
Phosphorus
Photocatalysis
Physicochemical properties
Renewable energy
renewable energy sources
Splitting
Sustainable energy
Transition metals
Valence
Water splitting
Title Design strategies of phosphorus-containing catalysts for photocatalytic, photoelectrochemical and electrocatalytic water splitting
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