Redox induced oxidative C-C coupling of non-innocent bis(heterocyclo)methanides

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 5; no. 45; pp. 16647 - 16659
• Main Authors: Panda, Sanjib, Baliyan, Rupal, Dhara, Suman, Huang, Kuo-Wei, Lahiri, Goutam Kumar
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 23.11.2021
• Subjects: Coupling (molecular); Covalent bonds; Mathematical analysis; Oxygen; Oxygenation; Ruthenium

Redox driven C-C bond formation has gained recent attention over the traditional sequence of oxidative addition, insertion and reductive elimination reactions. In this regard, the transient radical mediated diverse reactivity profile of bis(heterocyclo)methanes (H-BHM: HL1-HL4) has been demonstrated...