Organo-macrocycle-containing hierarchical metal-organic frameworks and cages: design, structures, and applications
Developing hierarchical ordered systems is challenging. Using organo-macrocycles to construct metal-organic frameworks (MOFs) and porous coordination cages (PCCs) provides an efficient way to obtain hierarchical assemblies. Macrocycles, such as crown ethers, cyclodextrins, calixarenes, cucurbiturils...
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| Published in | Chemical Society reviews Vol. 51; no. 19; pp. 8378 - 845 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Royal Society of Chemistry
03.10.2022
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Developing hierarchical ordered systems is challenging. Using organo-macrocycles to construct metal-organic frameworks (MOFs) and porous coordination cages (PCCs) provides an efficient way to obtain hierarchical assemblies. Macrocycles, such as crown ethers, cyclodextrins, calixarenes, cucurbiturils, and pillararenes, can be incorporated within MOFs/PCCs and they also endow the resultant composites with enhanced properties and functionalities. This review summarizes recent developments of organo-macrocycle-containing hierarchical MOFs/PCCs, emphasizing applications and structure-property relationships of these hierarchically porous materials. This review provides insights for future research on hierarchical self-assembly using macrocycles as building blocks and functional ligands to extend the applications of the composites.
Organo-macrocycles can directly build metal-organic frameworks (MOFs) and porous coordination cages (PCCs), or be functionalized on them. These hierarchical assemblies extend the properties and functionalities for recognition, adsorption, catalysis, energy storage and so on. |
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| Bibliography: | Feihe Huang is Changjiang Scholar Chair Professor of Zhejiang University. His current research is focused on supramolecular polymers and nonporous adaptive crystals (NACs). Awards and honours he has received include Chinese Chemical Society AkzoNobel Chemical Sciences Award, The Cram Lehn Pedersen Prize in Supramolecular Chemistry, Royal Society of Chemistry Polymer Chemistry Lectureship award, and Bruno Werdelmann Lectureship Award. His publications have been cited more than 32117 times. His h-index is 97. He sits/sat on the Advisory Boards of JACS, Chem Soc Rev, ChemCommun, Macromolecules, ACS Macro Lett, and Polym Chem. He is an Editorial Board Member of Mater Chem Front. Hong-Cai "Joe" Zhou obtained his PhD in 2000 from Texas A&M University under F. A. Cotton. After a postdoctoral stint at Harvard University with R. H. Holm, he joined the faculty of Miami University, Oxford in 2002. He moved to Texas A&M University in 2008 and was promoted to a Robert A. Welch Chair in Chemistry in 2015. In June 2013, he became an associate editor for Inorganic Chemistry (ACS). Since 2014, he has been listed as a Highly Cited Researcher annually by Clarivate Analytics. His research focuses on the preparation and application of Metal-Organic Frameworks (MOFs). Yu Liang graduated with honors in 2020 and received a master's degree in chemistry from Hunan University. After that, she went on to pursue her doctoral degree in chemistry under the supervision of Professor Yu Fang at Hunan University. Her research interests include porous coordination cages and their synthesis and applications in hybrid materials. Errui Li received his bachelor's degree in Chemical Engineering and Technology from Hefei University of Technology in 2016. Than he obtained his PhD in 2021 under the guidance of Prof. Feihe Huang, from Department of Chemistry, Zhejiang University, China. His research interests include functional supramolecular materials and porous crystalline solids. Liangliang Zhang received his PhD in Inorganic Chemistry from Shandong University under the supervision of Prof. Daofeng Sun. In 2013, he joined the faculty of China University of petroleum. He worked in Prof. Hongcai Zhou's group at Texas A&M University as a visiting scholar during 2016-2017; then, he moved to Northwestern Polytechnical University in 2018. He worked with Prof. Hai-Long Jiang at USTC in 2019. His current research interests are centered on construction of high-valence porous MOFs and their catalytic applications. Kun-Yu Wang received his BSc in Chemistry (Po-Ling class) from Nankai University in 2018, where he studied luminescent metal-organic frameworks under the guidance of Prof. Wei Shi. Currently, he is a PhD candidate in Prof. Hong-Cai Zhou's research group at Texas A&M University. His research interest now focuses on hierarchically porous framework materials. He has received multiple research awards, including the Foresight Fellowship in Molecular Machines and the Dow Chemical Company Charlene Black Miller '79 Endowed Memorial Fellowship. Yu Fang obtained his MS in 2010 from Shanghai Jiaotong University. Then he pursuited PhD degree at The University of Tokyo in Prof. Makoto Fujita's lab. From 2015, he joined Prof. Hong-Cai Zhou's research group at Texas A&M University as a postdoctoral researcher. In 2019, he joined Hunan Univeristy as independent project investigator. His research focuses on the design and synthesis of Porous Coordination Cages (PCCs), and the fine tune of the properties and applciations. ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-3 content type line 23 ObjectType-Review-1 |
| ISSN: | 0306-0012 1460-4744 |
| DOI: | 10.1039/d2cs00232a |