Europium complexes with dinitropyrazole: unusual luminescence thermal behavior and irreversible temperature sensing
Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating, i.e. there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. We propose and successfully demonstrate the possibility of using this phenomenon for sensing overheating...
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| Published in | Physical chemistry chemical physics : PCCP Vol. 23; no. 45; pp. 2548 - 25484 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
24.11.2021
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1463-9076 1463-9084 1463-9084 |
| DOI | 10.1039/d1cp03924e |
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| Abstract | Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating,
i.e.
there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. We propose and successfully demonstrate the possibility of using this phenomenon for sensing overheating above this temperature. An on/off ratio of 37 is reached.
Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating,
i.e.
there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. |
|---|---|
| AbstractList | Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating,
i.e.
there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. We propose and successfully demonstrate the possibility of using this phenomenon for sensing overheating above this temperature. An on/off ratio of 37 is reached.
Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating,
i.e.
there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating, i.e. there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. We propose and successfully demonstrate the possibility of using this phenomenon for sensing overheating above this temperature. An on/off ratio of 37 is reached. Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating, i.e. there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. We propose and successfully demonstrate the possibility of using this phenomenon for sensing overheating above this temperature. An on/off ratio of 37 is reached. Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating, i.e. there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. We propose and successfully demonstrate the possibility of using this phenomenon for sensing overheating above this temperature. An on/off ratio of 37 is reached.Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating, i.e. there is a noticeable increase of the luminescence intensity beyond a temperature of 200 °C. We propose and successfully demonstrate the possibility of using this phenomenon for sensing overheating above this temperature. An on/off ratio of 37 is reached. |
| Author | Tsymbarenko, Dmitry M Vatsadze, Sergey Z Utochnikova, Valentina V Goloveshkin, Alexander S Vatsadze, Irina A |
| AuthorAffiliation | M.V. Lomonosov Moscow State University Leninskie Gory A.N. Nesmeyanov Institute of Organoelement Compounds RAS N.D. Zelinsky Institute of Organic Chemistry RAS Leninsky Prosp. 47 |
| AuthorAffiliation_xml | – name: M.V. Lomonosov Moscow State University – name: N.D. Zelinsky Institute of Organic Chemistry RAS – name: Leninskie Gory – name: Leninsky Prosp. 47 – name: A.N. Nesmeyanov Institute of Organoelement Compounds RAS |
| Author_xml | – sequence: 1 givenname: Valentina V surname: Utochnikova fullname: Utochnikova, Valentina V – sequence: 2 givenname: Irina A surname: Vatsadze fullname: Vatsadze, Irina A – sequence: 3 givenname: Dmitry M surname: Tsymbarenko fullname: Tsymbarenko, Dmitry M – sequence: 4 givenname: Alexander S surname: Goloveshkin fullname: Goloveshkin, Alexander S – sequence: 5 givenname: Sergey Z surname: Vatsadze fullname: Vatsadze, Sergey Z |
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| Cites_doi | 10.1002/chem.201501816 10.1021/acs.inorgchem.1c00581 10.1016/j.foodres.2010.11.011 10.1002/biot.201300203 10.3390/s8095673 10.1016/B978-0-12-385904-4.00010-X 10.1016/j.cej.2014.08.010 10.1002/jhet.5570100635 10.1016/j.foodres.2020.109225 10.1016/j.ccr.2013.11.017 10.1039/C4CC10432C 10.1016/j.inoche.2011.11.009 10.1016/j.jlumin.2018.09.027 10.1002/ejic.201600843 10.1039/C7TB00403F 10.1016/B978-0-08-102029-6.00009-9 10.1016/j.jlumin.2018.05.022 10.1016/j.jphotochem.2012.04.022 |
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| References_xml | – issn: 2018 end-page: p 215-233 publication-title: Luminescence Thermometry doi: Drami anin – issn: 2003 end-page: p 1033-1038 publication-title: TEMPERATURE: Its Measurement and Control in Science and Industry; Eighth Temperature Symposium doi: Allison Gates Beshears Gillies – issn: 2011 publication-title: Basics of Lanthanide Photophysics doi: Bunzli Eliseeva Bünzli Eliseeva – volume: 21 start-page: 17921 year: 2016 ident: D1CP03924E/cit15 publication-title: Chem. – Eur. J. doi: 10.1002/chem.201501816 – volume: 60 start-page: 8049 year: 2021 ident: D1CP03924E/cit21 publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.1c00581 – volume: 44 start-page: 71 year: 2011 ident: D1CP03924E/cit1 publication-title: Food Res. Int. doi: 10.1016/j.foodres.2010.11.011 – volume: 9 start-page: 241 year: 2014 ident: D1CP03924E/cit7 publication-title: Biotechnol. J. doi: 10.1002/biot.201300203 – volume: 8 start-page: 5673 year: 2008 ident: D1CP03924E/cit12 publication-title: Sensors doi: 10.3390/s8095673 – volume: 63 start-page: 1 year: 2011 ident: D1CP03924E/cit9 publication-title: Adv. Inorg. Chem. doi: 10.1016/B978-0-12-385904-4.00010-X – volume-title: Basics of Lanthanide Photophysics year: 2011 ident: D1CP03924E/cit19 – volume: 259 start-page: 70 year: 2015 ident: D1CP03924E/cit3 publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2014.08.010 – volume: 10 start-page: 1055 year: 1973 ident: D1CP03924E/cit18 publication-title: J. Heterocycl. Chem. doi: 10.1002/jhet.5570100635 – volume: 134 start-page: 109225 year: 2020 ident: D1CP03924E/cit2 publication-title: Food Res. Int. doi: 10.1016/j.foodres.2020.109225 – start-page: 1033 volume-title: TEMPERATURE: Its Measurement and Control in Science and Industry; Eighth Temperature Symposium year: 2003 ident: D1CP03924E/cit11 – volume: 273–274 start-page: 13 year: 2014 ident: D1CP03924E/cit5 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2013.11.017 – volume: 51 start-page: 4129 year: 2015 ident: D1CP03924E/cit6 publication-title: Chem. Commun. doi: 10.1039/C4CC10432C – volume: 16 start-page: 4 year: 2012 ident: D1CP03924E/cit13 publication-title: Inorg. Chem. Commun. doi: 10.1016/j.inoche.2011.11.009 – volume: 205 start-page: 429 year: 2019 ident: D1CP03924E/cit17 publication-title: J. Lumin. doi: 10.1016/j.jlumin.2018.09.027 – start-page: 107 year: 2017 ident: D1CP03924E/cit14 publication-title: Eur. J. Inorg. Chem. doi: 10.1002/ejic.201600843 – volume: 5 start-page: 4365 year: 2017 ident: D1CP03924E/cit8 publication-title: J. Mater. Chem. B doi: 10.1039/C7TB00403F – volume: 11 start-page: 100095 year: 2021 ident: D1CP03924E/cit4 publication-title: Energy Convers. Manage.: X – start-page: 215 volume-title: Luminescence Thermometry year: 2018 ident: D1CP03924E/cit10 doi: 10.1016/B978-0-08-102029-6.00009-9 – volume: 202 start-page: 38 year: 2018 ident: D1CP03924E/cit16 publication-title: J. Lumin. doi: 10.1016/j.jlumin.2018.05.022 – volume: 239 start-page: 37 year: 2012 ident: D1CP03924E/cit20 publication-title: J. Photochem. Photobiol., A doi: 10.1016/j.jphotochem.2012.04.022 |
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| Snippet | Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating,
i.e.
there is a noticeable increase of the luminescence... Europium 3,5-dinitropyrazole complexes demonstrate an unusual luminescence behavior upon heating, i.e. there is a noticeable increase of the luminescence... |
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| Title | Europium complexes with dinitropyrazole: unusual luminescence thermal behavior and irreversible temperature sensing |
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