Preparation and characterization of foamed glass-ceramics based on waste glass and slow-cooled high-titanium blast furnace slag using borax as a flux agent

•Foamed glass-ceramics were prepared at 1000 °C through the one-step sintering process.•The one-step sintering process concurrently completed foaming and crystallizing process.•Borax was influential to both foaming and crystallizing process of foamed glass-ceramics. Foamed glass-ceramics were prepar...

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Published inJournal of non-crystalline solids Vol. 590; p. 121703
Main Authors Zhou, Hongling, Feng, Keqin, Liu, Yanfang, Cai, Liangping
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.08.2022
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Abstract •Foamed glass-ceramics were prepared at 1000 °C through the one-step sintering process.•The one-step sintering process concurrently completed foaming and crystallizing process.•Borax was influential to both foaming and crystallizing process of foamed glass-ceramics. Foamed glass-ceramics were prepared at 1000 °C through the one-step sintering process by applying waste glass and slow-cooled high-titanium blast furnace slag as raw materials. This study investigated the effects of borax as the flux agent on the crystalline phases, microstructure, and properties of foamed glass-ceramics, respectively. It was found that the borax would decrease the system's softening temperature and viscosity, thus enhancing the foaming and crystallizing process. Besides, the XRD results showed that the main crystal types of foamed glass-ceramics presented no difference with different contents of borax addition, but their crystallinity and crystal morphology differed. With the increasing borax content, the porosity and water absorption increased, while the volume density, thermal conductivity, and compressive strength all decreased. In particular, the sample added with 6 wt% borax exhibited the optimal comprehensive properties. This study provided a practical guideline for effectively reusing solid industrial wastes to produce foamed glass-ceramics.
AbstractList •Foamed glass-ceramics were prepared at 1000 °C through the one-step sintering process.•The one-step sintering process concurrently completed foaming and crystallizing process.•Borax was influential to both foaming and crystallizing process of foamed glass-ceramics. Foamed glass-ceramics were prepared at 1000 °C through the one-step sintering process by applying waste glass and slow-cooled high-titanium blast furnace slag as raw materials. This study investigated the effects of borax as the flux agent on the crystalline phases, microstructure, and properties of foamed glass-ceramics, respectively. It was found that the borax would decrease the system's softening temperature and viscosity, thus enhancing the foaming and crystallizing process. Besides, the XRD results showed that the main crystal types of foamed glass-ceramics presented no difference with different contents of borax addition, but their crystallinity and crystal morphology differed. With the increasing borax content, the porosity and water absorption increased, while the volume density, thermal conductivity, and compressive strength all decreased. In particular, the sample added with 6 wt% borax exhibited the optimal comprehensive properties. This study provided a practical guideline for effectively reusing solid industrial wastes to produce foamed glass-ceramics.
ArticleNumber 121703
Author Cai, Liangping
Feng, Keqin
Liu, Yanfang
Zhou, Hongling
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  surname: Zhou
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  email: zhouhongling@cqu.edu.cn
  organization: College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
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  givenname: Yanfang
  surname: Liu
  fullname: Liu, Yanfang
  organization: School of Mechanical Engineering, Sichuan University, Chengdu 610065, China
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  givenname: Liangping
  surname: Cai
  fullname: Cai, Liangping
  organization: School of Mechanical Engineering, Sichuan University, Chengdu 610065, China
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Keywords Foamed glass-ceramics
Borax
Slow-cooled high-titanium blast furnace slag
Foaming
Crystallizing
Language English
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Snippet •Foamed glass-ceramics were prepared at 1000 °C through the one-step sintering process.•The one-step sintering process concurrently completed foaming and...
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SubjectTerms Borax
Crystallizing
Foamed glass-ceramics
Foaming
Slow-cooled high-titanium blast furnace slag
Title Preparation and characterization of foamed glass-ceramics based on waste glass and slow-cooled high-titanium blast furnace slag using borax as a flux agent
URI https://dx.doi.org/10.1016/j.jnoncrysol.2022.121703
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