Passivation of Cu-Rh Alloys
Historically, there have been two general approaches for understanding alloy passivation behavior. One involves study of the composition and crystal structure of the passive film and the other is concerned with how the composition and structure of the metallic alloy dictates the formation of the fil...
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Published in | Journal of the Electrochemical Society Vol. 168; no. 7; pp. 71505 - 71509 |
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01.07.2021
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Abstract | Historically, there have been two general approaches for understanding alloy passivation behavior. One involves study of the composition and crystal structure of the passive film and the other is concerned with how the composition and structure of the metallic alloy dictates the formation of the film. Herein we describe a recently developed theory based on a conjecture of Sieradzki and Newman connected to percolation theory and use the theory to model the passivation behavior of a series of Cu-Rh alloys. Our results are in quantitative agreement with the predictions of this theory. We discuss how the theory elucidates the important role of short-range order in understanding how composition affects the details of the passivation process. |
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AbstractList | Historically, there have been two general approaches for understanding alloy passivation behavior. One involves study of the composition and crystal structure of the passive film and the other is concerned with how the composition and structure of the metallic alloy dictates the formation of the film. Herein we describe a recently developed theory based on a conjecture of Sieradzki and Newman connected to percolation theory and use the theory to model the passivation behavior of a series of Cu-Rh alloys. Our results are in quantitative agreement with the predictions of this theory. We discuss how the theory elucidates the important role of short-range order in understanding how composition affects the details of the passivation process. |
Author | Jin, Hai-Jun Sieradzki, Karl Xie, Yusi Liu, Ling-Zhi Chatterjee, Swarnendu |
Author_xml | – sequence: 1 givenname: Yusi surname: Xie fullname: Xie, Yusi organization: Arizona State University Ira A. Fulton School of Engineering, Tempe, Arizona 85287, United States of America – sequence: 2 givenname: Swarnendu surname: Chatterjee fullname: Chatterjee, Swarnendu organization: Arizona State University Ira A. Fulton School of Engineering, Tempe, Arizona 85287, United States of America – sequence: 3 givenname: Ling-Zhi surname: Liu fullname: Liu, Ling-Zhi organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China – sequence: 4 givenname: Hai-Jun surname: Jin fullname: Jin, Hai-Jun organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China – sequence: 5 givenname: Karl orcidid: 0000-0002-4789-3956 surname: Sieradzki fullname: Sieradzki, Karl organization: Arizona State University Ira A. Fulton School of Engineering, Tempe, Arizona 85287, United States of America |
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Title | Passivation of Cu-Rh Alloys |
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