Swallow-Nest Architectures with Cobalt Molybdate Particulates Fixed Constructed Carbon Nanotube Supports for Stable Sodium-Ion Battery Anode

A swallow-nest architecture is fabricated through in situ prefabricated heating using cobalt molybdate (CoMoO4) as the subject and acid-functionalized carbon nanotubes (AF-CNTs) as the skeleton (CoMoO4/AF-CNT nest). The CoMoO4/AF-CNT nest is fixed via the C-O-Mo bond between the AF-CNT supports and...

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Published inJournal of the Electrochemical Society Vol. 167; no. 8; pp. 80528 - 80536
Main Authors Zhao, Yixing, Xu, Zhanwei, Fu, Hao, Xiao, Ronglin, Fu, Maosen, Yue, Hao, Huang, Jianfeng
Format Journal Article
LanguageEnglish
Published IOP Publishing 12.05.2020
Subjects
anode
cobalt molybdate
long-life
swallow nest architectures
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Abstract A swallow-nest architecture is fabricated through in situ prefabricated heating using cobalt molybdate (CoMoO4) as the subject and acid-functionalized carbon nanotubes (AF-CNTs) as the skeleton (CoMoO4/AF-CNT nest). The CoMoO4/AF-CNT nest is fixed via the C-O-Mo bond between the AF-CNT supports and CoMoO4 nanoparticles and hydrogen bonds of neighboring CNTs. The size of CoMoO4 in the CoMoO4/AF-CNT nest is confined to the nanometer level (30 nm), which will lead to negligible nanoscale volume changes during charge and discharge. The swallow-nest architecture can enhance the stability of the electrode, thus accelerating electrolyte penetration and providing fast diffusion channels for charge and Na+ ion transfer. When used as the anode of sodium-ion batteries, the CoMoO4/AF-CNT nest electrodes exhibit a reversible capacity of 151.6 mA h g−1 at the promising current densities of 2.0 A g−1 with degradation rate lower than 5.4 A h g−1 cycle−1 after 2000 cycles.
AbstractList A swallow-nest architecture is fabricated through in situ prefabricated heating using cobalt molybdate (CoMoO4) as the subject and acid-functionalized carbon nanotubes (AF-CNTs) as the skeleton (CoMoO4/AF-CNT nest). The CoMoO4/AF-CNT nest is fixed via the C-O-Mo bond between the AF-CNT supports and CoMoO4 nanoparticles and hydrogen bonds of neighboring CNTs. The size of CoMoO4 in the CoMoO4/AF-CNT nest is confined to the nanometer level (30 nm), which will lead to negligible nanoscale volume changes during charge and discharge. The swallow-nest architecture can enhance the stability of the electrode, thus accelerating electrolyte penetration and providing fast diffusion channels for charge and Na+ ion transfer. When used as the anode of sodium-ion batteries, the CoMoO4/AF-CNT nest electrodes exhibit a reversible capacity of 151.6 mA h g−1 at the promising current densities of 2.0 A g−1 with degradation rate lower than 5.4 A h g−1 cycle−1 after 2000 cycles.
Author Fu, Maosen
Xu, Zhanwei
Fu, Hao
Zhao, Yixing
Huang, Jianfeng
Xiao, Ronglin
Yue, Hao
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Cites_doi 10.1021/acsnano.8b00168
10.1016/j.electacta.2018.01.092
10.1039/C8TA09221D
10.1002/celc.201600706
10.1002/smll.201703086
10.1039/C5CP03331D
10.1016/j.nanoen.2014.12.032
10.1016/j.electacta.2016.01.228
10.1039/C0JM02156C
10.1021/ja406016j
10.1002/aenm.201803137
10.1039/C4CS00350K
10.1021/acs.chemmater.6b00761
10.1016/j.electacta.2017.05.092
10.1002/ente.201700555
10.1002/anie.201209689
10.1021/jz200836h
10.1002/anie.201607469
10.1016/j.jpowsour.2015.09.011
10.1039/C7TA08868J
10.1016/j.carbon.2015.09.091
10.1039/c3cc46665e
10.1039/C2TA00163B
10.1002/smll.201700917
10.1021/am505983m
10.1016/j.cej.2015.11.105
10.1002/aenm.201702434
10.1021/acsnano.6b03683
10.1021/cr500192f
10.1016/j.jpowsour.2017.12.053
10.1021/acsami.5b06590
10.1016/j.jallcom.2019.03.283
10.1002/smll.201600565
10.1039/C4TA05073H
10.1039/c1ee01782a
10.1142/S1793604718501047
10.1039/c2ra01300b
10.3390/en4040582
10.1021/cm9012014
10.1039/C7QM00175D
10.1016/j.ensm.2016.06.005
10.1002/smll.201702961
10.1021/acssuschemeng.7b01595
10.1016/j.jpowsour.2008.12.032
10.1002/advs.201900264
10.1039/C8TA00889B
10.1039/C7TA01308F
10.1038/35035045
10.1016/j.electacta.2017.10.114
10.1016/j.carbon.2019.01.009
10.1039/C5DT00622H
10.1016/j.nanoen.2014.02.002
10.1021/acsami.8b16324
10.1016/j.cej.2018.07.139
10.1007/s12598-017-0904-y
10.1016/0378-7753(94)02030-7
10.1016/j.susc.2018.05.018
10.1016/j.cej.2016.10.073
10.1016/j.jpowsour.2018.12.032
10.1016/j.jpowsour.2011.10.027
10.1039/C5NR02961A
10.1007/s10854-017-8050-8
10.1021/am302583c
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References 44
45
46
47
48
49
50
51
52
53
10
54
11
55
12
56
13
57
14
58
15
59
16
17
18
19
1
2
3
4
5
6
7
8
9
60
61
62
63
20
64
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
References_xml – ident: 21
  doi: 10.1021/acsnano.8b00168
– ident: 30
  doi: 10.1016/j.electacta.2018.01.092
– ident: 35
  doi: 10.1039/C8TA09221D
– ident: 22
  doi: 10.1002/celc.201600706
– ident: 57
  doi: 10.1002/smll.201703086
– ident: 29
  doi: 10.1039/C5CP03331D
– ident: 45
  doi: 10.1016/j.nanoen.2014.12.032
– ident: 18
  doi: 10.1016/j.electacta.2016.01.228
– ident: 23
  doi: 10.1039/C0JM02156C
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  doi: 10.1021/ja406016j
– ident: 62
  doi: 10.1002/aenm.201803137
– ident: 38
  doi: 10.1039/C4CS00350K
– ident: 25
  doi: 10.1021/acs.chemmater.6b00761
– ident: 60
  doi: 10.1016/j.electacta.2017.05.092
– ident: 26
  doi: 10.1002/ente.201700555
– ident: 42
  doi: 10.1002/anie.201209689
– ident: 31
  doi: 10.1021/jz200836h
– ident: 52
  doi: 10.1002/anie.201607469
– ident: 16
  doi: 10.1016/j.jpowsour.2015.09.011
– ident: 32
  doi: 10.1039/C7TA08868J
– ident: 7
  doi: 10.1016/j.carbon.2015.09.091
– ident: 49
  doi: 10.1039/c3cc46665e
– ident: 64
  doi: 10.1039/C2TA00163B
– ident: 24
  doi: 10.1002/smll.201700917
– ident: 11
  doi: 10.1021/am505983m
– ident: 4
  doi: 10.1016/j.cej.2015.11.105
– ident: 43
  doi: 10.1002/aenm.201702434
– ident: 34
  doi: 10.1021/acsnano.6b03683
– ident: 2
  doi: 10.1021/cr500192f
– ident: 5
  doi: 10.1016/j.jpowsour.2017.12.053
– ident: 53
  doi: 10.1021/acsami.5b06590
– ident: 61
  doi: 10.1016/j.jallcom.2019.03.283
– ident: 55
  doi: 10.1002/smll.201600565
– ident: 36
  doi: 10.1039/C4TA05073H
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  doi: 10.1039/c1ee01782a
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  doi: 10.1142/S1793604718501047
– ident: 19
  doi: 10.1039/c2ra01300b
– ident: 50
  doi: 10.3390/en4040582
– ident: 13
  doi: 10.1021/cm9012014
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  doi: 10.1039/C7QM00175D
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  doi: 10.1016/j.ensm.2016.06.005
– ident: 58
  doi: 10.1002/smll.201702961
– ident: 44
  doi: 10.1021/acssuschemeng.7b01595
– ident: 48
  doi: 10.1016/j.jpowsour.2008.12.032
– ident: 56
  doi: 10.1002/advs.201900264
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  doi: 10.1039/C8TA00889B
– ident: 27
  doi: 10.1039/C7TA01308F
– ident: 39
  doi: 10.1038/35035045
– ident: 46
  doi: 10.1016/j.electacta.2017.10.114
– ident: 59
  doi: 10.1016/j.carbon.2019.01.009
– ident: 14
  doi: 10.1039/C5DT00622H
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  doi: 10.1016/j.nanoen.2014.02.002
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  doi: 10.1021/acsami.8b16324
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  doi: 10.1016/j.cej.2018.07.139
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  doi: 10.1007/s12598-017-0904-y
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  doi: 10.1016/0378-7753(94)02030-7
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  doi: 10.1016/j.susc.2018.05.018
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  doi: 10.1039/C5NR02961A
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Snippet A swallow-nest architecture is fabricated through in situ prefabricated heating using cobalt molybdate (CoMoO4) as the subject and acid-functionalized carbon...
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SubjectTerms anode
cobalt molybdate
long-life
swallow nest architectures
Title Swallow-Nest Architectures with Cobalt Molybdate Particulates Fixed Constructed Carbon Nanotube Supports for Stable Sodium-Ion Battery Anode
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