Swallow-Nest Architectures with Cobalt Molybdate Particulates Fixed Constructed Carbon Nanotube Supports for Stable Sodium-Ion Battery Anode

• Published in: Journal of the Electrochemical Society Vol. 167; no. 8; pp. 80528 - 80536
• Main Authors: Zhao, Yixing, Xu, Zhanwei, Fu, Hao, Xiao, Ronglin, Fu, Maosen, Yue, Hao, Huang, Jianfeng
• Format: Journal Article
• Language: English
• Published: IOP Publishing 12.05.2020
• Subjects: anode; cobalt molybdate; long-life; swallow nest architectures
• ISSN: 0013-4651; 1945-7111; 1945-7111
• DOI: 10.1149/1945-7111/ab8fd8

A swallow-nest architecture is fabricated through in situ prefabricated heating using cobalt molybdate (CoMoO4) as the subject and acid-functionalized carbon nanotubes (AF-CNTs) as the skeleton (CoMoO4/AF-CNT nest). The CoMoO4/AF-CNT nest is fixed via the C-O-Mo bond between the AF-CNT supports and CoMoO4 nanoparticles and hydrogen bonds of neighboring CNTs. The size of CoMoO4 in the CoMoO4/AF-CNT nest is confined to the nanometer level (30 nm), which will lead to negligible nanoscale volume changes during charge and discharge. The swallow-nest architecture can enhance the stability of the electrode, thus accelerating electrolyte penetration and providing fast diffusion channels for charge and Na+ ion transfer. When used as the anode of sodium-ion batteries, the CoMoO4/AF-CNT nest electrodes exhibit a reversible capacity of 151.6 mA h g−1 at the promising current densities of 2.0 A g−1 with degradation rate lower than 5.4 A h g−1 cycle−1 after 2000 cycles.