Synthesis, characterization and crystal structure of a 1D thiocyanato bridged [Cu(en)2Zn(NCS)4]⋅H2O. Comparison of the three structures with the same [Cu(en)2Zn(NCS)4] unit − different in structural terms

• Published in: Journal of molecular structure Vol. 1083; pp. 374 - 380
• Main Authors: Wrzeszcz, Grzegorz, Muzioł, Tadeusz M., Tereba, Natalia
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.03.2015
• Subjects: Copper(II); Heterometallic complex; Magnetic measurements; Thiocyanato bridge; X-ray; Zinc(II); Heterometallic complex; Magnetic measurements; X-ray; Thiocyanato bridge; Zinc(II); Copper(II)

[Display omitted] •A new complex with known [Cu(en)2Zn(NCS)4] zigzag unit was synthesized.•The structure has been characterized by single crystal X-ray crystallography.•Structural similarities and differences of three related compounds are discussed.•Spectroscopic and magnetic properties are present...