Tailoring amphiphilic polymeric coating with durable antifogging performance

Foggy surfaces can damage the optical performance of devices and even cause adverse consequences like safety concerns in some cases. Various antifogging coatings have been proposed to relieve this trouble. Nevertheless, most coatings suffer from temporary fog-repellency features due to hygroscopic s...

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Published inProgress in organic coatings Vol. 179; p. 107523
Main Authors Gong, Xiaodan, Yu, Haojie, Wang, Li, Hu, Jian, Wang, Luming, Li, Chengjiang
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.06.2023
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Abstract Foggy surfaces can damage the optical performance of devices and even cause adverse consequences like safety concerns in some cases. Various antifogging coatings have been proposed to relieve this trouble. Nevertheless, most coatings suffer from temporary fog-repellency features due to hygroscopic swelling behavior and detachable interface. Herein, we reported an antifogging coating with persistent fogging prevention via the introduction of the amphiphilic polymer and interfacial layer. With the aid of benzophenone (BP) groups, both bulk crosslinking and interfacial bonding were achieved to prevent relatively macroscopic motions of coating from the substrate under extreme conditions. In virtue of the minor swelling and interfacial adhesion, the coating could preserve the fog-free behavior after 50-cycle antifogging tests and even aging for 90 days under harsh conditions. Notably, both in vitro (pig larynx) and vivo (living rabbit) outcomes indicated excellent fog-repellency of the polymer-coated endoscope. [Display omitted] •The antifogging amphiphilic coating was reported.•The photoreactive CH insertion of bulk crosslinking and interfacial bonding was achieved to prevent coating detachment.•Persistent fogging prevention was presented due to the minor swelling and strong interfacial adhesion.•The coating showed potential application on endoscopes for clear fog-free vision.
AbstractList Foggy surfaces can damage the optical performance of devices and even cause adverse consequences like safety concerns in some cases. Various antifogging coatings have been proposed to relieve this trouble. Nevertheless, most coatings suffer from temporary fog-repellency features due to hygroscopic swelling behavior and detachable interface. Herein, we reported an antifogging coating with persistent fogging prevention via the introduction of the amphiphilic polymer and interfacial layer. With the aid of benzophenone (BP) groups, both bulk crosslinking and interfacial bonding were achieved to prevent relatively macroscopic motions of coating from the substrate under extreme conditions. In virtue of the minor swelling and interfacial adhesion, the coating could preserve the fog-free behavior after 50-cycle antifogging tests and even aging for 90 days under harsh conditions. Notably, both in vitro (pig larynx) and vivo (living rabbit) outcomes indicated excellent fog-repellency of the polymer-coated endoscope. [Display omitted] •The antifogging amphiphilic coating was reported.•The photoreactive CH insertion of bulk crosslinking and interfacial bonding was achieved to prevent coating detachment.•Persistent fogging prevention was presented due to the minor swelling and strong interfacial adhesion.•The coating showed potential application on endoscopes for clear fog-free vision.
ArticleNumber 107523
Author Wang, Luming
Yu, Haojie
Wang, Li
Li, Chengjiang
Hu, Jian
Gong, Xiaodan
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  organization: The First Affiliated Hospital, Zhejiang University School of Medicine, Zhejiang University, Hangzhou 310003, PR China
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CitedBy_id crossref_primary_10_1016_j_polymertesting_2024_108619
crossref_primary_10_1039_D4LP00322E
crossref_primary_10_1002_smll_202402114
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Keywords Interfacial adhesion
Surface modification
Antifogging coating
Amphiphilic polymers
Benzophenone
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Snippet Foggy surfaces can damage the optical performance of devices and even cause adverse consequences like safety concerns in some cases. Various antifogging...
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elsevier
SourceType Enrichment Source
Index Database
Publisher
StartPage 107523
SubjectTerms Amphiphilic polymers
Antifogging coating
Benzophenone
Interfacial adhesion
Surface modification
Title Tailoring amphiphilic polymeric coating with durable antifogging performance
URI https://dx.doi.org/10.1016/j.porgcoat.2023.107523
Volume 179
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