One-step environmentally friendly exfoliation and functionalization of hexagonal boron nitride by β-cyclodextrin-assisted ball milling

Hexagonal boron nitride nanosheets (BNNs) are gaining much attention owing to their extraordinary performance; however, difficulties remain in achieving their large-scale preparation and dispersion at high concentration in solvents. A facile yet efficient β-cyclodextrin-assisted mechanochemical exfo...

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Published inCeramics international Vol. 46; no. 13; pp. 21084 - 21089
Main Authors Ji, Dong, Wang, Zhen, Zhu, Yanjiao, Yu, Haibin
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.09.2020
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Abstract Hexagonal boron nitride nanosheets (BNNs) are gaining much attention owing to their extraordinary performance; however, difficulties remain in achieving their large-scale preparation and dispersion at high concentration in solvents. A facile yet efficient β-cyclodextrin-assisted mechanochemical exfoliation method is proposed to exfoliate and functionalize hexagonal boron nitride (h-BN). The β-cyclodextrin-assisted ball milling process gave a high yield of 60%, with the resultant BNNs being covalently grafted with hydroxyl, and well dispersed in water and other solvents. The concentration of the hydroxyl-functionalized boron nitride nanosheets (OH-BNNs) reached 3 mg/mL, and was stable for several weeks. Next, we fabricated a membrane based on the resulting OH-BNNs to effectively capture Congo red dye. This work not only offers an environmentally friendly, efficient, solvent-less and extremely cost-effective scalable production method, but also assists in our understanding of the mechanism of exfoliation and functionalization in other layered materials.
AbstractList Hexagonal boron nitride nanosheets (BNNs) are gaining much attention owing to their extraordinary performance; however, difficulties remain in achieving their large-scale preparation and dispersion at high concentration in solvents. A facile yet efficient β-cyclodextrin-assisted mechanochemical exfoliation method is proposed to exfoliate and functionalize hexagonal boron nitride (h-BN). The β-cyclodextrin-assisted ball milling process gave a high yield of 60%, with the resultant BNNs being covalently grafted with hydroxyl, and well dispersed in water and other solvents. The concentration of the hydroxyl-functionalized boron nitride nanosheets (OH-BNNs) reached 3 mg/mL, and was stable for several weeks. Next, we fabricated a membrane based on the resulting OH-BNNs to effectively capture Congo red dye. This work not only offers an environmentally friendly, efficient, solvent-less and extremely cost-effective scalable production method, but also assists in our understanding of the mechanism of exfoliation and functionalization in other layered materials.
Author Yu, Haibin
Ji, Dong
Zhu, Yanjiao
Wang, Zhen
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β-Cyclodextrin-assisted ball milling
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Snippet Hexagonal boron nitride nanosheets (BNNs) are gaining much attention owing to their extraordinary performance; however, difficulties remain in achieving their...
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SubjectTerms Environmentally friendly
High yield
Stable
β-Cyclodextrin-assisted ball milling
Title One-step environmentally friendly exfoliation and functionalization of hexagonal boron nitride by β-cyclodextrin-assisted ball milling
URI https://dx.doi.org/10.1016/j.ceramint.2020.05.181
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