Effects of hydrolysis degree on ion-doped anion exchange membranes in direct borohydride fuel cells
Herein, polyvinyl alcohol based anion exchange membranes (AEMs) doped with various cobalt and chloride salts are synthesized to investigate the structure-performance relationship of ion-doped AEMs systemically. The performances of ion-doped AEMs are found to be related to the hydrolysis degree (DH)...
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Published in | International journal of hydrogen energy Vol. 48; no. 69; pp. 26990 - 27000 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
12.08.2023
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Subjects | |
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Abstract | Herein, polyvinyl alcohol based anion exchange membranes (AEMs) doped with various cobalt and chloride salts are synthesized to investigate the structure-performance relationship of ion-doped AEMs systemically. The performances of ion-doped AEMs are found to be related to the hydrolysis degree (DH) of the doped anions and cations. It is found that cations with varying DH transformed into hydroxides with different sizes and dispersions, which plays a key role in determining the structures and properties of cation-doped AEMs. On the other hand, weak-acid anions remained in the AEMs after alkali immersion, hindering OH− conduction and leading to the degradation of the anion-doped AEMs. High DH cations mildly react with the matrix and transform into more dispersive complexes, while low DH anions are replaced by OH−.The direct borohydride fuel cell using CuCl2-doped AEM exhibits a maximum power density of 202.4 mW cm−2 at 30 °C.
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•The properties of ion-doped AEMs are effected by the DH of doped-ions.•Cations transform into hydroxides with various sizes in the cation-doped AEM.•Weak-acid anions stay in the anion-doped AEM and hinder the OH− conduction.•Mildbase strong-acid salts are concluded as the most promising ionic additives. |
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AbstractList | Herein, polyvinyl alcohol based anion exchange membranes (AEMs) doped with various cobalt and chloride salts are synthesized to investigate the structure-performance relationship of ion-doped AEMs systemically. The performances of ion-doped AEMs are found to be related to the hydrolysis degree (DH) of the doped anions and cations. It is found that cations with varying DH transformed into hydroxides with different sizes and dispersions, which plays a key role in determining the structures and properties of cation-doped AEMs. On the other hand, weak-acid anions remained in the AEMs after alkali immersion, hindering OH− conduction and leading to the degradation of the anion-doped AEMs. High DH cations mildly react with the matrix and transform into more dispersive complexes, while low DH anions are replaced by OH−.The direct borohydride fuel cell using CuCl2-doped AEM exhibits a maximum power density of 202.4 mW cm−2 at 30 °C.
[Display omitted]
•The properties of ion-doped AEMs are effected by the DH of doped-ions.•Cations transform into hydroxides with various sizes in the cation-doped AEM.•Weak-acid anions stay in the anion-doped AEM and hinder the OH− conduction.•Mildbase strong-acid salts are concluded as the most promising ionic additives. |
Author | He, Junjing Wei, Jinyang He, Yan Liu, Jiabin Chu, Wen Hu, Yongping Ni, Hualiang Li, Dandan Qin, Haiying |
Author_xml | – sequence: 1 givenname: Dandan surname: Li fullname: Li, Dandan organization: New Energy Materials Research Center, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China – sequence: 2 givenname: Wen surname: Chu fullname: Chu, Wen email: bjfuchuwen@163.com organization: School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 3 givenname: Jinyang surname: Wei fullname: Wei, Jinyang organization: New Energy Materials Research Center, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China – sequence: 4 givenname: Yongping surname: Hu fullname: Hu, Yongping organization: New Energy Materials Research Center, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China – sequence: 5 givenname: Yan surname: He fullname: He, Yan organization: Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203, PR China – sequence: 6 givenname: Haiying orcidid: 0000-0002-5273-9515 surname: Qin fullname: Qin, Haiying email: hyqin@hdu.edu.cn organization: New Energy Materials Research Center, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China – sequence: 7 givenname: Jiabin surname: Liu fullname: Liu, Jiabin organization: School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, PR China – sequence: 8 givenname: Junjing orcidid: 0000-0002-8348-1633 surname: He fullname: He, Junjing organization: New Energy Materials Research Center, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China – sequence: 9 givenname: Hualiang surname: Ni fullname: Ni, Hualiang organization: New Energy Materials Research Center, College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, PR China |
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Keywords | Anion exchange membranes Hydrolysis degree Direct borohydride fuel cells Ion doping |
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