Status of biodiesel production using heterogeneous alkaline catalysts

This paper describes biodiesel production using heterogeneous alkaline catalysts instead of the conventional homogenous alkaline catalysts, such as NaOH, KOH or sodium methoxide, for the methanolysis reaction, in the search for more profitable and sustainable alternatives regarding biodiesel product...

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Published inInternational journal of environmental studies Vol. 69; no. 4; pp. 635 - 653
Main Authors Gomes, João F.P, Puna, Jaime F.B, Bordado, João C.M, Correia, M. Joana N, Dias, Ana P.S
Format Journal Article
LanguageEnglish
Published Routledge 01.08.2012
Subjects
Activation
alkaline earth metals
Biodiesel
Catalysis
Catalysts
Environmental studies
Heterogeneous alkaline catalysts
methanol
methanolysis
Methyl alcohol
potassium hydroxide
Sodium
sodium hydroxide
Transesterification
vegetable oil
Vegetable oils
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Abstract This paper describes biodiesel production using heterogeneous alkaline catalysts instead of the conventional homogenous alkaline catalysts, such as NaOH, KOH or sodium methoxide, for the methanolysis reaction, in the search for more profitable and sustainable alternatives regarding biodiesel production. The heterogeneous catalytic process has many differences from that currently used in industrial homogeneous processes. The main advantage is that it requires lower investment costs, as there is no need for separation steps such as methanol/catalyst, biodiesel/catalyst and glycerine/catalyst. This paper also describes experimental work towards the development of new heterogeneous alkaline catalysts able to produce biodiesel from vegetable oils. The research has resulted in the selection of CaO and CaO modified with alkaline and alkaline earth metal catalysts. They show very good catalytic performances with high activity and stability. In fact, biodiesel (FAME) yields higher than 94% were observed in several consecutive reaction batches without expensive intermediate reactivation procedures. Therefore, those catalysts appear to be suitable for biodiesel production.
AbstractList This paper describes biodiesel production using heterogeneous alkaline catalysts instead of the conventional homogenous alkaline catalysts, such as NaOH, KOH or sodium methoxide, for the methanolysis reaction, in the search for more profitable and sustainable alternatives regarding biodiesel production. The heterogeneous catalytic process has many differences from that currently used in industrial homogeneous processes. The main advantage is that it requires lower investment costs, as there is no need for separation steps such as methanol/catalyst, biodiesel/catalyst and glycerine/catalyst. This paper also describes experimental work towards the development of new heterogeneous alkaline catalysts able to produce biodiesel from vegetable oils. The research has resulted in the selection of CaO and CaO modified with alkaline and alkaline earth metal catalysts. They show very good catalytic performances with high activity and stability. In fact, biodiesel (FAME) yields higher than 94% were observed in several consecutive reaction batches without expensive intermediate reactivation procedures. Therefore, those catalysts appear to be suitable for biodiesel production.
Author Gomes, João F.P
Bordado, João C.M
Correia, M. Joana N
Puna, Jaime F.B
Dias, Ana P.S
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Snippet This paper describes biodiesel production using heterogeneous alkaline catalysts instead of the conventional homogenous alkaline catalysts, such as NaOH, KOH...
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SubjectTerms Activation
alkaline earth metals
Biodiesel
Catalysis
Catalysts
Environmental studies
Heterogeneous alkaline catalysts
methanol
methanolysis
Methyl alcohol
potassium hydroxide
Sodium
sodium hydroxide
Transesterification
vegetable oil
Vegetable oils
Title Status of biodiesel production using heterogeneous alkaline catalysts
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