Synthesis and characterization of V(III), Cr(III) and Fe(III) hippurates

Hippurates of V(III), Cr(III) and Fe(III) were isolated as solids with the general formula; [V(hip) 3]·15H 2O, [Cr(hip) 3]·6H 2O and [Fe(hip) 3]·1.5H 2O. The compounds were characterized from elemental analysis, infrared spectra, 1H NMR, electronic spectra and thermogravimetric analysis and proof th...

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Published inJournal of molecular structure Vol. 737; no. 2; pp. 139 - 145
Main Authors Sadeek, S.A., Refat, M.S., Teleb, S.M., El-Megharbel, S.M.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 04.03.2005
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Abstract Hippurates of V(III), Cr(III) and Fe(III) were isolated as solids with the general formula; [V(hip) 3]·15H 2O, [Cr(hip) 3]·6H 2O and [Fe(hip) 3]·1.5H 2O. The compounds were characterized from elemental analysis, infrared spectra, 1H NMR, electronic spectra and thermogravimetric analysis and proof that metal–ligand coordination involves only via the carboxylate group.
AbstractList Hippurates of V(III), Cr(III) and Fe(III) were isolated as solids with the general formula; [V(hip) 3]·15H 2O, [Cr(hip) 3]·6H 2O and [Fe(hip) 3]·1.5H 2O. The compounds were characterized from elemental analysis, infrared spectra, 1H NMR, electronic spectra and thermogravimetric analysis and proof that metal–ligand coordination involves only via the carboxylate group.
Author Sadeek, S.A.
Refat, M.S.
Teleb, S.M.
El-Megharbel, S.M.
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  organization: Chemistry Department, Faculty of Science, Zagazig University, Zagazig, Egypt
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  surname: El-Megharbel
  fullname: El-Megharbel, S.M.
  organization: Chemistry Department, Faculty of Science, Zagazig University, Zagazig, Egypt
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Keywords 1H NMR
Hippuric acid
Electronic spectra
TGA
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Snippet Hippurates of V(III), Cr(III) and Fe(III) were isolated as solids with the general formula; [V(hip) 3]·15H 2O, [Cr(hip) 3]·6H 2O and [Fe(hip) 3]·1.5H 2O. The...
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SubjectTerms 1H NMR
Electronic spectra
Hippuric acid
TGA
Title Synthesis and characterization of V(III), Cr(III) and Fe(III) hippurates
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