Role of chemical functional groups on thermal and electrical properties of various graphene oxide derivatives: a comparative x-ray photoelectron spectroscopy analysis

In recent years, graphene and its derivatives have become prominent subject matter due to their fascinating combination of properties and potential applications in a number application. While several fundamental studies have been progressed, there is a particular need to understand how different gra...

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Published inMaterials research express Vol. 5; no. 3; pp. 35604 - 35617
Main Authors Mohan, Velram Balaji, Jakisch, Lothar, Jayaraman, Krishnan, Bhattacharyya, Debes
Format Journal Article
LanguageEnglish
Published IOP Publishing 14.03.2018
Subjects
chemical entities
electrical conductivity
graphene derivatives
thermal conductivity
x-ray photoelectron spectroscopy
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ISSN2053-1591
2053-1591
DOI10.1088/2053-1591/aab316

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Abstract In recent years, graphene and its derivatives have become prominent subject matter due to their fascinating combination of properties and potential applications in a number application. While several fundamental studies have been progressed, there is a particular need to understand how different graphene derivatives are influenced in terms of their electrical and thermal conductivities by different functional groups they end up with through their manufacturing and functionalisation methods. This article addresses of the role of different functional groups present of different of reduced graphene oxides (rGO) concerning their electrical and thermal properties, and the results were compared with elemental analyses of functionalised reduced graphene oxide (frGO) and graphene. The results showed that electrical and thermal conductivities of the rGO samples, highly dependent on the presence of residual functional groups from oxidation, reduction and functionalisation processes. The increase in reduction of oxygen, hydroxyl, carboxylic, epoxide moieties and heterocyclic compounds increase the specific surface area of the samples through which the mean electron path has increased. This improved both electrical and thermal conductivities together in all the samples which were highly dependent on the efficiency of different reductant used in this study.
AbstractList In recent years, graphene and its derivatives have become prominent subject matter due to their fascinating combination of properties and potential applications in a number application. While several fundamental studies have been progressed, there is a particular need to understand how different graphene derivatives are influenced in terms of their electrical and thermal conductivities by different functional groups they end up with through their manufacturing and functionalisation methods. This article addresses of the role of different functional groups present of different of reduced graphene oxides (rGO) concerning their electrical and thermal properties, and the results were compared with elemental analyses of functionalised reduced graphene oxide (frGO) and graphene. The results showed that electrical and thermal conductivities of the rGO samples, highly dependent on the presence of residual functional groups from oxidation, reduction and functionalisation processes. The increase in reduction of oxygen, hydroxyl, carboxylic, epoxide moieties and heterocyclic compounds increase the specific surface area of the samples through which the mean electron path has increased. This improved both electrical and thermal conductivities together in all the samples which were highly dependent on the efficiency of different reductant used in this study.
Author Bhattacharyya, Debes
Jakisch, Lothar
Jayaraman, Krishnan
Mohan, Velram Balaji
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Snippet In recent years, graphene and its derivatives have become prominent subject matter due to their fascinating combination of properties and potential...
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StartPage 35604
SubjectTerms chemical entities
electrical conductivity
graphene derivatives
thermal conductivity
x-ray photoelectron spectroscopy
Title Role of chemical functional groups on thermal and electrical properties of various graphene oxide derivatives: a comparative x-ray photoelectron spectroscopy analysis
URI https://iopscience.iop.org/article/10.1088/2053-1591/aab316
Volume 5
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