Measurement and Correlation for Solubility of Adipic Acid in Several Solvents

Using a laser detecting system, solubility data were measured for adipic acid dissolved in six pure solvents, namely, cyclohexanone, cyclohexanol, acetic acid, N,N-dimethylformamide, N,N-dimethylacetamide, and dimethylsulfoxide at the temperature range from 293.15K to 353.15K. All these data were re...

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Published inChinese journal of chemical engineering Vol. 15; no. 1; pp. 110 - 114
Main Author 樊丽华 马沛生 相政乐
Format Journal Article
LanguageEnglish
Published 01.02.2007
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ISSN1004-9541
2210-321X
DOI10.1016/S1004-9541(07)60042-1

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Abstract Using a laser detecting system, solubility data were measured for adipic acid dissolved in six pure solvents, namely, cyclohexanone, cyclohexanol, acetic acid, N,N-dimethylformamide, N,N-dimethylacetamide, and dimethylsulfoxide at the temperature range from 293.15K to 353.15K. All these data were regressed by 2h, NRTL, Wilson, and the modified Wilson models. For the study of six, 2h, NRTL, and the modified Wilson models were found to provide an accurate mathematical representation of the experimental results, with overall average absolute relative deviations between measured and calculated values as 1.74%, 2.06%, and 3.06%, respectively. The results showed that the λh model is the most suitable for description of the solid-liquid equilibrium containing adipic acid.
AbstractList Using a laser detecting system, solubility data were measured for adipic acid dissolved in six pure solvents, namely, cyclohexanone, cyclohexanol, acetic acid, N,N-dimethylformamide, N,N-dimethylacetamide, and dimethylsulfoxide at the temperature range from 293.15K to 353.15K. All these data were regressed by lambdah, NRTL, Wilson, and the modified Wilson models. For the study of six, Deltah, NRTL, and the modified Wilson models were found to provide an accurate mathematical representation of the experimental results, with overall average absolute relative deviations between measured and calculated values as 1.74%, 2.06%, and 3.06%, respectively. The results showed that the Deltah model is the most suitable for description of the solid-liquid equilibrium containing adipic acid.
Using a laser detecting system, solubility data were measured for adipic acid dissolved in six pure solvents, namely, cyclohexanone, cyclohexanol, acetic acid, N,N-dimethylformamide, N,N-dimethylacetamide, and dimethylsulfoxide at the temperature range from 293.15K to 353.15K. All these data were regressed by 2h, NRTL, Wilson, and the modified Wilson models. For the study of six, 2h, NRTL, and the modified Wilson models were found to provide an accurate mathematical representation of the experimental results, with overall average absolute relative deviations between measured and calculated values as 1.74%, 2.06%, and 3.06%, respectively. The results showed that the λh model is the most suitable for description of the solid-liquid equilibrium containing adipic acid.
Author 樊丽华 马沛生 相政乐
AuthorAffiliation School of Chemical Engineering, Tianjin University, Tianjin 300072, China College of Chemical Engineering and Biological Technology, Hebei Polytechnic University, Tangshan 063009 China
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Notes solid-liquid equilibrium, solubility, adipic acid, modeling
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SubjectTerms 固液平衡
溶剂种类
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Title Measurement and Correlation for Solubility of Adipic Acid in Several Solvents
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