Exploring SEI Characteristics in Propylene Carbonate-Based Electrolyte with 2-Isocyanatoethyl Methacrylate at Graphite Electrode
Propylene carbonate (PC) has the advantage of a much lower melting point than ethylene carbonate (EC), but it cannot suppress the exfoliation of graphite layers because of its cointercalation with Li + before forming a stable solid electrolyte interface (SEI). This paper introduces 2−isocyanatoethyl...
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Published in | Journal of the Electrochemical Society Vol. 170; no. 11; pp. 110519 - 110526 |
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Language | English |
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Abstract | Propylene carbonate (PC) has the advantage of a much lower melting point than ethylene carbonate (EC), but it cannot suppress the exfoliation of graphite layers because of its cointercalation with Li
+
before forming a stable solid electrolyte interface (SEI). This paper introduces 2−isocyanatoethyl methacrylate (ICEMA) as an additive in PC−based electrolytes. ICEMA is a bifunctional monomer in which the isocyanate group is linked by the ethyl group to the acrylate group, which reacts through thermal polymerization. The isocyanate moiety is initiated as a radical during the initial charging process to induce electropolymerization and reaction with the PC radical. Radicals propagate through the entire reaction at the electrode to form a stable SEI. The modified interface suppresses the cointercalation of Li
+
−PC to graphite electrode. In situ Fourier transform infrared effectively showed the polymerization of the isocyanate and active reaction with the PC radical. Consequently, the reaction mechanisms to form the stable SEI in PC−based electrolytes were determined. |
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AbstractList | Propylene carbonate (PC) has the advantage of a much lower melting point than ethylene carbonate (EC), but it cannot suppress the exfoliation of graphite layers because of its cointercalation with Li
+
before forming a stable solid electrolyte interface (SEI). This paper introduces 2−isocyanatoethyl methacrylate (ICEMA) as an additive in PC−based electrolytes. ICEMA is a bifunctional monomer in which the isocyanate group is linked by the ethyl group to the acrylate group, which reacts through thermal polymerization. The isocyanate moiety is initiated as a radical during the initial charging process to induce electropolymerization and reaction with the PC radical. Radicals propagate through the entire reaction at the electrode to form a stable SEI. The modified interface suppresses the cointercalation of Li
+
−PC to graphite electrode. In situ Fourier transform infrared effectively showed the polymerization of the isocyanate and active reaction with the PC radical. Consequently, the reaction mechanisms to form the stable SEI in PC−based electrolytes were determined. |
Author | Kim, Yong-eun Jung, Cheolsoo |
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References | Xie (jesad09fbbib17) 2021; 143 Ramasubramanian (jesad09fbbib5) 2019; 123 Xing (jesad09fbbib27) 2018; 51 Takenaka (jesad09fbbib18) 2014; 118 Yao (jesad09fbbib2) 2020; 56 Kim (jesad09fbbib42) 2022; 169 Hobold (jesad09fbbib1) 2020; 32 Ederer (jesad09fbbib53) 2017; 7 Lee (jesad09fbbib25) 2018; 265 Winter (jesad09fbbib10) 2009; 223 Choi (jesad09fbbib47) 2020; 11 Kern (jesad09fbbib49) 2007; 174 Wang (jesad09fbbib15) 2019; 11 Agubra (jesad09fbbib19) 2014; 268 Hosseinioun (jesad09fbbib31) 2020; 594 Shafiei Sabet (jesad09fbbib48) 2019; 425 Zhu (jesad09fbbib33) 2020; 476 Zhang (jesad09fbbib8) 2018; 8 Verma (jesad09fbbib9) 2010; 55 Li (jesad09fbbib37) 2023; 554 Zhou (jesad09fbbib32) 2021; 34 Tan (jesad09fbbib12) 2021; 2100046 Shi (jesad09fbbib54) 2017; 121 Morales-Ugarte (jesad09fbbib56) 2018; 122 Cho (jesad09fbbib22) 2012; 198 An (jesad09fbbib13) 2016; 105 Momma (jesad09fbbib44) 2012; 216 Spotte-Smith (jesad09fbbib16) 2022; 7 Jung (jesad09fbbib41) 2017; 164 Peled (jesad09fbbib3) 1979; 126 Li (jesad09fbbib36) 2021; 13 Chung (jesad09fbbib57) 2021; 369 Santner (jesad09fbbib34) 2003; 119–121 Xu (jesad09fbbib28) 2009; 156 Li (jesad09fbbib39) 2018; 30 Vidal (jesad09fbbib21) 2019; 68 Huang (jesad09fbbib46) 2019; 13 Korepp (jesad09fbbib35) 2007; 174 Qian (jesad09fbbib55) 2022; 45 Lim (jesad09fbbib51) 2021; 93 Pathan (jesad09fbbib40) 2019; 1 Frankenberger (jesad09fbbib43) 2019; 5 Wang (jesad09fbbib4) 2018; 4 Zhao (jesad09fbbib6) 2019; 7 Qian (jesad09fbbib7) 2019; 20 Han (jesad09fbbib38) 2020; 13 Xiang (jesad09fbbib29) 2015; 7 Jorcin (jesad09fbbib45) 2006; 51 Soto (jesad09fbbib14) 2015; 27 Rikka (jesad09fbbib11) 2018; 122 Silva (jesad09fbbib24) 2007; 806 Shi (jesad09fbbib30) 2019; 429 Lee (jesad09fbbib52) 2017; 8 Petzl (jesad09fbbib20) 2015; 275 Seo (jesad09fbbib50) 2015; 119 Zhao (jesad09fbbib23) 2014; 161 Zhang (jesad09fbbib26) 2021; 2 |
References_xml | – volume: 118 start-page: 10874 year: 2014 ident: jesad09fbbib18 publication-title: J. Phys. Chem. C doi: 10.1021/jp5018696 contributor: fullname: Takenaka – volume: 119 start-page: 14038 year: 2015 ident: jesad09fbbib50 publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.5b03694 contributor: fullname: Seo – volume: 174 start-page: 387 year: 2007 ident: jesad09fbbib49 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2007.06.141 contributor: fullname: Kern – volume: 68 start-page: 4560 year: 2019 ident: jesad09fbbib21 publication-title: IEEE Trans. Veh. Technol. doi: 10.1109/TVT.2019.2906487 contributor: fullname: Vidal – volume: 275 start-page: 799 year: 2015 ident: jesad09fbbib20 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2014.11.065 contributor: fullname: Petzl – volume: 7 start-page: 12464 year: 2017 ident: jesad09fbbib53 publication-title: RSC Adv. doi: 10.1039/C6RA28745J contributor: fullname: Ederer – volume: 1 year: 2019 ident: jesad09fbbib40 publication-title: J. Phys.: Energy contributor: fullname: Pathan – volume: 156 start-page: A751 year: 2009 ident: jesad09fbbib28 publication-title: J. Electrochem. Soc. doi: 10.1149/1.3166182 contributor: fullname: Xu – volume: 51 start-page: 1473 year: 2006 ident: jesad09fbbib45 publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2005.02.128 contributor: fullname: Jorcin – volume: 476 year: 2020 ident: jesad09fbbib33 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2020.228697 contributor: fullname: Zhu – volume: 554 year: 2023 ident: jesad09fbbib37 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2022.232337 contributor: fullname: Li – volume: 7 start-page: 8700 year: 2019 ident: jesad09fbbib6 publication-title: J. Mater. Chem. A doi: 10.1039/C9TA00126C contributor: fullname: Zhao – volume: 143 start-page: 13245 year: 2021 ident: jesad09fbbib17 publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.1c05807 contributor: fullname: Xie – volume: 594 year: 2020 ident: jesad09fbbib31 publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2019.117456 contributor: fullname: Hosseinioun – volume: 2100046 start-page: 1 year: 2021 ident: jesad09fbbib12 publication-title: Adv. Energy Mater. contributor: fullname: Tan – volume: 32 start-page: 2341 year: 2020 ident: jesad09fbbib1 publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.9b04550 contributor: fullname: Hobold – volume: 13 start-page: 5497 year: 2020 ident: jesad09fbbib38 publication-title: ChemSusChem doi: 10.1002/cssc.202001423 contributor: fullname: Han – volume: 122 start-page: 18223 year: 2018 ident: jesad09fbbib56 publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.8b03636 contributor: fullname: Morales-Ugarte – volume: 265 start-page: 662 year: 2018 ident: jesad09fbbib25 publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2018.01.193 contributor: fullname: Lee – volume: 8 start-page: 1 year: 2018 ident: jesad09fbbib8 publication-title: Adv. Energy Mater. contributor: fullname: Zhang – volume: 93 start-page: 12594 year: 2021 ident: jesad09fbbib51 publication-title: Anal. Chem. doi: 10.1021/acs.analchem.1c02127 contributor: fullname: Lim – volume: 119–121 start-page: 368 year: 2003 ident: jesad09fbbib34 publication-title: J. Power Sources doi: 10.1016/S0378-7753(03)00268-4 contributor: fullname: Santner – volume: 11 start-page: 789 year: 2019 ident: jesad09fbbib15 publication-title: Nat. Chem. doi: 10.1038/s41557-019-0304-z contributor: fullname: Wang – volume: 5 start-page: 71 year: 2019 ident: jesad09fbbib43 publication-title: Batteries doi: 10.3390/batteries5040071 contributor: fullname: Frankenberger – volume: 105 start-page: 52 year: 2016 ident: jesad09fbbib13 publication-title: Carbon doi: 10.1016/j.carbon.2016.04.008 contributor: fullname: An – volume: 806 start-page: 23 year: 2007 ident: jesad09fbbib24 publication-title: J. Mol. Struct. THEOCHEM doi: 10.1016/j.theochem.2006.10.014 contributor: fullname: Silva – volume: 223 start-page: 1395 year: 2009 ident: jesad09fbbib10 publication-title: Zeitschrift fur Phys. Chemie doi: 10.1524/zpch.2009.6086 contributor: fullname: Winter – volume: 7 start-page: 20687 year: 2015 ident: jesad09fbbib29 publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.5b05552 contributor: fullname: Xiang – volume: 20 start-page: 208 year: 2019 ident: jesad09fbbib7 publication-title: Energy Storage Mater. doi: 10.1016/j.ensm.2018.11.015 contributor: fullname: Qian – volume: 13 start-page: 737 year: 2019 ident: jesad09fbbib46 publication-title: ACS Nano doi: 10.1021/acsnano.8b08012 contributor: fullname: Huang – volume: 429 start-page: 67 year: 2019 ident: jesad09fbbib30 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2019.04.113 contributor: fullname: Shi – volume: 216 start-page: 304 year: 2012 ident: jesad09fbbib44 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2012.05.095 contributor: fullname: Momma – volume: 369 year: 2021 ident: jesad09fbbib57 publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2020.137698 contributor: fullname: Chung – volume: 161 start-page: A194 year: 2014 ident: jesad09fbbib23 publication-title: J. Electrochem. Soc. doi: 10.1149/2.095401jes contributor: fullname: Zhao – volume: 123 start-page: 10237 year: 2019 ident: jesad09fbbib5 publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.9b00436 contributor: fullname: Ramasubramanian – volume: 51 start-page: 282 year: 2018 ident: jesad09fbbib27 publication-title: Acc. Chem. Res. doi: 10.1021/acs.accounts.7b00474 contributor: fullname: Xing – volume: 27 start-page: 7990 year: 2015 ident: jesad09fbbib14 publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.5b03358 contributor: fullname: Soto – volume: 164 start-page: A1361 year: 2017 ident: jesad09fbbib41 publication-title: J. Electrochem. Soc. doi: 10.1149/2.0021707jes contributor: fullname: Jung – volume: 8 start-page: 1 year: 2017 ident: jesad09fbbib52 publication-title: Nat. Commun. doi: 10.1038/s41467-016-0009-6 contributor: fullname: Lee – volume: 198 start-page: 273 year: 2012 ident: jesad09fbbib22 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2011.09.111 contributor: fullname: Cho – volume: 34 start-page: 629 year: 2021 ident: jesad09fbbib32 publication-title: Energy Storage Mater. doi: 10.1016/j.ensm.2020.10.012 contributor: fullname: Zhou – volume: 2 start-page: 1747 year: 2021 ident: jesad09fbbib26 publication-title: Mater. Adv. doi: 10.1039/D0MA00847H contributor: fullname: Zhang – volume: 11 start-page: 1 year: 2020 ident: jesad09fbbib47 publication-title: J. Electrochem. Sci. Technol. doi: 10.33961/jecst.2019.00528 contributor: fullname: Choi – volume: 122 start-page: 28717 year: 2018 ident: jesad09fbbib11 publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.8b09210 contributor: fullname: Rikka – volume: 13 start-page: 26023 year: 2021 ident: jesad09fbbib36 publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.1c04607 contributor: fullname: Li – volume: 425 start-page: 121 year: 2019 ident: jesad09fbbib48 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2019.03.068 contributor: fullname: Shafiei Sabet – volume: 30 start-page: 2566 year: 2018 ident: jesad09fbbib39 publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.7b04861 contributor: fullname: Li – volume: 7 start-page: 1446 year: 2022 ident: jesad09fbbib16 publication-title: ACS Energy Lett. doi: 10.1021/acsenergylett.2c00517 contributor: fullname: Spotte-Smith – volume: 169 year: 2022 ident: jesad09fbbib42 publication-title: J. Electrochem. Soc. doi: 10.1149/1945-7111/acad36 contributor: fullname: Kim – volume: 268 start-page: 153 year: 2014 ident: jesad09fbbib19 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2014.06.024 contributor: fullname: Agubra – volume: 56 start-page: 14570 year: 2020 ident: jesad09fbbib2 publication-title: Chem. Commun. doi: 10.1039/D0CC05084A contributor: fullname: Yao – volume: 121 start-page: 14476 year: 2017 ident: jesad09fbbib54 publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.7b04132 contributor: fullname: Shi – volume: 126 start-page: 2047 year: 1979 ident: jesad09fbbib3 publication-title: J. E. Soc. doi: 10.1149/1.2128859 contributor: fullname: Peled – volume: 174 start-page: 628 year: 2007 ident: jesad09fbbib35 publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2007.06.140 contributor: fullname: Korepp – volume: 55 start-page: 6332 year: 2010 ident: jesad09fbbib9 publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2010.05.072 contributor: fullname: Verma – volume: 45 start-page: 14 year: 2022 ident: jesad09fbbib55 publication-title: Energy Storage Mater. doi: 10.1016/j.ensm.2021.11.029 contributor: fullname: Qian – volume: 4 start-page: 15 year: 2018 ident: jesad09fbbib4 publication-title: npj Comput. Mater. doi: 10.1038/s41524-018-0064-0 contributor: fullname: Wang |
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