Comparison on corrosion resistance and surface film of pure Mg and Mg−14Li alloy
To study different corrosion resistances and surface film types of hexagonal close-packed (HCP) pure Mg and body-centered cubic (BCC) Mg−14wt.%Li alloy in 0.1 mol/L NaCl, a series of experiments were conducted, including hydrogen evolution, mass loss, in-situ electrochemical testing combined with Ra...
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| Published in | Transactions of Nonferrous Metals Society of China Vol. 30; no. 9; pp. 2413 - 2423 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
01.09.2020
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| Subjects | |
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| Abstract | To study different corrosion resistances and surface film types of hexagonal close-packed (HCP) pure Mg and body-centered cubic (BCC) Mg−14wt.%Li alloy in 0.1 mol/L NaCl, a series of experiments were conducted, including hydrogen evolution, mass loss, in-situ electrochemical testing combined with Raman spectroscopy and microstructural observation. The results indicate that the corrosion resistance of pure Mg is superior to that of Mg−14Li, and the protective function of the surface films on both magnesium systems is elevated within 16 h of immersion in 0.1 mol/L NaCl. An articulated, thick, and needle-like surface film containing Li2CO3 on Mg−14Li, different from the typically thin, flaky Mg(OH)2 film on pure Mg, is confirmed via scanning electron microscopy (SEM). However, both surface films can be broken down at a high anodic over-potential. Thus, different corrosion resistances of the two Mg systems are ascribed to various protective films forming on their surfaces. |
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| AbstractList | To study different corrosion resistances and surface film types of hexagonal close-packed (HCP) pure Mg and body-centered cubic (BCC) Mg−14wt.%Li alloy in 0.1 mol/L NaCl, a series of experiments were conducted, including hydrogen evolution, mass loss, in-situ electrochemical testing combined with Raman spectroscopy and microstructural observation. The results indicate that the corrosion resistance of pure Mg is superior to that of Mg−14Li, and the protective function of the surface films on both magnesium systems is elevated within 16 h of immersion in 0.1 mol/L NaCl. An articulated, thick, and needle-like surface film containing Li2CO3 on Mg−14Li, different from the typically thin, flaky Mg(OH)2 film on pure Mg, is confirmed via scanning electron microscopy (SEM). However, both surface films can be broken down at a high anodic over-potential. Thus, different corrosion resistances of the two Mg systems are ascribed to various protective films forming on their surfaces. |
| Author | HE, Yi-bin ZHANG, Peng TONG, Zhi-pei HUANG, Huai-pei LI, Chuan-qiang DONG, Yong |
| Author_xml | – sequence: 1 givenname: Chuan-qiang surname: LI fullname: LI, Chuan-qiang email: cqli13s@alum.imr.ac.cn – sequence: 2 givenname: Zhi-pei surname: TONG fullname: TONG, Zhi-pei – sequence: 3 givenname: Yi-bin surname: HE fullname: HE, Yi-bin – sequence: 4 givenname: Huai-pei surname: HUANG fullname: HUANG, Huai-pei – sequence: 5 givenname: Yong surname: DONG fullname: DONG, Yong – sequence: 6 givenname: Peng surname: ZHANG fullname: ZHANG, Peng |
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