Formation of new phosphates from aldehydes by a DBU-catalysed phospha-Brook rearrangement in a polar solvent
Addition of dialkylphosphites to aromatic aldehydes (Pudovik reaction) by treatment with a base results in two different possible reaction pathways depending on the solvent used. Apolar solvents give the normal Pudovik adduct, whereas the use of DBU in a polar solvent allows the formation of a phosp...
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Published in | Synlett no. 15; pp. 2335 - 2336 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
STUTTGART
Thieme Medical Publishers
19.09.2005
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Subjects | |
Online Access | Get more information |
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