Luminescence and self-referenced optical temperature sensing performance in Ca2YZr2Al3O12:Bi3+,Eu3+ phosphors
Ca2YZr2Al3O12:Bi3+,Eu3+ phosphors were elaborated by a traditional solid-state reaction method. The luminescence of Ca2YZr2Al3O12:Bi3+ samples, energy transfer from Bi3+ to Eu3+, and the temperature sensing properties of Ca2YZr2Al3O12:Bi3+,Eu3+ samples have been systematically researched. Under the...
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| Published in | Ceramics international Vol. 46; no. 5; pp. 6154 - 6159 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
01.04.2020
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0272-8842 1873-3956 |
| DOI | 10.1016/j.ceramint.2019.11.081 |
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| Abstract | Ca2YZr2Al3O12:Bi3+,Eu3+ phosphors were elaborated by a traditional solid-state reaction method. The luminescence of Ca2YZr2Al3O12:Bi3+ samples, energy transfer from Bi3+ to Eu3+, and the temperature sensing properties of Ca2YZr2Al3O12:Bi3+,Eu3+ samples have been systematically researched. Under the excitation of ultraviolet light, Bi3+ single doped phosphors give 313 and 392 nm emission bands, which origin from the substitutions of Bi3+ instead of Ca2+ and Y3+ sites, respectively. And the color-adjustable emission from blue to red were observed by increasing Eu3+ content in Ca2YZr2Al3O12:Bi3+,Eu3+ samples. Relying on different temperature dependent variation tendency, the fluorescence intensity ratio (FIR) values present outstanding temperature sensing properties. The absolute and relative sensitivity can be up to 0.826 %K-1 and 0.664 %K-1, respectively. All above results suggest that Ca2YZr2Al3O12:Bi3+,Eu3+ phosphor is a potential alternative for optical thermometer. |
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| AbstractList | Ca2YZr2Al3O12:Bi3+,Eu3+ phosphors were elaborated by a traditional solid-state reaction method. The luminescence of Ca2YZr2Al3O12:Bi3+ samples, energy transfer from Bi3+ to Eu3+, and the temperature sensing properties of Ca2YZr2Al3O12:Bi3+,Eu3+ samples have been systematically researched. Under the excitation of ultraviolet light, Bi3+ single doped phosphors give 313 and 392 nm emission bands, which origin from the substitutions of Bi3+ instead of Ca2+ and Y3+ sites, respectively. And the color-adjustable emission from blue to red were observed by increasing Eu3+ content in Ca2YZr2Al3O12:Bi3+,Eu3+ samples. Relying on different temperature dependent variation tendency, the fluorescence intensity ratio (FIR) values present outstanding temperature sensing properties. The absolute and relative sensitivity can be up to 0.826 %K-1 and 0.664 %K-1, respectively. All above results suggest that Ca2YZr2Al3O12:Bi3+,Eu3+ phosphor is a potential alternative for optical thermometer. |
| Author | Hu, Fangfang Zhang, Jiafei Guo, Hai Wei, Rongfei Zheng, Zhigang Liu, Xueyun |
| Author_xml | – sequence: 1 givenname: Zhigang surname: Zheng fullname: Zheng, Zhigang organization: Department of Physics, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China – sequence: 2 givenname: Jiafei surname: Zhang fullname: Zhang, Jiafei organization: Department of Physics, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China – sequence: 3 givenname: Xueyun surname: Liu fullname: Liu, Xueyun organization: Laboratory of Infrared Material and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo, 315211, China – sequence: 4 givenname: Rongfei surname: Wei fullname: Wei, Rongfei organization: Department of Physics, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China – sequence: 5 givenname: Fangfang surname: Hu fullname: Hu, Fangfang organization: Department of Physics, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China – sequence: 6 givenname: Hai surname: Guo fullname: Guo, Hai email: ghh@zjnu.cn organization: Department of Physics, Zhejiang Normal University, Jinhua, Zhejiang, 321004, China |
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| Snippet | Ca2YZr2Al3O12:Bi3+,Eu3+ phosphors were elaborated by a traditional solid-state reaction method. The luminescence of Ca2YZr2Al3O12:Bi3+ samples, energy transfer... |
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| SubjectTerms | Energy transfer Phosphors Temperature sensing |
| Title | Luminescence and self-referenced optical temperature sensing performance in Ca2YZr2Al3O12:Bi3+,Eu3+ phosphors |
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