A new squalene-derived epoxy tri-THF diol from Spathelia glabrescens
A new triterpenoid polyether containing three THF rings and an epoxide has been isolated from Spathelia glabrescens and the structure determined by NMR methods. Graphic
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Published in | Tetrahedron letters Vol. 42; no. 42; pp. 7379 - 7381 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
15.10.2001
Elsevier |
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Abstract | A new triterpenoid polyether containing three THF rings and an epoxide has been isolated from
Spathelia glabrescens and the structure determined by NMR methods.
Graphic |
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AbstractList | A new triterpenoid polyether containing three THF rings and an epoxide has been isolate from Spathelia glabrescens and the structure determined by NMR methods. (C) 2001 Elsevier Science Ltd. All rights reserved. A new triterpenoid polyether containing three THF rings and an epoxide has been isolated from Spathelia glabrescens and the structure determined by NMR methods. Graphic |
Author | Harding, Wayne W Simpson, Denise S Jacobs, Helen Reynolds, William F McLean, Stewart |
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Cites_doi | 10.1021/ja0007657 10.1016/S0960-894X(98)00347-3 10.1016/0040-4020(95)00762-W 10.1016/0040-4039(95)01957-J 10.1016/S0040-4020(98)01036-9 10.1016/0031-9422(93)85356-V 10.1002/1521-3773(20000717)39:14<2552::AID-ANIE2552>3.0.CO;2-D 10.1016/S0040-4020(97)10124-7 10.1016/S0031-9422(00)90854-9 10.1016/S0040-4020(97)00124-5 10.1021/ja000842y |
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Keywords | polyether NMR squalene natural product epoxide TRITERPENOIDS |
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Stereoselective synthesis of reported glabrescol publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION contributor: fullname: Hioki, H – volume: 53 start-page: 16891 year: 1997 ident: WOS:A1997YG78600024 article-title: Testudinariol A and B, two unusual triterpenoids from the skin and the mucus of the marine mollusc Pleurobrancus testudinarius publication-title: TETRAHEDRON contributor: fullname: Spinella, A – volume: 34 start-page: 765 year: 1993 ident: WOS:A1993MC47300035 article-title: SQUALENE DERIVATIVES FROM EURYCOMA-LONGIFOLIA publication-title: PHYTOCHEMISTRY contributor: fullname: MORITA, H – volume: 53 start-page: 4649 year: 1997 ident: WOS:A1997WQ93500012 article-title: New polyether squalene derivatives from Laurencia publication-title: TETRAHEDRON contributor: fullname: Norte, M – volume: 55 start-page: 167 year: 1999 ident: WOS:000077634800009 article-title: Two terpenoid diepoxides from the green microalga Botryococcus braunii: their biomimetic conversion to tetrahydrofurans and tetrahydropyrans publication-title: TETRAHEDRON contributor: fullname: Metzger, P – volume: 34 start-page: 1603 year: 1993 ident: WOS:A1993MN64800027 article-title: SAPELENINS A,B AND C, ACYCLIC TRITERPENOIDS FROM THE STEM BARK OF ENTANDROPHRAGMA-CYLINDRICUM publication-title: PHYTOCHEMISTRY contributor: fullname: NGNOKAM, D – volume: 8 start-page: 2005 year: 1998 ident: WOS:000075279900014 article-title: Diastereoselective two-directional synthesis and cation transport ability of the central tristetrahydrofuranyl unit of meso polyether glabrescol as naturally occurring podand publication-title: BIOORGANIC & MEDICINAL CHEMISTRY LETTERS contributor: fullname: Morimoto, Y – volume: 122 start-page: 7124 year: 2000 ident: WOS:000088522700040 article-title: Revised structure of squalene-derived PentaTHF polyether, glabrescol, through its enantioselective total synthesis: Biogenetically intriguing C-s vs C-2 symmetric relationships publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja0007657 contributor: fullname: Morimoto, Y – volume: 122 start-page: 4831 year: 2000 ident: WOS:000087118100044 article-title: Simple total synthesis of the pentacyclic C-s-symmetric structure attributed to the squalenoid glabrescol and three C-s-symmetric diastereomers compel structural revision publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: Xiong, ZM – volume: 36 start-page: 9137 year: 1995 ident: WOS:A1995TJ83200014 article-title: GLABRESCOL - A UNIQUE SQUALENE-DERIVED PENTA-THF DIOL FROM SPATHELIA-GLABRESCENS (RUTACEAE) publication-title: TETRAHEDRON LETTERS contributor: fullname: HARDING, WW – volume: 51 start-page: 11959 year: 1995 ident: WOS:A1995TA95200005 article-title: QUASSIOLS B-D, NEW SQUALENE TRITERPENES FROM QUASSIA-MULTIFLORA publication-title: TETRAHEDRON contributor: fullname: MILLER, SL – volume: 8 start-page: 2005 year: 1998 ident: 10.1016/S0040-4039(01)01578-7_BIB2 publication-title: Bioorg. 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Ed. doi: 10.1002/1521-3773(20000717)39:14<2552::AID-ANIE2552>3.0.CO;2-D contributor: fullname: Hioki – volume: 53 start-page: 16891 year: 1997 ident: 10.1016/S0040-4039(01)01578-7_BIB9 publication-title: Tetrahedron doi: 10.1016/S0040-4020(97)10124-7 contributor: fullname: Spinella – volume: 34 start-page: 1603 year: 1993 ident: 10.1016/S0040-4039(01)01578-7_BIB10 publication-title: Phytochemistry doi: 10.1016/S0031-9422(00)90854-9 contributor: fullname: Ngnokam – volume: 53 start-page: 4649 year: 1997 ident: 10.1016/S0040-4039(01)01578-7_BIB8 publication-title: Tetrahedron doi: 10.1016/S0040-4020(97)00124-5 contributor: fullname: Norte – volume: 122 start-page: 7124 year: 2000 ident: 10.1016/S0040-4039(01)01578-7_BIB4 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0007657 contributor: fullname: Morimoto – volume: 122 start-page: 4831 year: 2000 ident: 10.1016/S0040-4039(01)01578-7_BIB5 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja000842y contributor: fullname: Corey |
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Snippet | A new triterpenoid polyether containing three THF rings and an epoxide has been isolated from
Spathelia glabrescens and the structure determined by NMR... A new triterpenoid polyether containing three THF rings and an epoxide has been isolate from Spathelia glabrescens and the structure determined by NMR methods.... |
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SubjectTerms | Chemistry Chemistry, Organic epoxide natural product NMR Physical Sciences polyether Science & Technology squalene |
Title | A new squalene-derived epoxy tri-THF diol from Spathelia glabrescens |
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