Kinetics and mechanism of complex formation: the reaction of nickel(II) with 1,4,7-triazacyclononane- N, N′, N″-triacetic acid

• Published in: Inorganica Chimica Acta Vol. 251; no. 1; pp. 347 - 354
• Main Authors: Größ, Stefan, Elias, Horst
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.10.1996
• Subjects: Azamacrocyclic ligand complexes; Kinetics and mechanism; Nickel(II) complexes; Kinetics and mechanism; Nickel(II) complexes; Azamacrocyclic ligand complexes

Conventional and multi wavelength stopped-flow spectrophotometry was used to study the kinetics of the reaction of Ni 2+ ions with the hexadentate macrocyclic ligand TCTA (1,4,7- triazacyclononane- N, N′, N″-triacetic acid) to yield the complex Ni(TCTA) −. The experiments were carried out at variabl...