Enhancement of graphite surface mechanical properties using carbon film from polymer precursor
A hard carbon film can be converted from poly(phenylcarbyne) polymer precursor by a simple and economic process in the temperature range 800–1200°C at 1 atm pressure of an inert gas. The polymer is easily soluble in organic solvents, which can be coated on a complex shape with large area. Under heat...
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| Published in | Surface & coatings technology Vol. 122; no. 2; pp. 277 - 280 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
15.12.1999
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| Subjects | |
| Online Access | Get full text |
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| Abstract | A hard carbon film can be converted from poly(phenylcarbyne) polymer precursor by a simple and economic process in the temperature range 800–1200°C at 1
atm pressure of an inert gas. The polymer is easily soluble in organic solvents, which can be coated on a complex shape with large area. Under heat-treatment at high temperature (above 800°C) for 2
h, the polymer film on graphite substrate converted into hard carbon film with a hardness of about 8
GPa, which greatly improved the surface hardness of graphite substrate, with a hardness of about 0.3
GPa. |
|---|---|
| AbstractList | A hard carbon film can be converted from poly(phenylcarbyne) polymer precursor by a simple and economic process in the temperature range 800–1200°C at 1
atm pressure of an inert gas. The polymer is easily soluble in organic solvents, which can be coated on a complex shape with large area. Under heat-treatment at high temperature (above 800°C) for 2
h, the polymer film on graphite substrate converted into hard carbon film with a hardness of about 8
GPa, which greatly improved the surface hardness of graphite substrate, with a hardness of about 0.3
GPa. |
| Author | Jia, W.B. Sun, Z. Shi, X. |
| Author_xml | – sequence: 1 givenname: Z. surname: Sun fullname: Sun, Z. email: ezsun@ntu.edu.sg organization: School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 6397798, Singapore – sequence: 2 givenname: W.B. surname: Jia fullname: Jia, W.B. organization: Department of Modern Physics, Lanzhou University, Lanzhou 730000, People's Republic of China – sequence: 3 givenname: X. surname: Shi fullname: Shi, X. organization: School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 6397798, Singapore |
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| CitedBy_id | crossref_primary_10_1016_S0378_7753_01_00909_0 crossref_primary_10_1016_j_actamat_2023_119439 crossref_primary_10_1016_j_jallcom_2013_03_213 crossref_primary_10_1016_j_bios_2012_03_007 crossref_primary_10_1080_10601320801946108 crossref_primary_10_1016_S0040_6090_00_01923_4 crossref_primary_10_1016_j_surfcoat_2009_06_027 crossref_primary_10_1021_cr9002819 |
| Cites_doi | 10.1126/science.260.5113.1496 10.1016/0925-9635(92)90137-D 10.1016/0257-8972(95)02462-X 10.1116/1.575297 10.1557/JMR.1992.1564 10.1016/S0925-9635(99)00009-6 10.1016/S0925-9635(96)00620-6 10.1103/PhysRevB.41.3738 |
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| References | Shroder, Nemanich, Glass (REF9) 1990; 41 Robertson (REF2) 1992; 1 Sun, Sun, Yang, Wang, Zheng (REF3) 1996; 79 Sun, Shi, Wang, Sun (REF5) 1999; 8 Sun, Shi, Tay, Flynn, Wang, Zheng, Sun (REF4) 1997; 6 Vissclier, Nesting, Badding, Bianconi (REF6) 1993; 260 Nemanich, Glass, Lucovsky, Shroder (REF8) 1988; 6 Oliver, Pharr (REF7) 1992; 7 Page (REF1) 1991 Sun (10.1016/S0257-8972(99)00379-5_REF3) 1996; 79 Nemanich (10.1016/S0257-8972(99)00379-5_REF8) 1988; 6 Robertson (10.1016/S0257-8972(99)00379-5_REF2) 1992; 1 Sun (10.1016/S0257-8972(99)00379-5_REF5) 1999; 8 Page (10.1016/S0257-8972(99)00379-5_REF1) 1991 Shroder (10.1016/S0257-8972(99)00379-5_REF9) 1990; 41 Oliver (10.1016/S0257-8972(99)00379-5_REF7) 1992; 7 Sun (10.1016/S0257-8972(99)00379-5_REF4) 1997; 6 Vissclier (10.1016/S0257-8972(99)00379-5_REF6) 1993; 260 |
| References_xml | – volume: 79 start-page: 108 year: 1996 ident: REF3 publication-title: Surf. Coat. Technol. contributor: fullname: Zheng – volume: 6 start-page: 230 year: 1997 ident: REF4 publication-title: Diamond Relat. Mater. contributor: fullname: Sun – volume: 8 start-page: 1107 year: 1999 ident: REF5 publication-title: Diamond Relat. Mater. contributor: fullname: Sun – volume: 1 start-page: 397 year: 1992 ident: REF2 publication-title: Diamond Relat. Mater. contributor: fullname: Robertson – volume: 260 start-page: 1496 year: 1993 ident: REF6 publication-title: Science contributor: fullname: Bianconi – volume: 6 start-page: 1783 year: 1988 ident: REF8 publication-title: J. Vac. Sci. Technol. A contributor: fullname: Shroder – volume: 7 start-page: 1564 year: 1992 ident: REF7 publication-title: J. Mater. Res. contributor: fullname: Pharr – year: 1991 ident: REF1 publication-title: Industrial Graphite Engineering Handbook contributor: fullname: Page – volume: 41 start-page: 3738 year: 1990 ident: REF9 publication-title: Phys. Rev. B contributor: fullname: Glass – year: 1991 ident: 10.1016/S0257-8972(99)00379-5_REF1 contributor: fullname: Page – volume: 260 start-page: 1496 year: 1993 ident: 10.1016/S0257-8972(99)00379-5_REF6 publication-title: Science doi: 10.1126/science.260.5113.1496 contributor: fullname: Vissclier – volume: 1 start-page: 397 year: 1992 ident: 10.1016/S0257-8972(99)00379-5_REF2 publication-title: Diamond Relat. Mater. doi: 10.1016/0925-9635(92)90137-D contributor: fullname: Robertson – volume: 79 start-page: 108 year: 1996 ident: 10.1016/S0257-8972(99)00379-5_REF3 publication-title: Surf. Coat. Technol. doi: 10.1016/0257-8972(95)02462-X contributor: fullname: Sun – volume: 6 start-page: 1783 year: 1988 ident: 10.1016/S0257-8972(99)00379-5_REF8 publication-title: J. Vac. Sci. Technol. A doi: 10.1116/1.575297 contributor: fullname: Nemanich – volume: 7 start-page: 1564 year: 1992 ident: 10.1016/S0257-8972(99)00379-5_REF7 publication-title: J. Mater. Res. doi: 10.1557/JMR.1992.1564 contributor: fullname: Oliver – volume: 8 start-page: 1107 year: 1999 ident: 10.1016/S0257-8972(99)00379-5_REF5 publication-title: Diamond Relat. Mater. doi: 10.1016/S0925-9635(99)00009-6 contributor: fullname: Sun – volume: 6 start-page: 230 year: 1997 ident: 10.1016/S0257-8972(99)00379-5_REF4 publication-title: Diamond Relat. Mater. doi: 10.1016/S0925-9635(96)00620-6 contributor: fullname: Sun – volume: 41 start-page: 3738 year: 1990 ident: 10.1016/S0257-8972(99)00379-5_REF9 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.41.3738 contributor: fullname: Shroder |
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| Title | Enhancement of graphite surface mechanical properties using carbon film from polymer precursor |
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