Oxidative fluorination of some organoantimony and organotellurium compounds by 2-hydroperfluoropropyl azide

Triphenylantimony and diphenyltellurium are readily oxidatively fluorinated by 2-hydroperfluoropropyl azide, CF 3CHFCF 2N 3, to form appropriate difluorides from moderate to high yields.

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Bibliographic Details
Published inJournal of fluorine chemistry Vol. 94; no. 1; pp. 43 - 45
Main Authors Lermontov, Sergei A., Shkavrov, Sergei V., Lermontov, Anatoly S., Zavelsky, Vladimir O., Zefirov, Nikolai S.
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 11.02.1999
Elsevier
Subjects
2-Hydroperfluoropropyl azide
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Diphenyltellurium difluoride
Oxidative fluorination
Physical Sciences
Science & Technology
Triphenylantimony difluoride
Triphenylantimony difluoride
Oxidative fluorination
2-Hydroperfluoropropyl azide
Diphenyltellurium difluoride
oxidative fluorination
XENON DIFLUORIDE
REAGENTS
ORGANIC-COMPOUNDS
AGENTS
2-hydroperfluoropropyl azide
diphenyltellurium difluoride
triphenylantimony difluoride
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Summary:Triphenylantimony and diphenyltellurium are readily oxidatively fluorinated by 2-hydroperfluoropropyl azide, CF 3CHFCF 2N 3, to form appropriate difluorides from moderate to high yields.
ISSN:0022-1139
1873-3328
DOI:10.1016/S0022-1139(98)00335-2