Reactions of [(Me 3SiNCH 2CH 2) 3N]WH with dihydrogen, olefins, acetylenes, carbon monoxide, n-butylisocyanide and azobenzene

Dihydrogen reacts slowly with [N 3N]WH ([N 3N] 3−[(Me 3SiNCH 2CH 2) 3N] 3−) in benzene at 22°C to form white, crystalline, diamagnetic [N 3N]WH 3 quantitatively. [N 3N]WH in C 6D 6 reacts with ethylene to produced [N 3N]WCMe quantitatively, while the reaction between [N 3N]WH and propylene at 45°C...

Full description

Saved in:
Bibliographic Details
Published inInorganica Chimica Acta Vol. 263; no. 1; pp. 171 - 180
Main Authors Dobbs, Daniel A., Schrock, Richard R., Davis, William M.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.10.1997
Subjects
Crystal structures
Triamidoamine complexes
Tungsten complexes
Crystal structures
Triamidoamine complexes
Tungsten complexes
Online AccessGet full text

Cover

Abstract Dihydrogen reacts slowly with [N 3N]WH ([N 3N] 3−[(Me 3SiNCH 2CH 2) 3N] 3−) in benzene at 22°C to form white, crystalline, diamagnetic [N 3N]WH 3 quantitatively. [N 3N]WH in C 6D 6 reacts with ethylene to produced [N 3N]WCMe quantitatively, while the reaction between [N 3N]WH and propylene at 45°C for 24 h produces a mixture of [N 3N]WCCH 2CH 3 and [N 3N]WH 3. Addition of 1 equiv. of diphenylacetylene to [N 3N]WH gives the diamagnetic ‘tungstacyclopropene’ complex, [N 3N]W(CPhCHPh). Heating a mixture of [N 3N]WH and 1 equiv. of azobenzene to 75°C produces the green azobenzene adduct, [N 3N]W(H)(PhNNPh), while [N 3N]WH reacts with 1 equiv. of carbon monoxide at 0°C to produce [N 3N]W(H)(CO). Upon addition of trimethylamine to a mixture of [N 3N]W(H)(CO) and Me 3SiI, colorless [N 3N]WCOTMS is formed. [N 3N]WH reacts with 1 equiv. of n-butylisocyanide at −20° to yield diamagnetic [N 3N]W(H)(BuNC). The structures of [N 3N]WH 3, [N 3N]W(PhCCHPh), [N 3N]W(H)(PhNNPh) and [N 3N]W(H)(CO) have been determined via X-ray crystallography.
AbstractList Dihydrogen reacts slowly with [N 3N]WH ([N 3N] 3−[(Me 3SiNCH 2CH 2) 3N] 3−) in benzene at 22°C to form white, crystalline, diamagnetic [N 3N]WH 3 quantitatively. [N 3N]WH in C 6D 6 reacts with ethylene to produced [N 3N]WCMe quantitatively, while the reaction between [N 3N]WH and propylene at 45°C for 24 h produces a mixture of [N 3N]WCCH 2CH 3 and [N 3N]WH 3. Addition of 1 equiv. of diphenylacetylene to [N 3N]WH gives the diamagnetic ‘tungstacyclopropene’ complex, [N 3N]W(CPhCHPh). Heating a mixture of [N 3N]WH and 1 equiv. of azobenzene to 75°C produces the green azobenzene adduct, [N 3N]W(H)(PhNNPh), while [N 3N]WH reacts with 1 equiv. of carbon monoxide at 0°C to produce [N 3N]W(H)(CO). Upon addition of trimethylamine to a mixture of [N 3N]W(H)(CO) and Me 3SiI, colorless [N 3N]WCOTMS is formed. [N 3N]WH reacts with 1 equiv. of n-butylisocyanide at −20° to yield diamagnetic [N 3N]W(H)(BuNC). The structures of [N 3N]WH 3, [N 3N]W(PhCCHPh), [N 3N]W(H)(PhNNPh) and [N 3N]W(H)(CO) have been determined via X-ray crystallography.
Author Dobbs, Daniel A.
Schrock, Richard R.
Davis, William M.
Author_xml – sequence: 1
  givenname: Daniel A.
  surname: Dobbs
  fullname: Dobbs, Daniel A.
– sequence: 2
  givenname: Richard R.
  surname: Schrock
  fullname: Schrock, Richard R.
– sequence: 3
  givenname: William M.
  surname: Davis
  fullname: Davis, William M.
BookMark eNqFkFtLAzEQhYNUsK3-BCGPLXQ12ewtTyJFrVArWMUHkZBNJjbSJrJZL1vwv7ttxVcfhjPMzDkMXw91nHeA0DElJ5TQ7HROSEwimnE24PmQpFmSR8Ue6tIiZxGL07SDun8nB6gXwishjGQs7aLvO5Cqtt4F7A1-GtwAZnM7G09wvKkhZrPnxwn-tPUCa7todOVfwI2wX4KxLoywVFA3S3DQ9kpWpXd45Z3_shpG2EXle7u1watGunaEpdNYrn0Jbt16DtG-kcsAR7_aRw-XF_fjSTS9vboen08jxUheRxnJioQWZVwyw1liCOc0iZM0bRvNjaaEZGnBckZZEhdMgpaloa3EueSxoqyP0l2uqnwIFRjxVtmVrBpBidgwFFuGYgNI8FxsGYqi9Z3tfNA-92GhEkFZcAq0rUDVQnv7T8IPDtp5Ow
CitedBy_id crossref_primary_10_1021_ic800945m
crossref_primary_10_1021_om970966s
crossref_primary_10_1021_jacs_9b10304
crossref_primary_10_1139_v05_013
crossref_primary_10_1039_C6DT01848C
crossref_primary_10_1002_ange_200352177
crossref_primary_10_1021_ja049346q
crossref_primary_10_1021_ic040095w
crossref_primary_10_1021_ic0613457
crossref_primary_10_1002_chem_200390145
crossref_primary_10_1021_om050373e
crossref_primary_10_1016_S0022_328X_00_00711_7
crossref_primary_10_1016_S0022_328X_00_00310_7
crossref_primary_10_1016_j_ccr_2017_06_019
crossref_primary_10_1016_S0010_8545_00_00269_1
crossref_primary_10_1021_ic900468n
crossref_primary_10_1021_jacs_6b04307
crossref_primary_10_1021_om990748u
crossref_primary_10_1021_ic001122v
crossref_primary_10_1021_om980220
crossref_primary_10_1021_ja983902x
crossref_primary_10_1016_j_jorganchem_2011_06_006
crossref_primary_10_1039_C5SC03490F
crossref_primary_10_1002_anie_200352177
crossref_primary_10_1039_C7DT04859A
Cites_doi 10.1021/ja00089a028
10.1021/ja963822y
10.1021/ic00110a040
10.1021/ja960639w
10.1002/anie.199520441
10.1021/ar950195t
10.1021/cr00019a008
10.1021/ar00027a003
10.1021/ic00037a003
10.1021/om00042a034
10.1021/ic960889d
10.1021/ja00098a048
10.1021/ja00105a081
10.1002/9780470166406.ch1
10.1021/ja00017a030
10.1021/ar00033a005
10.1021/ja00129a032
10.1021/ja961405f
10.1016/0022-328X(96)06264-X
ContentType Journal Article
Copyright 1997
Copyright_xml – notice: 1997
DBID AAYXX
CITATION
DOI 10.1016/S0020-1693(97)05647-8
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1873-3255
EndPage 180
ExternalDocumentID 10_1016_S0020_1693_97_05647_8
S0020169397056478
GroupedDBID AAYXX
CITATION
ID FETCH-LOGICAL-c307t-6068418b2b3f934f099142455099d9fd100658373134283aedabf1aed27a92c13
IEDL.DBID .~1
ISSN 0020-1693
IngestDate Fri Aug 23 02:48:08 EDT 2024
Thu Aug 18 19:12:54 EDT 2022
IsPeerReviewed true
IsScholarly true
Issue 1
Keywords Crystal structures
Triamidoamine complexes
Tungsten complexes
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c307t-6068418b2b3f934f099142455099d9fd100658373134283aedabf1aed27a92c13
PageCount 10
ParticipantIDs crossref_primary_10_1016_S0020_1693_97_05647_8
elsevier_sciencedirect_doi_10_1016_S0020_1693_97_05647_8
PublicationCentury 1900
PublicationDate 1997-10-15
PublicationDateYYYYMMDD 1997-10-15
PublicationDate_xml – month: 10
  year: 1997
  text: 1997-10-15
  day: 15
PublicationDecade 1990
PublicationTitle Inorganica Chimica Acta
PublicationYear 1997
Publisher Elsevier B.V
Publisher_xml – name: Elsevier B.V
References Johnson-Carr, Zanetti, Schrock, Hopkins (BIB7) 1996; 118
Zanetti, Schrock, Davis (BIB6) 1995; 34
Schrock, Shih, Dobbs, Davis (BIB9) 1995; 117
R.R. Schrock, S.W. Seidel, N.C. Zanetti, K.-Y. Shih and W.M. Davis, unpublished results.
Glassman, Vale, Schrock (BIB18) 1992; 31
Wu, Rovnyak, Johnson, Zanetti, Musaev, Morokuma, Schrock, Griffin, Cummins (BIB8) 1996; 118
Feng, Templeton (BIB15) 1992; 11
Shih, Schrock, Kempe (BIB4) 1994; 116
Kol, Schrock, Kempe, Davis (BIB3) 1994; 116
Protasiewicz, Lippard (BIB21) 1991; 113
Shih, Totland, Seidel, Schrock (BIB10) 1994; 116
Rosenberger, Schrock, Davis (BIB11) 1997; 36
Feldman, Schrock (BIB16) 1991; 39
Murdzek, Schrock (BIB20) 1988
Toreki, Schrock, Davis (BIB12) 1996; 520
Carnahan, Protasiewicz, Lippard (BIB22) 1993; 26
Suiton (BIB17) 1993; 93
Schrock (BIB1) 1997; 30
Duan, Verkade (BIB13) 1995; 34
Nugent, Mayer (BIB19) 1988
Verkade (BIB2) 1993; 26
O'Donoghue, Zanetti, Schrock, Davis (BIB5) 1997; 119
Shih (10.1016/S0020-1693(97)05647-8_BIB4) 1994; 116
Toreki (10.1016/S0020-1693(97)05647-8_BIB12) 1996; 520
Glassman (10.1016/S0020-1693(97)05647-8_BIB18) 1992; 31
Murdzek (10.1016/S0020-1693(97)05647-8_BIB20) 1988
Schrock (10.1016/S0020-1693(97)05647-8_BIB9) 1995; 117
Rosenberger (10.1016/S0020-1693(97)05647-8_BIB11) 1997; 36
Wu (10.1016/S0020-1693(97)05647-8_BIB8) 1996; 118
Suiton (10.1016/S0020-1693(97)05647-8_BIB17) 1993; 93
Schrock (10.1016/S0020-1693(97)05647-8_BIB1) 1997; 30
Verkade (10.1016/S0020-1693(97)05647-8_BIB2) 1993; 26
Duan (10.1016/S0020-1693(97)05647-8_BIB13) 1995; 34
O'Donoghue (10.1016/S0020-1693(97)05647-8_BIB5) 1997; 119
Johnson-Carr (10.1016/S0020-1693(97)05647-8_BIB7) 1996; 118
10.1016/S0020-1693(97)05647-8_BIB14
Zanetti (10.1016/S0020-1693(97)05647-8_BIB6) 1995; 34
Carnahan (10.1016/S0020-1693(97)05647-8_BIB22) 1993; 26
Feng (10.1016/S0020-1693(97)05647-8_BIB15) 1992; 11
Feldman (10.1016/S0020-1693(97)05647-8_BIB16) 1991; 39
Kol (10.1016/S0020-1693(97)05647-8_BIB3) 1994; 116
Nugent (10.1016/S0020-1693(97)05647-8_BIB19) 1988
Shih (10.1016/S0020-1693(97)05647-8_BIB10) 1994; 116
Protasiewicz (10.1016/S0020-1693(97)05647-8_BIB21) 1991; 113
References_xml – volume: 116
  start-page: 12103
  year: 1994
  ident: BIB10
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Schrock
– volume: 119
  start-page: 2753
  year: 1997
  ident: BIB5
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Davis
– volume: 93
  start-page: 995
  year: 1993
  ident: BIB17
  publication-title: Chem. Rev.
  contributor:
    fullname: Suiton
– volume: 36
  start-page: 123
  year: 1997
  ident: BIB11
  publication-title: Inorg. Chem.
  contributor:
    fullname: Davis
– volume: 30
  start-page: 9
  year: 1997
  ident: BIB1
  publication-title: Acc. Chem. Res.
  contributor:
    fullname: Schrock
– volume: 520
  start-page: 69
  year: 1996
  ident: BIB12
  publication-title: J. Organomet. Chem.
  contributor:
    fullname: Davis
– volume: 34
  start-page: 1576
  year: 1995
  ident: BIB13
  publication-title: Inorg. Chem.
  contributor:
    fullname: Verkade
– volume: 39
  start-page: 1
  year: 1991
  ident: BIB16
  publication-title: Prog. Inorg. Chem.
  contributor:
    fullname: Schrock
– volume: 118
  start-page: 11305
  year: 1996
  ident: BIB7
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Hopkins
– year: 1988
  ident: BIB19
  article-title: Metal-Ligand Multiple Bonds
  contributor:
    fullname: Mayer
– volume: 11
  start-page: 2168
  year: 1992
  ident: BIB15
  publication-title: Organometallics
  contributor:
    fullname: Templeton
– volume: 118
  start-page: 10654
  year: 1996
  ident: BIB8
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Cummins
– volume: 117
  start-page: 6609
  year: 1995
  ident: BIB9
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Davis
– volume: 31
  start-page: 1985
  year: 1992
  ident: BIB18
  publication-title: Inorg. Chem.
  contributor:
    fullname: Schrock
– volume: 26
  start-page: 483
  year: 1993
  ident: BIB2
  publication-title: Acc. Chem. Res.
  contributor:
    fullname: Verkade
– volume: 113
  start-page: 6564
  year: 1991
  ident: BIB21
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Lippard
– volume: 116
  start-page: 4382
  year: 1994
  ident: BIB3
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Davis
– start-page: 147
  year: 1988
  ident: BIB20
  article-title: High Oxidation State Alkylidyne Complexes
  contributor:
    fullname: Schrock
– volume: 34
  start-page: 2044
  year: 1995
  ident: BIB6
  publication-title: Angew. Chem., Int. Ed. Engl.
  contributor:
    fullname: Davis
– volume: 26
  start-page: 97
  year: 1993
  ident: BIB22
  publication-title: Acc. Chem. Res.
  contributor:
    fullname: Lippard
– volume: 116
  start-page: 8804
  year: 1994
  ident: BIB4
  publication-title: J. Am. Chem. Soc.
  contributor:
    fullname: Kempe
– volume: 116
  start-page: 4382
  year: 1994
  ident: 10.1016/S0020-1693(97)05647-8_BIB3
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00089a028
  contributor:
    fullname: Kol
– volume: 119
  start-page: 2753
  year: 1997
  ident: 10.1016/S0020-1693(97)05647-8_BIB5
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja963822y
  contributor:
    fullname: O'Donoghue
– volume: 34
  start-page: 1576
  year: 1995
  ident: 10.1016/S0020-1693(97)05647-8_BIB13
  publication-title: Inorg. Chem.
  doi: 10.1021/ic00110a040
  contributor:
    fullname: Duan
– volume: 118
  start-page: 10654
  year: 1996
  ident: 10.1016/S0020-1693(97)05647-8_BIB8
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja960639w
  contributor:
    fullname: Wu
– volume: 34
  start-page: 2044
  year: 1995
  ident: 10.1016/S0020-1693(97)05647-8_BIB6
  publication-title: Angew. Chem., Int. Ed. Engl.
  doi: 10.1002/anie.199520441
  contributor:
    fullname: Zanetti
– ident: 10.1016/S0020-1693(97)05647-8_BIB14
– volume: 30
  start-page: 9
  year: 1997
  ident: 10.1016/S0020-1693(97)05647-8_BIB1
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar950195t
  contributor:
    fullname: Schrock
– volume: 93
  start-page: 995
  year: 1993
  ident: 10.1016/S0020-1693(97)05647-8_BIB17
  publication-title: Chem. Rev.
  doi: 10.1021/cr00019a008
  contributor:
    fullname: Suiton
– volume: 26
  start-page: 97
  year: 1993
  ident: 10.1016/S0020-1693(97)05647-8_BIB22
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar00027a003
  contributor:
    fullname: Carnahan
– volume: 31
  start-page: 1985
  year: 1992
  ident: 10.1016/S0020-1693(97)05647-8_BIB18
  publication-title: Inorg. Chem.
  doi: 10.1021/ic00037a003
  contributor:
    fullname: Glassman
– volume: 11
  start-page: 2168
  year: 1992
  ident: 10.1016/S0020-1693(97)05647-8_BIB15
  publication-title: Organometallics
  doi: 10.1021/om00042a034
  contributor:
    fullname: Feng
– volume: 36
  start-page: 123
  year: 1997
  ident: 10.1016/S0020-1693(97)05647-8_BIB11
  publication-title: Inorg. Chem.
  doi: 10.1021/ic960889d
  contributor:
    fullname: Rosenberger
– volume: 116
  start-page: 8804
  year: 1994
  ident: 10.1016/S0020-1693(97)05647-8_BIB4
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00098a048
  contributor:
    fullname: Shih
– volume: 116
  start-page: 12103
  year: 1994
  ident: 10.1016/S0020-1693(97)05647-8_BIB10
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00105a081
  contributor:
    fullname: Shih
– volume: 39
  start-page: 1
  year: 1991
  ident: 10.1016/S0020-1693(97)05647-8_BIB16
  publication-title: Prog. Inorg. Chem.
  doi: 10.1002/9780470166406.ch1
  contributor:
    fullname: Feldman
– year: 1988
  ident: 10.1016/S0020-1693(97)05647-8_BIB19
  contributor:
    fullname: Nugent
– volume: 113
  start-page: 6564
  year: 1991
  ident: 10.1016/S0020-1693(97)05647-8_BIB21
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00017a030
  contributor:
    fullname: Protasiewicz
– volume: 26
  start-page: 483
  year: 1993
  ident: 10.1016/S0020-1693(97)05647-8_BIB2
  publication-title: Acc. Chem. Res.
  doi: 10.1021/ar00033a005
  contributor:
    fullname: Verkade
– volume: 117
  start-page: 6609
  year: 1995
  ident: 10.1016/S0020-1693(97)05647-8_BIB9
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00129a032
  contributor:
    fullname: Schrock
– start-page: 147
  year: 1988
  ident: 10.1016/S0020-1693(97)05647-8_BIB20
  article-title: High Oxidation State Alkylidyne Complexes
  contributor:
    fullname: Murdzek
– volume: 118
  start-page: 11305
  year: 1996
  ident: 10.1016/S0020-1693(97)05647-8_BIB7
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja961405f
  contributor:
    fullname: Johnson-Carr
– volume: 520
  start-page: 69
  year: 1996
  ident: 10.1016/S0020-1693(97)05647-8_BIB12
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(96)06264-X
  contributor:
    fullname: Toreki
SSID ssj0030635
ssj0000182
Score 1.6701894
Snippet Dihydrogen reacts slowly with [N 3N]WH ([N 3N] 3−[(Me 3SiNCH 2CH 2) 3N] 3−) in benzene at 22°C to form white, crystalline, diamagnetic [N 3N]WH 3...
SourceID crossref
elsevier
SourceType Aggregation Database
Publisher
StartPage 171
SubjectTerms Crystal structures
Triamidoamine complexes
Tungsten complexes
Title Reactions of [(Me 3SiNCH 2CH 2) 3N]WH with dihydrogen, olefins, acetylenes, carbon monoxide, n-butylisocyanide and azobenzene
URI https://dx.doi.org/10.1016/S0020-1693(97)05647-8
Volume 263
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NS8MwFA8yD3oRP_GbHDxMWDfbtDY5ylCq4g7qcCBSkibBwkjHnOAE_dt9r-38APHgoRRSXii_vr68l-T3CyEHRjNuhQm9SJkACpSIe0ob7lmuweBYqlgjUfiqd5z0w4tBNJgj3RkXBrdV1rG_iulltK5bOjWanVGeI8c3KKVERAyDeBgj4RfFtsCn2-_-Nwkp_qknBelxdeIm1kxo-kXpqborG5siPix79Pjvg9W3AehsmSzVmSM9qV5uhcwZt0oWurMD29bI27WpWApPtLD0vnllKLvJe92EBngdUtZ7uEsozrxSnT9O9bgA72nRYmhs7p5aVGZmMh1i8GvRTI5V4Sg4afGSa9OizlPP8DSHrzmVDpqodJrK10IZ9wo266R_dnrbTbz6dAUvg_964kHlwkOfq0AxK1hoIVVE1htULEJoYbVfZicsZj5DUTZptFTWh1sQSxFkPtsgDVc4s0koV4L5UuOaG9RnzEpfHkVWAtgc8iGbbZH2DMZ0VIlopF-7ywD3FHFPcSkccU_5FuEzsNMf3pBCoP_bdPv_pjtksRSnxf0q0S5pTMbPZg9SjonaL31qn8yfnF8mvQ-4Ms3a
link.rule.ids 315,783,787,4511,24130,27938,27939,45599,45693
linkProvider Elsevier
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1bS8MwFA7qHvRFvOK85sGHCauzTbsmj2Mondv64AUFkZI0CRYklW2CG_jfPWk7LyA--FAKKSeUr6cn30nOBaFjJQnVTPlOIJQHDkpAHSEVdTSVINDmIpQ2UXgYt6Nb__I-uF9A3XkujA2rrGx_adMLa12NtCo0Wy9ZZnN8vaKUCAthEfdDuohqwAYYKHut0-tH8bcqUvSzpBQw5LLppnWbrPRXVk85YzHYYOFJMalDf1-vvq1BF2totSKPuFO-3zpaUGYDLXfnPds20fuVKhMVxjjX-KExVJhcZ3E3wp69TjCJH-8ibDdfscyepnKUgwI1cf6sdGbGTcxTNZk-W_vXxCkfidxg0NP8LZOqiY0jXuFpBh90yg0MYW4k5rNcKDMDmS10e3F-042cqsGCk8KvPXHAeaG-S4UniGbE18AWbeIbOC2MSaalWxAUEhKX2LpsXEkutAs3L-TMS12yjZZMbtQOwlQw4nJpj93ARSOau_ws0BzApkCJdFpHp3MYk5eyjkbyFWAGuCcW98SehlvcE1pHdA528kMhErD1f4vu_l_0CC1HN8NBMujF_T20UtSqteErwT5amoxe1QEwkIk4rDTsAwpQ0Jc
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Reactions+of+%5B%28Me3SiNCH2CH2%293N%5DWH+with+dihydrogen%2C+olefins%2C+acetylenes%2C+carbon+monoxide%2C+n-butylisocyanide+and+azobenzene&rft.jtitle=Inorganica+Chimica+Acta&rft.au=Dobbs%2C+Daniel+A.&rft.au=Schrock%2C+Richard+R.&rft.au=Davis%2C+William+M.&rft.date=1997-10-15&rft.issn=0020-1693&rft.volume=263&rft.issue=1-2&rft.spage=171&rft.epage=180&rft_id=info:doi/10.1016%2FS0020-1693%2897%2905647-8&rft.externalDBID=n%2Fa&rft.externalDocID=10_1016_S0020_1693_97_05647_8
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0020-1693&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0020-1693&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0020-1693&client=summon