Enhancement in amoxicillin adsorption and regeneration properties of SBA-15 after surface modification with polyaniline

• Published in: Colloid and interface science communications Vol. 43; p. 100432
• Main Authors: Pandey, Prashant, Shankar, Aparajita, Biney, Michael, Saini, Vipin K.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.07.2021
• Subjects: Amoxicillin; Kinetics; Pharmaceutical pollution; Polyaniline; Reusability; SBA-15; Reusability; Kinetics; Polyaniline; SBA-15; Pharmaceutical pollution; Amoxicillin
• ISSN: 2215-0382; 2215-0382
• DOI: 10.1016/j.colcom.2021.100432

In this study, the ordered-mesoporous silica SBA-15 was modified into a composite adsorbent (PANI-SBA-15) through in-situ polymerization of aniline inside its mesopores. During polymerization, the residual cationic species from SBA-15 were washed away, which increased the surface negative charge in PANI-SBA-15. It encouraged faster and higher adsorption of amoxicillin (34.2 mg·g−1) with PANI-SBA-15, as compared to SBA-15 (24.7 mg·g−1). The kinetics study shows that adsorption on PANI-SBA-15 follows pseudo-second-order rate expression and is regulated by the pore-diffusion mechanism. The adsorption mechanism was explained with changes in surface chemistry and kinetics of adsorption. The regeneration of exhausted PANI-SBA-15 with HNO3 is higher (up to 98%) as compared to SBA-15 (86%). The regenerated composite material were reused successfully without significant loss of its adsorption capacity (>80% after 6 cycles). The PANI-SBA-15 removed 64.7 to 70.8% impurities from different simulated hospital wastewater samples. [Display omitted] •The surface of mesoporous SBA-15 was modified with in situ polymerization of aniline.•Incorporation of polyaniline increased the negative charge and π-electrons density.•The modified nanocomposite PANI-SBA-15 shows faster adsorption with 38.5% higher adsorption capacity.•The exhausted nanocomposite was regenerated (98%) with HNO3 and reused several time.•The PANI-SBA-15 removed 64.7 to 70.8% of impurities from simulated hospital wastewater samples.