Cerium based metal-organic framework as the efficient radical quencher for proton exchange membrane fuel cells

• Published in: Journal of membrane science Vol. 699; p. 122641
• Main Authors: Xu, Kangwei, Liu, Guipeng, Xu, Xiaojun, Wang, Zhihui, Liu, Gaochong, Liu, Feng, Zhang, Yongming, Zhou, Yongfeng, Zou, Yecheng, Pei, Supeng
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.04.2024
• Subjects: Ce-based radical quenchers; Chemical stability; Fuel cell; Metal-organic frameworks; Proton exchange membrane; Proton exchange membrane; Metal-organic frameworks; Ce-based radical quenchers; Chemical stability; Fuel cell
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2024.122641

Durability is one of the most key problems for the widespread commercialization of proton exchange membrane fuel cells (PEMFCs). Proton exchange membranes (PEMs) are pivotal components of the PEMFCs and their chemical stability is thus an important for the PEMFCs reliability. The incorporation of Ce-based radical quenchers such as ceria in PEMs can obviously alleviate the chemical deterioration of PEMs. Nevertheless, cell performance may decrease due to the presence of Ce-based radical quenchers. Therefore, a trade-off between cell performance and chemical stability of Ce-based radical quenchers containing PEM appears. To solve this issue, we developed a Ce-based metal organic framework Ce-BTC MOF with high radical trapping and proton-conducting properties. The Ce-BTC MOFs are introduced into the PFSA membrane to enhance the chemical stability and proton conductivity of the PFSA membrane. The PFSA/Ce-BTC membrane showed a maximum power density of 1.71 W/cm2 at 75 °C under 80％RH. After OCV test, PFSA/Ce-BTC membrane exhibited a decay of 0.56 mV/h after 120 h; pristine PFSA and Nafion membrane exhibited accelerated decay (for pristine PFSA, 1.72 mV/h; for Nafion membrane, 2.36 mV/h). Therefore, introduction of Ce-BTC MOFs offers an active defence approach to enhance the chemical stability of PEMFCs without sacrificing their cell performance. [Display omitted] •A Ce-based metal organic framework (Ce-BTC MOF) was prepared by solvothermal method.•The Ce-BTC MOF has high radical scavenging and proton-conducting properties.•The fabricated membrane has excellent chemical durability and cell performance.