Dynamics of absorbed water in saponite clay: Neutron scattering study
This Letter concerns measurement of water dynamics associated within the interlamellar region of native saponite and ‘Al 13’ intercalated polycation, as investigated using the quasielastic neutron scattering technique. The dynamics is described by random jump diffusion model. Diffusivity is found to...
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| Published in | Chemical physics letters Vol. 426; no. 4; pp. 296 - 300 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
04.08.2006
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| Abstract | This Letter concerns measurement of water dynamics associated within the interlamellar region of native saponite and ‘Al
13’ intercalated polycation, as investigated using the quasielastic neutron scattering technique. The dynamics is described by random jump diffusion model. Diffusivity is found to be larger in case of the Al
13 intercalated saponite than native saponite. Variation of half width at half maxima (HWHM) of the quasielastic spectra of the translational component with
Q
2. Solid lines are the fit assuming random jump diffusion model.
This report concerns measurement of water dynamics associated within the interlamellar region of native saponite and its tridecameric ‘Al
13’ intercalated polycation, as investigated using the quasielastic neutron scattering technique. The diffusion constant corresponding to the translational motion is found to be much lower as compared to that of bulk water that indicates the water adsorbed in between layers of saponite clays is dynamically hindered. The dynamics is described by a model in which the molecules undergo random jump diffusion. Diffusivity is found to be larger in case of the Al
13 intercalated saponite than native saponite because of the larger interlayer spacings in the former. |
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| AbstractList | This Letter concerns measurement of water dynamics associated within the interlamellar region of native saponite and ‘Al
13’ intercalated polycation, as investigated using the quasielastic neutron scattering technique. The dynamics is described by random jump diffusion model. Diffusivity is found to be larger in case of the Al
13 intercalated saponite than native saponite. Variation of half width at half maxima (HWHM) of the quasielastic spectra of the translational component with
Q
2. Solid lines are the fit assuming random jump diffusion model.
This report concerns measurement of water dynamics associated within the interlamellar region of native saponite and its tridecameric ‘Al
13’ intercalated polycation, as investigated using the quasielastic neutron scattering technique. The diffusion constant corresponding to the translational motion is found to be much lower as compared to that of bulk water that indicates the water adsorbed in between layers of saponite clays is dynamically hindered. The dynamics is described by a model in which the molecules undergo random jump diffusion. Diffusivity is found to be larger in case of the Al
13 intercalated saponite than native saponite because of the larger interlayer spacings in the former. |
| Author | Mitra, S. Gil, Antonio Gautam, Siddharth Mukhopadhyay, R. Chakrabarty, Debojit Vicente, Miguel A. |
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| Cites_doi | 10.1081/CR-100100261 10.1038/physci236015b0 10.1346/CCMN.1981.0290401 10.1016/S0167-2738(97)00020-9 10.1103/PhysRevA.31.1913 10.1346/CCMN.1999.0470103 10.1139/p67-025 10.1039/f19848000309 10.1016/S0168-9002(01)00867-1 10.1039/sd9700100194 10.1007/BF02705012 10.1039/f19858100833 10.1038/physci230192b0 10.1063/1.1305870 10.1016/0169-1317(95)00029-4 |
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| Title | Dynamics of absorbed water in saponite clay: Neutron scattering study |
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