Experimental study and thermodynamic modeling of phase equilibria of systems containing cyclohexane, alcohols (C4 and C5), and deep eutectic solvents
•LLE data of (cyclohexane + alcohols + deep eutectic solvents) were measured.•Three choline chloride-based deep eutectic solvents were prepared.•Experimental LLE data were correlated with NRTL model.•The interaction parameters were optimized by the Particle Swarm Optimization algorithm.•Distribution...
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| Published in | Journal of molecular liquids Vol. 340; p. 117196 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
15.10.2021
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| Abstract | •LLE data of (cyclohexane + alcohols + deep eutectic solvents) were measured.•Three choline chloride-based deep eutectic solvents were prepared.•Experimental LLE data were correlated with NRTL model.•The interaction parameters were optimized by the Particle Swarm Optimization algorithm.•Distribution coefficients and selectivity were evaluated.
Liquid-liquid equilibrium (LLE) data were measured and comparatively analyzed for six ternary mixtures of (cyclohexane + alcohols + deep eutectic solvents) at T = 298.2 K and p = 101 kPa. In this work, three choline chloride-based deep eutectic solvents (ChCl-DESs) were prepared for the extraction of the two structurally similar primary alcohols (1-butanol and 3-methyl-1-butanol) from a hydrocarbon (cyclohexane). The chosen DESs were DES1 (ChCl-propylene glycol with molar ratio = 1:3), DES2 (ChCl-ethylene glycol with molar ratio = 1:2), and DES3 (ChCl-glycerol with molar ratio = 1:2). The quality of the tie-line compositions was checked using the Othmer-Tobias correlation equation. The NRTL model was successfully applied to fit the experimental equilibrium data. The model binary interaction parameters were optimized by the Particle Swarm Optimization (PSO) algorithm. The model validation confirms that all the calculated parameters are consistent with the experimental data. Evaluation of the capacities of the deep eutectic solvent was carried out via the calculation of solute distribution coefficients and selectivity from the LLE data. The influence of the chemical structure of the alcohol on the phase equilibria was investigated. The extraction ability of the studied deep eutectic solvents displays promising results. The highest solute distribution coefficients were determined for (cyclohexane + 1-butanol + DES1). |
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| AbstractList | •LLE data of (cyclohexane + alcohols + deep eutectic solvents) were measured.•Three choline chloride-based deep eutectic solvents were prepared.•Experimental LLE data were correlated with NRTL model.•The interaction parameters were optimized by the Particle Swarm Optimization algorithm.•Distribution coefficients and selectivity were evaluated.
Liquid-liquid equilibrium (LLE) data were measured and comparatively analyzed for six ternary mixtures of (cyclohexane + alcohols + deep eutectic solvents) at T = 298.2 K and p = 101 kPa. In this work, three choline chloride-based deep eutectic solvents (ChCl-DESs) were prepared for the extraction of the two structurally similar primary alcohols (1-butanol and 3-methyl-1-butanol) from a hydrocarbon (cyclohexane). The chosen DESs were DES1 (ChCl-propylene glycol with molar ratio = 1:3), DES2 (ChCl-ethylene glycol with molar ratio = 1:2), and DES3 (ChCl-glycerol with molar ratio = 1:2). The quality of the tie-line compositions was checked using the Othmer-Tobias correlation equation. The NRTL model was successfully applied to fit the experimental equilibrium data. The model binary interaction parameters were optimized by the Particle Swarm Optimization (PSO) algorithm. The model validation confirms that all the calculated parameters are consistent with the experimental data. Evaluation of the capacities of the deep eutectic solvent was carried out via the calculation of solute distribution coefficients and selectivity from the LLE data. The influence of the chemical structure of the alcohol on the phase equilibria was investigated. The extraction ability of the studied deep eutectic solvents displays promising results. The highest solute distribution coefficients were determined for (cyclohexane + 1-butanol + DES1). |
| ArticleNumber | 117196 |
| Author | Jahanbin sardroodi, J. Rahmdel, Sh Ghanadzadeh Gilani, A. Verpoort, F. |
| Author_xml | – sequence: 1 givenname: A. surname: Ghanadzadeh Gilani fullname: Ghanadzadeh Gilani, A. email: aggilani@guilan.ac.ir organization: Department of Chemistry, Faculty of Science, University of Guilan, Rasht, Iran – sequence: 2 givenname: J. surname: Jahanbin sardroodi fullname: Jahanbin sardroodi, J. organization: Department of Chemistry, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran – sequence: 3 givenname: F. surname: Verpoort fullname: Verpoort, F. organization: Ghent University, Global Campus Songdo, 119 Songdomunhwa-Ro, Yeonsu-Gu, Incheon, Republic of Korea – sequence: 4 givenname: Sh surname: Rahmdel fullname: Rahmdel, Sh organization: Department of Chemistry, Faculty of Science, University of Guilan, Rasht, Iran |
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| Cites_doi | 10.1016/j.fluid.2017.05.011 10.1007/s11721-007-0002-0 10.1016/j.jct.2016.10.002 10.1016/j.jct.2005.06.011 10.1039/B815169E 10.1016/j.fluid.2016.11.009 10.1039/b210714g 10.1016/S0167-7322(98)00084-1 10.1021/je400501z 10.1021/je500204v 10.1016/S1007-0214(06)70180-8 10.1039/C5GC02909K 10.1021/ie50390a011 10.1016/j.molliq.2005.08.002 10.1002/aic.690140124 10.1007/s10953-018-0793-1 10.1021/je800593p 10.1016/j.jct.2016.09.002 10.1039/c3gc37030e 10.3390/ma12030350 10.1021/je060238o 10.1021/cr300162p 10.1016/j.ymben.2016.10.007 10.1021/acs.jctc.6b00449 10.1080/01496395.2014.952748 10.1016/j.jct.2005.09.004 10.1021/je900324s 10.2514/6.2005-1897 10.3390/molecules24030636 10.1021/je990226l 10.1021/acssuschemeng.9b05629 10.1007/s11814-018-0030-z 10.1021/acs.iecr.5b02611 10.1016/j.jtice.2012.01.007 10.1021/je700580g 10.1039/c2gc35660k 10.1021/je049687j 10.1139/v95-156 10.1016/j.aca.2012.12.019 10.1016/j.seppur.2020.117975 10.1023/B:JOSL.0000048056.49122.6d 10.1021/je400884v 10.1016/j.copbio.2011.02.004 10.1007/s11814-015-0054-6 10.1021/ja048266j 10.1016/j.molliq.2017.01.086 10.1016/0378-3812(79)80027-8 10.1016/0378-3812(95)02804-N 10.1016/j.molliq.2020.113524 10.1021/je60039a002 10.1021/acs.jced.5b00717 10.1021/je060248p 10.1016/j.seppur.2016.10.036 |
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| Keywords | Liquid-liquid equilibrium Choline chloride Deep eutectic solvent Thermodynamic model |
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| References | Rodriguez, Ferre Guell, Kroon (b0250) 2016; 61 Marcilla, Ruiz, García (b0295) 1995; 112 Oliveira, Pereiro, Rebelo, Marrucho (b0015) 2013; 15 Francisco, van den Bruinhorst, Kroon (b0040) 2012; 14 A. Ghanadzadeh Gilani, M. Moghadam, S.E. Hosseini, Dielectric study of primary alkanediols (C3, C4, C5) with 1-pentanol isomers, J. Mol. Liq. 231 (2017) 27–38, https://doi.org/10.1016/j.molliq.2017.01.086 Uosaki, Ito, Kondo, Kitaura, Moriyoshi (b0190) 2006; 51 Li, Zhu, Lei (b0020) 2015; 32 Tanaka, Yokoyama (b0180) 2004; 33 Poling, Prausnitz, O’Connell (b0140) 2001 Marcilla, Reyes-Labarta, Olaya (b0290) 2017; 433 Hadj-Kali, Salleh, Ali, Khan, Hashim (b0075) 2017; 448 J.A. Reyes-Labarta, Graphical User Interface (GUI) for the Representation of GMSurfaces and Curves, Including Tie-Lines (Topological Analysis of Liquid-Liquid Equilibrium Correlations), Institutional Repository of the University of Alicante (RUA), http://hdl.handle.net/10045/51725 M. I. Aralaguppi, J. G. Baragi, Physico-chemical and excess properties of the binary mixtures of methylcyclohexane + ethanol, + propan-1-ol, + propan-2-ol, + butan-1-ol, + 2-methyl-1-propanol, or 3-methyl-1-butanol at T = (298.15, 303.15, and 308.15) K, J. Chem. Thermodyn. 38 (2006) 434–442, https://doi.org/10.1016/j.jct. 2005.06.011. Li, Mumford, Shang, Smith, Chen, Wang, Stevens (b0275) 2014; 59 Salleh, Wazeer, Mulyono, El-blidi, Hashim, Hadj-Kali (b0130) 2017; 104 Sørensen, Magnussen, Rasmussen, Fredenslund (b0285) 1979; 3 Green (b0090) 2011; 22 Dai, van Spronsen, Witkamp, Verpoorte, Choi (b0070) 2013; 766 Smith, Abbott, Ryder (b0035) 2014; 114 Wang, Hou, Wu, Liu, Ji, Ren (b0045) 2016; 18 H. Rania, C. Babak, W. Olivier de, V. Gerhard, A comparison of particle swarm optimization and the genetic algorithm. In 46th AIAA/ASME/ASCE/AHS/ASC structures, structural dynamics and materials conference, American Institute of Aeronautics and Astronautics, 2005, https://doi.org/10.2514/6.2005-1897. Ritzoulis, Missopolinou, Doulami, Panayiotou (b0195) 2000; 45 Homan, Shahbaz, Farid (b0230) 2017; 174 Abbott, Capper, Davies, Rasheed, Tambyrajah (b0005) 2003; 1 Durov (b0080) 1998; 78 Renon, Prausnitz (b0135) 1968; 14 Abbott, Boothby, Capper, Davies, Rasheed (b0025) 2004; 126 Verhoeye (b0120) 1968; 13 J. P. Wojeicchowski, C. Marques, L. I. Mafra, J. A.P. Coutinho, and M. R. Mafra, Extraction of phenolic compounds from rosemary using choline chloride – based deep eutectic solvents, Sep. Purif. Technol. 258 (2021) 117975-117983, https://doi.org/10.1016/j.seppur.2020.117975. J. Vuksanović, M. Lj. Kijevčanin, and I.R. Radović, Effect of water addition on extraction ability of eutectic solvent choline chloride+ 1,2-propanediol for separation of hexane/heptane+ethanol systems, Korean J. Chem. Eng. 35 (2018) 1477-1487, https://doi.org/10.1007/s11814-018-0030-z. Chmielewska, Żurada, Klimaszewski, Bald (b0210) 2009; 54 Z. Li, PhD dissertation: “Thermodynamic Modelling of Liquid–liquid Equilibria Using the Nonrandom Two-Liquid Model and Its Applications”, Department of Chemical and Biomolecular Engineering The University of Melbourne, Aug. (2015). C. C. Bannan, G. Calabró, D. Y. Kyu, D. L. Mobley, Calculating partition coefficients of small molecules in octanol/water cyclohexane/water. J. Chem. Theory Comput. 12 (2016) 4015−4024, https://doi.org/10.1021/acs.jctc.6b00449. Vogt, Brüsseler, van Ooyen, Bott, Marienhagen (b0100) 2016; 38 Othmer, Tobias (b0265) 1942; 34 M. K. Hadj-Kali, H. F. Hizaddin, I. Wazeer, L. El blidi, S. Mulyono, and M. A. Hashim, Separation of aromatic and aliphatic hydrocarbons using deep eutectic solvents: A critical review, Fluid Phase Equilib. 448 (2017) 152-167, https://doi.org/10.1016/j.fluid.2017.05.011. Romero, Giner, Haro, Artigas, Lafuente (b0175) 2006; 38 Lu, Yang, Luo (b0060) 2010; 55 Kennedy, Eberhart (b0145) 1995 Riggio, Martinez, Salas, Toigo, Ramos (b0185) 1995; 73 J.A. Riddick, W.B. Bunger, T.K. Sakano, Organic solvents: Physical properties and methods of purification, 4th ed., Techniques of chemistry series; Wiley, New York, II, 1986. Rodrigues, Silva, Marsaioli, Meirelles (b0300) 2005; 50 E. Zorebski, A. Waligóra, Densities, excess molar volumes, and isobaric thermal expansibilities for 1,2-ethanediol + 1-butanol, or 1-hexanol, or 1-octanol in the temperature range from (293.15 to 313.15) K, J. Chem. Eng. Data. 53 (2008) 591−595, https://doi.org/10.1021/je700580g. Daia, Spronsenb, Witkamp, Verpoorte, Choia (b0245) 2013; 766 J. A. Salas, G. C. Pedrosa, I.L. Acevedo, E.L. Arancibia, Excess molar volumes and excess viscosities of the 2,2,4-trimethylpentane (1) + 3-methyl-1-butanol (2) and propan-2-ol (3) ternary system at 298.15 K, J. Mol. Liq. 124 (2006) 37–44, https://doi.org/10.1016/j.molliq.2005.08.002. Chen, Ai, Li, Shan, Cui, Deng (b0240) 2014; 59 Gomis, Font, Saquete, García-Cano (b0085) 2013; 58 Li, Mumford, Shang, Smith, Chen, Wang, Stevens (b0280) 2014; 49 Poli, Kennedy, Blackwell (b0150) 2007; 1 Esfahani, Khoshsima, Pazuki (b0125) 2020; 313 Rudan-Tasič, Klofutar (b0170) 1998; 129 Leron, Soriano, Li (b0160) 2012; 43 Rodriguez, Requejo, Kroon (b0065) 2015; 54 J. M. Resa, J. M. Goenaga, M. Iglesias, Vapor−liquid equilibria at 101.3 kPa for binary mixtures containing 2-methyl-1-propanol + 2-methyl-1-butanol, 2-methyl-1-propanol + 3-methyl-1-butanol, and 2-methyl-1-propanol + 1-pentanol, J. Chem. Eng. Data. 51 (2006) 1892-1895, https://doi.org/10.1021/je060238o. Chen, Zhou, Cai, Zhu, Zou (b0010) 2009; 11 Mulia, Fauzia, Krisanti (b0235) 2019; 24 Martins, Pinho, Coutinho (b0030) 2019; 48 Kolesinska, Fraczyk, Binczarski, Modelska, Berlowska, Dziugan, Antolak, Kaminski, Witonska, Kregiel (b0095) 2019; 12 Xu, Meng, Li, Yu, Zhu, Wang, Ma, Gao (b0110) 2019; 7 Ma, Guo, Li, Zong, Ji, Liu (b0165) 2017; 105 Kuzrnanovic, Kuipers, de Haan, Kwant (b0105) 2006; 11 10.1016/j.molliq.2021.117196_b0305 10.1016/j.molliq.2021.117196_b0225 Poli (10.1016/j.molliq.2021.117196_b0150) 2007; 1 Poling (10.1016/j.molliq.2021.117196_b0140) 2001 10.1016/j.molliq.2021.117196_b0220 Leron (10.1016/j.molliq.2021.117196_b0160) 2012; 43 Kolesinska (10.1016/j.molliq.2021.117196_b0095) 2019; 12 Ritzoulis (10.1016/j.molliq.2021.117196_b0195) 2000; 45 10.1016/j.molliq.2021.117196_b0260 Tanaka (10.1016/j.molliq.2021.117196_b0180) 2004; 33 Hadj-Kali (10.1016/j.molliq.2021.117196_b0075) 2017; 448 Francisco (10.1016/j.molliq.2021.117196_b0040) 2012; 14 Lu (10.1016/j.molliq.2021.117196_b0060) 2010; 55 Rodriguez (10.1016/j.molliq.2021.117196_b0250) 2016; 61 Xu (10.1016/j.molliq.2021.117196_b0110) 2019; 7 Dai (10.1016/j.molliq.2021.117196_b0070) 2013; 766 Li (10.1016/j.molliq.2021.117196_b0020) 2015; 32 Smith (10.1016/j.molliq.2021.117196_b0035) 2014; 114 Green (10.1016/j.molliq.2021.117196_b0090) 2011; 22 Kennedy (10.1016/j.molliq.2021.117196_b0145) 1995 Wang (10.1016/j.molliq.2021.117196_b0045) 2016; 18 Ma (10.1016/j.molliq.2021.117196_b0165) 2017; 105 10.1016/j.molliq.2021.117196_b0115 Rudan-Tasič (10.1016/j.molliq.2021.117196_b0170) 1998; 129 10.1016/j.molliq.2021.117196_b0155 Riggio (10.1016/j.molliq.2021.117196_b0185) 1995; 73 Durov (10.1016/j.molliq.2021.117196_b0080) 1998; 78 Li (10.1016/j.molliq.2021.117196_b0280) 2014; 49 Verhoeye (10.1016/j.molliq.2021.117196_b0120) 1968; 13 10.1016/j.molliq.2021.117196_b0270 Esfahani (10.1016/j.molliq.2021.117196_b0125) 2020; 313 Chen (10.1016/j.molliq.2021.117196_b0010) 2009; 11 Uosaki (10.1016/j.molliq.2021.117196_b0190) 2006; 51 Homan (10.1016/j.molliq.2021.117196_b0230) 2017; 174 10.1016/j.molliq.2021.117196_b0205 10.1016/j.molliq.2021.117196_b0200 Chmielewska (10.1016/j.molliq.2021.117196_b0210) 2009; 54 Salleh (10.1016/j.molliq.2021.117196_b0130) 2017; 104 Marcilla (10.1016/j.molliq.2021.117196_b0295) 1995; 112 Oliveira (10.1016/j.molliq.2021.117196_b0015) 2013; 15 Abbott (10.1016/j.molliq.2021.117196_b0025) 2004; 126 Marcilla (10.1016/j.molliq.2021.117196_b0290) 2017; 433 Renon (10.1016/j.molliq.2021.117196_b0135) 1968; 14 Martins (10.1016/j.molliq.2021.117196_b0030) 2019; 48 Gomis (10.1016/j.molliq.2021.117196_b0085) 2013; 58 Rodrigues (10.1016/j.molliq.2021.117196_b0300) 2005; 50 10.1016/j.molliq.2021.117196_b0215 Abbott (10.1016/j.molliq.2021.117196_b0005) 2003; 1 Rodriguez (10.1016/j.molliq.2021.117196_b0065) 2015; 54 Mulia (10.1016/j.molliq.2021.117196_b0235) 2019; 24 Sørensen (10.1016/j.molliq.2021.117196_b0285) 1979; 3 10.1016/j.molliq.2021.117196_b0255 Vogt (10.1016/j.molliq.2021.117196_b0100) 2016; 38 10.1016/j.molliq.2021.117196_b0055 Daia (10.1016/j.molliq.2021.117196_b0245) 2013; 766 Li (10.1016/j.molliq.2021.117196_b0275) 2014; 59 10.1016/j.molliq.2021.117196_b0050 Othmer (10.1016/j.molliq.2021.117196_b0265) 1942; 34 Chen (10.1016/j.molliq.2021.117196_b0240) 2014; 59 Romero (10.1016/j.molliq.2021.117196_b0175) 2006; 38 Kuzrnanovic (10.1016/j.molliq.2021.117196_b0105) 2006; 11 |
| References_xml | – volume: 55 start-page: 510 year: 2010 end-page: 512 ident: b0060 article-title: Liquid− liquid equilibria for benzene+ cyclohexane+ 1-butyl-3-methylimidazolium hexaflourophosphate publication-title: J. Chem. Eng. Data. contributor: fullname: Luo – volume: 51 start-page: 1915 year: 2006 end-page: 1921 ident: b0190 article-title: Effect of pressure on the static relative permittivities of alkan-1-ols at 298.15 K publication-title: J. Chem. Eng. Data. contributor: fullname: Moriyoshi – volume: 73 start-page: 1274 year: 1995 end-page: 1277 ident: b0185 article-title: Excess properties for cyclohexanone + butanols at 298.15 K publication-title: Can. J. Chem. contributor: fullname: Ramos – volume: 38 start-page: 871 year: 2006 end-page: 878 ident: b0175 article-title: Thermophysical study of 1, 4-dioxane with cycloalkane mixtures publication-title: J. Chem. Thermodyn. contributor: fullname: Lafuente – volume: 313 start-page: 113524 year: 2020 ident: b0125 article-title: Choline chloride-based deep eutectic solvents as green extractant for the efficient extraction of 1-butanol or 2-butanol from Azeotropic n-Heptane + Butanol Mixtures publication-title: J. Mol. Liq. contributor: fullname: Pazuki – volume: 54 start-page: 801 year: 2009 end-page: 806 ident: b0210 article-title: Dielectric properties of methanol mixtures with ethanol, isomers of propanol, and butanol publication-title: J. Chem. Eng. Data. contributor: fullname: Bald – volume: 78 start-page: 51 year: 1998 end-page: 82 ident: b0080 article-title: Modeling of supramolecular ordering in molecular liquids: Structure, physicochemical properties, and macroscopic manifestations publication-title: J. Mol. Liq. contributor: fullname: Durov – volume: 58 start-page: 3320 year: 2013 end-page: 3326 ident: b0085 article-title: Liquid−Liquid, Vapor−Liquid, and Vapor−Liquid−Liquid Equilibrium Data for the water−n-Butanol−Cyclohexane System at Atmospheric Pressure: Experimental Determination and Correlation publication-title: J. Chem. Eng. Data contributor: fullname: García-Cano – start-page: 1942 year: 1995 end-page: 1948 ident: b0145 article-title: In particle swarm optimization, Neural Networks, Proceedings publication-title: IEEE International Conference on Nov/Dec contributor: fullname: Eberhart – volume: 13 start-page: 462 year: 1968 end-page: 467 ident: b0120 article-title: The system cyclohexane-2-propanol-water publication-title: J. Chem. Eng. Data contributor: fullname: Verhoeye – volume: 174 start-page: 570 year: 2017 end-page: 576 ident: b0230 article-title: Improving the production of propyl and butyl ester-based biodiesel by purification using deep eutectic solvents publication-title: Sep. Purif. Technol. contributor: fullname: Farid – volume: 129 start-page: 1245 year: 1998 end-page: 1257 ident: b0170 article-title: Apparent molar volume and expansibility of cyclohexanol in benzene and cyclohexane solutionsScheinbares Molvolumen und Expansibilität von Cyclohexanol in Benzol und Cyclohexan publication-title: Monatsh. Chem. contributor: fullname: Klofutar – volume: 38 start-page: 436 year: 2016 end-page: 445 ident: b0100 article-title: Production of 2-methyl-1-butanol and 3-methyl-1-butanol in engineered Corynebacterium glutamicum publication-title: Metab. Eng. contributor: fullname: Marienhagen – volume: 32 start-page: 2103 year: 2015 end-page: 2108 ident: b0020 article-title: Choline chloride-based deep eutectic solvents as additives for optimizing chromatographic behavior of caffeic acid publication-title: Korean J. Chem. Eng. contributor: fullname: Lei – volume: 766 start-page: 61 year: 2013 end-page: 68 ident: b0245 article-title: Natural deep eutectic solvents as new potential media for green technology publication-title: J. Anal. Chim. Acta contributor: fullname: Choia – volume: 766 start-page: 61 year: 2013 end-page: 68 ident: b0070 article-title: Natural deep eutectic solvents as new potential media for green technology publication-title: Anal. Chim. Acta. contributor: fullname: Choi – volume: 7 start-page: 19984 year: 2019 end-page: 19992 ident: b0110 article-title: Mechanism Analysis for Separation of Cyclohexane and tert-Butanol System via Ionic Liquids as Extractants and Process Optimization publication-title: ACS Sustainable Chem. Eng. contributor: fullname: Gao – volume: 14 start-page: 135 year: 1968 end-page: 144 ident: b0135 article-title: Local compositions in thermodynamic excess functions for liquid mixtures publication-title: AIChE J. contributor: fullname: Prausnitz – volume: 1 start-page: 70 year: 2003 end-page: 71 ident: b0005 article-title: Novel solvent properties of choline chloride/urea mixtures publication-title: Chem. Commun. contributor: fullname: Tambyrajah – volume: 15 start-page: 1326 year: 2013 end-page: 1330 ident: b0015 article-title: Deep eutectic solvents as extraction media for azeotropic mixtures publication-title: Green Chem. contributor: fullname: Marrucho – volume: 48 start-page: 962 year: 2019 end-page: 982 ident: b0030 article-title: Insights into the nature of eutectic and deep eutectic mixtures publication-title: J. Solution Chem. contributor: fullname: Coutinho – volume: 14 start-page: 2153 year: 2012 end-page: 2157 ident: b0040 article-title: New natural and renewable low transition temperature mixtures (LTTMs): screening as solvents for lignocellulosic biomass processing publication-title: Green Chem. contributor: fullname: Kroon – year: 2001 ident: b0140 article-title: The properties of gases and liquids contributor: fullname: O’Connell – volume: 22 start-page: 337 year: 2011 end-page: 343 ident: b0090 article-title: Fermentative production of butanol-the industrial perspective publication-title: Curr. Opin. Biotechnol. contributor: fullname: Green – volume: 59 start-page: 1247 year: 2014 end-page: 1253 ident: b0240 article-title: Solubilities of Carbon Dioxide in Eutectic Mixtures of Choline Chloride and Dihydric Alcohols publication-title: J. Chem. Eng. Data contributor: fullname: Deng – volume: 61 start-page: 865 year: 2016 end-page: 872 ident: b0250 article-title: Glycerol-based deep eutectic solvents as extractants for the separation of MEK and ethanol via liquid−liquid extraction publication-title: J. Chem. Eng. Data contributor: fullname: Kroon – volume: 33 start-page: 1061 year: 2004 end-page: 1072 ident: b0180 article-title: Apparent dipole moments of 1-butanol, 1-propanol, and chlorobenzene in cyclohexane or benzene, and excess molar volumes of (1-propanol or chlorobenzene + cyclohexane or benzene) at T = 298.15 K publication-title: J. Solution Chem. contributor: fullname: Yokoyama – volume: 34 start-page: 690 year: 1942 end-page: 692 ident: b0265 article-title: Liquid–liquid extraction data-toluene and acetaldehyde systems publication-title: Ind. Eng. Chem. contributor: fullname: Tobias – volume: 104 start-page: 33 year: 2017 end-page: 44 ident: b0130 article-title: Efficient removal of benzene from cyclohexane-benzene mixtures using deep eutectic solvents–COSMO-RS screening and experimental validation publication-title: J. Chem. Thermodyn. contributor: fullname: Hadj-Kali – volume: 12 start-page: 350 year: 2019 ident: b0095 article-title: Butanol Synthesis Routes for Biofuel Production: Trends and Perspectives publication-title: Materials contributor: fullname: Kregiel – volume: 433 start-page: 243 year: 2017 end-page: 252 ident: b0290 article-title: Should we trust all the published LLE correlation parameters in phase equilibria Necessity of their assessment prior to publication publication-title: Fluid Phase Equilib. contributor: fullname: Olaya – volume: 11 start-page: 222 year: 2006 end-page: 227 ident: b0105 article-title: Reactive Extraction of Alcohols from Apolar Hydrocarbons with Aqueous Solutions publication-title: Tsinghua Sci. Technol. contributor: fullname: Kwant – volume: 24 start-page: 636 year: 2019 ident: b0235 article-title: Polyalcohols as hydrogen-bonding donors in choline chloride-based deep eutectic solvents for extraction of xanthones from the pericarp of publication-title: J. Molecules contributor: fullname: Krisanti – volume: 112 start-page: 273 year: 1995 end-page: 289 ident: b0295 article-title: Liquid-liquid-solid equilibria of the quaternary system water-ethanol-acetone-sodium chloride at 25 °C publication-title: Fluid Phase Equilib. contributor: fullname: García – volume: 3 start-page: 47 year: 1979 end-page: 82 ident: b0285 article-title: Liquid-liquid equilibrium data: Their retrieval, correlation and prediction part II: correlation publication-title: Fluid Phase Equilib. contributor: fullname: Fredenslund – volume: 126 start-page: 9142 year: 2004 end-page: 9147 ident: b0025 article-title: Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids publication-title: J. Am. Chem. Soc. contributor: fullname: Rasheed – volume: 18 start-page: 3089 year: 2016 end-page: 3097 ident: b0045 article-title: Roles of a hydrogen bond donor and a hydrogen bond acceptor in the extraction of toluene from n-heptane using deep eutectic solvents publication-title: Green Chem. contributor: fullname: Ren – volume: 49 start-page: 2913 year: 2014 end-page: 2920 ident: b0280 article-title: Extraction of Phenol by Toluene in the Presence of Sodium Hydroxide publication-title: Sep. Sci. Technol. contributor: fullname: Stevens – volume: 105 start-page: 30 year: 2017 end-page: 36 ident: b0165 article-title: Molar enthalpy of mixing and refractive indices of choline chloride-based deep eutectic solvents with water publication-title: J. Chem. Thermodyn. contributor: fullname: Liu – volume: 448 start-page: 152 year: 2017 end-page: 167 ident: b0075 article-title: Separation of aromatic and aliphatic hydrocarbons using deep eutectic solvents: A critical review publication-title: Fluid Phase Equilib. contributor: fullname: Hashim – volume: 54 start-page: 11404 year: 2015 end-page: 11412 ident: b0065 article-title: Aliphatic-Aromatic Separation Using Deep Eutectic Solvents as Extracting Agents publication-title: Ind. Eng. Chem. Res. contributor: fullname: Kroon – volume: 1 start-page: 33 year: 2007 end-page: 57 ident: b0150 article-title: Particle swarm optimization publication-title: Swarm Intell. contributor: fullname: Blackwell – volume: 50 start-page: 517 year: 2005 end-page: 523 ident: b0300 article-title: Deacidification of Brazil Nut and Macadamia Nut Oils by Solvent Extraction: Liquid−Liquid Equilibrium Data at 298.2 K publication-title: J. Chem. Eng. Data. contributor: fullname: Meirelles – volume: 114 start-page: 11060 year: 2014 end-page: 11082 ident: b0035 article-title: Deep Eutectic Solvents (DESs) and Their Applications publication-title: Chem. Rev. contributor: fullname: Ryder – volume: 43 start-page: 551 year: 2012 end-page: 557 ident: b0160 article-title: Densities and refractive indices of the deep eutectic solvents (choline chloride + ethylene glycol or glycerol) and their aqueous mixtures at the temperature ranging from 298.15 to 333.15 K publication-title: J. Taiwan Inst. Chem. Eng. contributor: fullname: Li – volume: 11 start-page: 275 year: 2009 end-page: 278 ident: b0010 article-title: Simple and efficient methods for selective preparation of α-mono or α, α-dichloro ketones and β-ketoesters by using DCDMH publication-title: Green Chem. contributor: fullname: Zou – volume: 45 start-page: 636 year: 2000 end-page: 641 ident: b0195 article-title: Relative permittivities, densities, refractive indices and ultrasound velocities of the binary systems of γ-butyrolactone with methanol, ethanol, 1-butanol, and 1-octanol publication-title: J. Chem. Eng. Data contributor: fullname: Panayiotou – volume: 59 start-page: 2485 year: 2014 end-page: 2489 ident: b0275 article-title: Analysis of the Nonrandom Two-Liquid Model for Prediction of Liquid–liquid Equilibria publication-title: J. Chem. Eng. Data. contributor: fullname: Stevens – volume: 448 start-page: 152 year: 2017 ident: 10.1016/j.molliq.2021.117196_b0075 article-title: Separation of aromatic and aliphatic hydrocarbons using deep eutectic solvents: A critical review publication-title: Fluid Phase Equilib. doi: 10.1016/j.fluid.2017.05.011 contributor: fullname: Hadj-Kali – ident: 10.1016/j.molliq.2021.117196_b0270 – volume: 1 start-page: 33 issue: 1 year: 2007 ident: 10.1016/j.molliq.2021.117196_b0150 article-title: Particle swarm optimization publication-title: Swarm Intell. doi: 10.1007/s11721-007-0002-0 contributor: fullname: Poli – volume: 105 start-page: 30 year: 2017 ident: 10.1016/j.molliq.2021.117196_b0165 article-title: Molar enthalpy of mixing and refractive indices of choline chloride-based deep eutectic solvents with water publication-title: J. Chem. Thermodyn. doi: 10.1016/j.jct.2016.10.002 contributor: fullname: Ma – ident: 10.1016/j.molliq.2021.117196_b0220 doi: 10.1016/j.jct.2005.06.011 – ident: 10.1016/j.molliq.2021.117196_b0055 doi: 10.1016/j.fluid.2017.05.011 – volume: 11 start-page: 275 issue: 2 year: 2009 ident: 10.1016/j.molliq.2021.117196_b0010 article-title: Simple and efficient methods for selective preparation of α-mono or α, α-dichloro ketones and β-ketoesters by using DCDMH publication-title: Green Chem. doi: 10.1039/B815169E contributor: fullname: Chen – volume: 433 start-page: 243 year: 2017 ident: 10.1016/j.molliq.2021.117196_b0290 article-title: Should we trust all the published LLE correlation parameters in phase equilibria Necessity of their assessment prior to publication publication-title: Fluid Phase Equilib. doi: 10.1016/j.fluid.2016.11.009 contributor: fullname: Marcilla – volume: 1 start-page: 70 year: 2003 ident: 10.1016/j.molliq.2021.117196_b0005 article-title: Novel solvent properties of choline chloride/urea mixtures publication-title: Chem. Commun. doi: 10.1039/b210714g contributor: fullname: Abbott – volume: 78 start-page: 51 year: 1998 ident: 10.1016/j.molliq.2021.117196_b0080 article-title: Modeling of supramolecular ordering in molecular liquids: Structure, physicochemical properties, and macroscopic manifestations publication-title: J. Mol. Liq. doi: 10.1016/S0167-7322(98)00084-1 contributor: fullname: Durov – volume: 58 start-page: 3320 issue: 12 year: 2013 ident: 10.1016/j.molliq.2021.117196_b0085 article-title: Liquid−Liquid, Vapor−Liquid, and Vapor−Liquid−Liquid Equilibrium Data for the water−n-Butanol−Cyclohexane System at Atmospheric Pressure: Experimental Determination and Correlation publication-title: J. Chem. Eng. Data doi: 10.1021/je400501z contributor: fullname: Gomis – volume: 59 start-page: 2485 year: 2014 ident: 10.1016/j.molliq.2021.117196_b0275 article-title: Analysis of the Nonrandom Two-Liquid Model for Prediction of Liquid–liquid Equilibria publication-title: J. Chem. Eng. Data. doi: 10.1021/je500204v contributor: fullname: Li – volume: 11 start-page: 222 issue: 2 year: 2006 ident: 10.1016/j.molliq.2021.117196_b0105 article-title: Reactive Extraction of Alcohols from Apolar Hydrocarbons with Aqueous Solutions publication-title: Tsinghua Sci. Technol. doi: 10.1016/S1007-0214(06)70180-8 contributor: fullname: Kuzrnanovic – ident: 10.1016/j.molliq.2021.117196_b0305 – volume: 18 start-page: 3089 issue: 10 year: 2016 ident: 10.1016/j.molliq.2021.117196_b0045 article-title: Roles of a hydrogen bond donor and a hydrogen bond acceptor in the extraction of toluene from n-heptane using deep eutectic solvents publication-title: Green Chem. doi: 10.1039/C5GC02909K contributor: fullname: Wang – volume: 34 start-page: 690 issue: 6 year: 1942 ident: 10.1016/j.molliq.2021.117196_b0265 article-title: Liquid–liquid extraction data-toluene and acetaldehyde systems publication-title: Ind. Eng. Chem. doi: 10.1021/ie50390a011 contributor: fullname: Othmer – volume: 129 start-page: 1245 issue: 12 year: 1998 ident: 10.1016/j.molliq.2021.117196_b0170 article-title: Apparent molar volume and expansibility of cyclohexanol in benzene and cyclohexane solutionsScheinbares Molvolumen und Expansibilität von Cyclohexanol in Benzol und Cyclohexan publication-title: Monatsh. Chem. contributor: fullname: Rudan-Tasič – ident: 10.1016/j.molliq.2021.117196_b0225 doi: 10.1016/j.molliq.2005.08.002 – volume: 14 start-page: 135 issue: 1 year: 1968 ident: 10.1016/j.molliq.2021.117196_b0135 article-title: Local compositions in thermodynamic excess functions for liquid mixtures publication-title: AIChE J. doi: 10.1002/aic.690140124 contributor: fullname: Renon – volume: 48 start-page: 962 year: 2019 ident: 10.1016/j.molliq.2021.117196_b0030 article-title: Insights into the nature of eutectic and deep eutectic mixtures publication-title: J. Solution Chem. doi: 10.1007/s10953-018-0793-1 contributor: fullname: Martins – volume: 54 start-page: 801 issue: 3 year: 2009 ident: 10.1016/j.molliq.2021.117196_b0210 article-title: Dielectric properties of methanol mixtures with ethanol, isomers of propanol, and butanol publication-title: J. Chem. Eng. Data. doi: 10.1021/je800593p contributor: fullname: Chmielewska – volume: 104 start-page: 33 year: 2017 ident: 10.1016/j.molliq.2021.117196_b0130 article-title: Efficient removal of benzene from cyclohexane-benzene mixtures using deep eutectic solvents–COSMO-RS screening and experimental validation publication-title: J. Chem. Thermodyn. doi: 10.1016/j.jct.2016.09.002 contributor: fullname: Salleh – volume: 15 start-page: 1326 year: 2013 ident: 10.1016/j.molliq.2021.117196_b0015 article-title: Deep eutectic solvents as extraction media for azeotropic mixtures publication-title: Green Chem. doi: 10.1039/c3gc37030e contributor: fullname: Oliveira – volume: 12 start-page: 350 year: 2019 ident: 10.1016/j.molliq.2021.117196_b0095 article-title: Butanol Synthesis Routes for Biofuel Production: Trends and Perspectives publication-title: Materials doi: 10.3390/ma12030350 contributor: fullname: Kolesinska – ident: 10.1016/j.molliq.2021.117196_b0215 doi: 10.1021/je060238o – year: 2001 ident: 10.1016/j.molliq.2021.117196_b0140 contributor: fullname: Poling – volume: 114 start-page: 11060 year: 2014 ident: 10.1016/j.molliq.2021.117196_b0035 article-title: Deep Eutectic Solvents (DESs) and Their Applications publication-title: Chem. Rev. doi: 10.1021/cr300162p contributor: fullname: Smith – volume: 38 start-page: 436 year: 2016 ident: 10.1016/j.molliq.2021.117196_b0100 article-title: Production of 2-methyl-1-butanol and 3-methyl-1-butanol in engineered Corynebacterium glutamicum publication-title: Metab. Eng. doi: 10.1016/j.ymben.2016.10.007 contributor: fullname: Vogt – ident: 10.1016/j.molliq.2021.117196_b0115 doi: 10.1021/acs.jctc.6b00449 – volume: 49 start-page: 2913 year: 2014 ident: 10.1016/j.molliq.2021.117196_b0280 article-title: Extraction of Phenol by Toluene in the Presence of Sodium Hydroxide publication-title: Sep. Sci. Technol. doi: 10.1080/01496395.2014.952748 contributor: fullname: Li – volume: 38 start-page: 871 issue: 7 year: 2006 ident: 10.1016/j.molliq.2021.117196_b0175 article-title: Thermophysical study of 1, 4-dioxane with cycloalkane mixtures publication-title: J. Chem. Thermodyn. doi: 10.1016/j.jct.2005.09.004 contributor: fullname: Romero – volume: 55 start-page: 510 year: 2010 ident: 10.1016/j.molliq.2021.117196_b0060 article-title: Liquid− liquid equilibria for benzene+ cyclohexane+ 1-butyl-3-methylimidazolium hexaflourophosphate publication-title: J. Chem. Eng. Data. doi: 10.1021/je900324s contributor: fullname: Lu – start-page: 1942 year: 1995 ident: 10.1016/j.molliq.2021.117196_b0145 article-title: In particle swarm optimization, Neural Networks, Proceedings publication-title: IEEE International Conference on Nov/Dec contributor: fullname: Kennedy – ident: 10.1016/j.molliq.2021.117196_b0155 doi: 10.2514/6.2005-1897 – volume: 24 start-page: 636 year: 2019 ident: 10.1016/j.molliq.2021.117196_b0235 article-title: Polyalcohols as hydrogen-bonding donors in choline chloride-based deep eutectic solvents for extraction of xanthones from the pericarp of garcinia mangostana L publication-title: J. Molecules doi: 10.3390/molecules24030636 contributor: fullname: Mulia – volume: 45 start-page: 636 issue: 4 year: 2000 ident: 10.1016/j.molliq.2021.117196_b0195 article-title: Relative permittivities, densities, refractive indices and ultrasound velocities of the binary systems of γ-butyrolactone with methanol, ethanol, 1-butanol, and 1-octanol publication-title: J. Chem. Eng. Data doi: 10.1021/je990226l contributor: fullname: Ritzoulis – volume: 7 start-page: 19984 issue: 24 year: 2019 ident: 10.1016/j.molliq.2021.117196_b0110 article-title: Mechanism Analysis for Separation of Cyclohexane and tert-Butanol System via Ionic Liquids as Extractants and Process Optimization publication-title: ACS Sustainable Chem. Eng. doi: 10.1021/acssuschemeng.9b05629 contributor: fullname: Xu – ident: 10.1016/j.molliq.2021.117196_b0050 doi: 10.1007/s11814-018-0030-z – volume: 54 start-page: 11404 issue: 45 year: 2015 ident: 10.1016/j.molliq.2021.117196_b0065 article-title: Aliphatic-Aromatic Separation Using Deep Eutectic Solvents as Extracting Agents publication-title: Ind. Eng. Chem. Res. doi: 10.1021/acs.iecr.5b02611 contributor: fullname: Rodriguez – volume: 43 start-page: 551 issue: 4 year: 2012 ident: 10.1016/j.molliq.2021.117196_b0160 article-title: Densities and refractive indices of the deep eutectic solvents (choline chloride + ethylene glycol or glycerol) and their aqueous mixtures at the temperature ranging from 298.15 to 333.15 K publication-title: J. Taiwan Inst. Chem. Eng. doi: 10.1016/j.jtice.2012.01.007 contributor: fullname: Leron – ident: 10.1016/j.molliq.2021.117196_b0200 doi: 10.1021/je700580g – volume: 14 start-page: 2153 year: 2012 ident: 10.1016/j.molliq.2021.117196_b0040 article-title: New natural and renewable low transition temperature mixtures (LTTMs): screening as solvents for lignocellulosic biomass processing publication-title: Green Chem. doi: 10.1039/c2gc35660k contributor: fullname: Francisco – volume: 50 start-page: 517 year: 2005 ident: 10.1016/j.molliq.2021.117196_b0300 article-title: Deacidification of Brazil Nut and Macadamia Nut Oils by Solvent Extraction: Liquid−Liquid Equilibrium Data at 298.2 K publication-title: J. Chem. Eng. Data. doi: 10.1021/je049687j contributor: fullname: Rodrigues – volume: 73 start-page: 1274 issue: 8 year: 1995 ident: 10.1016/j.molliq.2021.117196_b0185 article-title: Excess properties for cyclohexanone + butanols at 298.15 K publication-title: Can. J. Chem. doi: 10.1139/v95-156 contributor: fullname: Riggio – volume: 766 start-page: 61 year: 2013 ident: 10.1016/j.molliq.2021.117196_b0070 article-title: Natural deep eutectic solvents as new potential media for green technology publication-title: Anal. Chim. Acta. doi: 10.1016/j.aca.2012.12.019 contributor: fullname: Dai – ident: 10.1016/j.molliq.2021.117196_b0255 doi: 10.1016/j.seppur.2020.117975 – volume: 33 start-page: 1061 issue: 9 year: 2004 ident: 10.1016/j.molliq.2021.117196_b0180 article-title: Apparent dipole moments of 1-butanol, 1-propanol, and chlorobenzene in cyclohexane or benzene, and excess molar volumes of (1-propanol or chlorobenzene + cyclohexane or benzene) at T = 298.15 K publication-title: J. Solution Chem. doi: 10.1023/B:JOSL.0000048056.49122.6d contributor: fullname: Tanaka – volume: 59 start-page: 1247 issue: 4 year: 2014 ident: 10.1016/j.molliq.2021.117196_b0240 article-title: Solubilities of Carbon Dioxide in Eutectic Mixtures of Choline Chloride and Dihydric Alcohols publication-title: J. Chem. Eng. Data doi: 10.1021/je400884v contributor: fullname: Chen – volume: 22 start-page: 337 issue: 3 year: 2011 ident: 10.1016/j.molliq.2021.117196_b0090 article-title: Fermentative production of butanol-the industrial perspective publication-title: Curr. Opin. Biotechnol. doi: 10.1016/j.copbio.2011.02.004 contributor: fullname: Green – volume: 766 start-page: 61 year: 2013 ident: 10.1016/j.molliq.2021.117196_b0245 article-title: Natural deep eutectic solvents as new potential media for green technology publication-title: J. Anal. Chim. Acta doi: 10.1016/j.aca.2012.12.019 contributor: fullname: Daia – volume: 32 start-page: 2103 issue: 10 year: 2015 ident: 10.1016/j.molliq.2021.117196_b0020 article-title: Choline chloride-based deep eutectic solvents as additives for optimizing chromatographic behavior of caffeic acid publication-title: Korean J. Chem. Eng. doi: 10.1007/s11814-015-0054-6 contributor: fullname: Li – volume: 126 start-page: 9142 year: 2004 ident: 10.1016/j.molliq.2021.117196_b0025 article-title: Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids publication-title: J. Am. Chem. Soc. doi: 10.1021/ja048266j contributor: fullname: Abbott – ident: 10.1016/j.molliq.2021.117196_b0260 doi: 10.1016/j.molliq.2017.01.086 – volume: 3 start-page: 47 issue: 1 year: 1979 ident: 10.1016/j.molliq.2021.117196_b0285 article-title: Liquid-liquid equilibrium data: Their retrieval, correlation and prediction part II: correlation publication-title: Fluid Phase Equilib. doi: 10.1016/0378-3812(79)80027-8 contributor: fullname: Sørensen – volume: 112 start-page: 273 issue: 2 year: 1995 ident: 10.1016/j.molliq.2021.117196_b0295 article-title: Liquid-liquid-solid equilibria of the quaternary system water-ethanol-acetone-sodium chloride at 25 °C publication-title: Fluid Phase Equilib. doi: 10.1016/0378-3812(95)02804-N contributor: fullname: Marcilla – volume: 313 start-page: 113524 year: 2020 ident: 10.1016/j.molliq.2021.117196_b0125 article-title: Choline chloride-based deep eutectic solvents as green extractant for the efficient extraction of 1-butanol or 2-butanol from Azeotropic n-Heptane + Butanol Mixtures publication-title: J. Mol. Liq. doi: 10.1016/j.molliq.2020.113524 contributor: fullname: Esfahani – ident: 10.1016/j.molliq.2021.117196_b0205 – volume: 13 start-page: 462 issue: 4 year: 1968 ident: 10.1016/j.molliq.2021.117196_b0120 article-title: The system cyclohexane-2-propanol-water publication-title: J. Chem. Eng. Data doi: 10.1021/je60039a002 contributor: fullname: Verhoeye – volume: 61 start-page: 865 issue: 2 year: 2016 ident: 10.1016/j.molliq.2021.117196_b0250 article-title: Glycerol-based deep eutectic solvents as extractants for the separation of MEK and ethanol via liquid−liquid extraction publication-title: J. Chem. Eng. Data doi: 10.1021/acs.jced.5b00717 contributor: fullname: Rodriguez – volume: 51 start-page: 1915 issue: 5 year: 2006 ident: 10.1016/j.molliq.2021.117196_b0190 article-title: Effect of pressure on the static relative permittivities of alkan-1-ols at 298.15 K publication-title: J. Chem. Eng. Data. doi: 10.1021/je060248p contributor: fullname: Uosaki – volume: 174 start-page: 570 year: 2017 ident: 10.1016/j.molliq.2021.117196_b0230 article-title: Improving the production of propyl and butyl ester-based biodiesel by purification using deep eutectic solvents publication-title: Sep. Purif. Technol. doi: 10.1016/j.seppur.2016.10.036 contributor: fullname: Homan |
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| Snippet | •LLE data of (cyclohexane + alcohols + deep eutectic solvents) were measured.•Three choline chloride-based deep eutectic solvents were prepared.•Experimental... |
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| SubjectTerms | Choline chloride Deep eutectic solvent Liquid-liquid equilibrium Thermodynamic model |
| Title | Experimental study and thermodynamic modeling of phase equilibria of systems containing cyclohexane, alcohols (C4 and C5), and deep eutectic solvents |
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